Table Of ContentLandolt-Börnstein / New Series
Landolt-Börnstein
Numerical Data and Functional Relationships
in Science and Technology
New Series
Units and Fundamental Constants in Physics and Chemistry
Elementary Particles, Nuclei and Atoms (Group I)
(Formerly: Nuclear and Particle Physics)
Molecules and Radicals (Group II)
(Formerly: Atomic and Molecular Physics)
Condensed Matter (Group III)
(Formerly: Solid State Physics)
Physical Chemistry (Group IV)
(Formerly: Macroscopic Properties of Matter)
Geophysics (Group V)
Astronomy and Astrophysics (Group VI)
Biophysics (Group VII)
Advanced Materials and Technologies (Group VIII)
Some of the group names have been changed to provide a better description of their contents.
Landolt-Börnstein
Numerical Data and Functional Relationships in Science and Technology
New Series
Group IV: Physical Chemistry
Volume 14
Microporous and other
Framework Materials with Zeolite-
Type Structures
Subvolume G
Zeolite-Type Crystal Structures and their Chemistry.
41 New Framework Type Codes
Editors and Authors
R.X. Fischer, W.H. Baur
ISSN 1615-2018 (Physical Chemistry)
ISBN 978-3-642-41451-0 Springer Berlin Heidelberg New York
Library of Congress Cataloging in Publication Data
Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie
Vol. IV/14G: Editors: R.X. Fischer, W.H. Baur
At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology.
Tables chiefly in English.
Intended to supersede the Physikalisch-chemische Tabellen by H. Landolt and R. Börnstein of which the 6th ed. began publication in 1950 under title:
Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik.
Vols. published after v. 1 of group I have imprint: Berlin, New York, Springer-Verlag
Includes bibliographies.
1. Physics--Tables. 2. Chemistry--Tables. 3. Engineering--Tables.
I. Börnstein, R. (Richard), 1852-1913. II. Landolt, H. (Hans), 1831-1910.
III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology.
QC61.23 502'.12 62-53136
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Editors and Authors
R.X. Fischer
Fachbereich Geowissenschaften
Kristallographie
Universität Bremen
Klagenfurter Str.
Geo II, Raum 2340
D-28359 Bremen
e-mail: [email protected]
W.H. Baur
Western Springs, IL, 60558, USA
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Landolt-Börnstein
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Preface
When we first planned these volumes (subvolume B and the following subvolumes of volume 14 of
Landolt-Börnstein, Group IV: Physical Chemistry) about 20 years ago, 87 framework-type codes (FTC)
of zeolitic topologies had been approved by the Structure Commission of the International Zeolite
Association. At the time we estimated that there would be about one thousand crystal structure determina-
tions covering these FTCs. As one can see from Fig. 1.3 in the introduction to the present volume this was
an underestimate by a factor of two. Seven years later, by the time the first volume (subvolume B) was
published, the number of crystal structure determinations of zeolites had increased to approximately 3,500
(see Fig. 1.3 in the introduction). This was also the time when the exponential growth of these published
structures stopped, and growth continued in a linear fashion. By the end of 2013 we have to deal with
more than 6,000 crystal structures of zeolites distributed by now over 213 approved FTCs. Had the
exponential growth continued until 2013 we would have to contend by now with ca. 10,000 crystal
structures of zeolites. In terms of framework type codes we have almost caught up. Including the present
volume we have covered now 206 codes. The missing seven codes were approved by the Structure
Commission of the International Zeolite Association in July of 2013. That was too late for us to include
them in this volume. We hoped in the preface to subvolume B in the year 2000 to continue “speedily”
with our series of publications. However, it took us 14 years to reach the present state and to almost catch
up with the remarkable speed of development of the field. What is still missing are the last seven FTCs
from 2013 and the crystal structures of previously described codes which have been published after we
covered them in a previous subvolume. To give an example subvolume C published in 2002 lists 636
structure determinations of FAU-type (faujasite, zeolite X and Y) crystals, while we presently know of
266 more bringing the total to 902 (as compared to more than 1,000 for the SOD-type). These two are the
most studied of all zeolite types.
In Tables 4.3 and 4.4 of the introduction we are presenting a complete overhaul of the late
J.V. Smith’s Tables 16.3.2 and 16.3.1 from subvolume A of this series. The many changes in this area
made this necessary.
As stated before we have been aiming here at a complete, systematic, and standardized description of
all presently known zeolites and zeolite-like materials. With the publication of this volume we are up-to-
date as of the beginning of 2013. For general remarks on the background of this work see the preface and
the introduction to subvolume B.
The preparation of these volumes was a formidable task. Despite our best efforts, we know that it is
impossible to present such a wealth of material (possibly millions of pieces of data) without oversights,
mistakes and typographical errors. We welcome readers to point out to us any errors of omission or
commission which they find in these volumes.
At this time we wish to acknowledge the immediate help which we received in preparing these
volumes. Thus we thank Johannes Birkenstock for his efforts persuading Word to properly format turned
tables, Gabi Ebert for her assistance in obtaining literature, Thomas Messner for his support in program-
ming various useful tools for processing the data, and Antje Endemann from the Landolt-Börnstein edito-
rial office for her continuous and competent support in producing this volume. We are indebted to all
authors of the original papers who responded to our inquiries concerning details in their papers. We thank
Lynne McCusker and Christian Baerlocher from the ETH Zürich, who are maintaining the IZA-Web site,
for their gracious help in supplying additional information when needed by us for this volume.
Bremen/Western Springs, September 2013 Reinhard X. Fischer
Werner H. Baur
Table of Contents
IV/14 Microporous and other Framework Materials with Zeolite-Type
Structures
Subvolume G: Zeolite-Type Crystal Structures and their Chemistry.
41 New Framework Type Codes.
Introduction
1 General remarks ..................................................................................................................... 1
2 Systematics, descriptions, and definitions ............................................................................. 6
2.1 Modifications and changes ..................................................................................................... 6
2.2 Minerals with zeolite-type frameworks ................................................................................. 7
3 List of abbreviations .............................................................................................................. 13
4 Polyhedral units ...................................................................................................................... 14
5 Chemistry ............................................................................................................................... 43
6 References .............................................................................................................................. 52
Data
ASV ASU-7 (SeVen) ...................................................................................................................... 57
BCT BCTT (Body-Centered tetragonal Tectosilicate) .................................................................. 65
BEC BEta polymorph C ................................................................................................................ 81
BOF UCSB-15 (One Five) ............................................................................................................ 92
BOZ Beryllium framework 10 (One Zero) .................................................................................... 97
BSV UCSB-7 (SeVen) ................................................................................................................... 116
CDO CDS-1 (One) ......................................................................................................................... 127
EON ECR-1 (ONe) ........................................................................................................................ 133
ETR ECR-34 (Thirty-fouR) .......................................................................................................... 142
EZT EMM-3 (Zeolite Three) ........................................................................................................ 148
FAR FARneseite ........................................................................................................................... 157
GIU GIUseppettite ........................................................................................................................ 164
IHW ITQ-32 (tHirty-tWo) ............................................................................................................. 174
IMF IM-5 (Five) ........................................................................................................................... 180
IRR ITQ-44 (foRty-fouR) ............................................................................................................. 195
ITH ITQ-13 (THirteen) ................................................................................................................. 201
VIII Table of Contents
ITR ITQ-34 (Thirty-fouR) ........................................................................................................... 209
ITV ITQ-37 (Thirty-seVen) .......................................................................................................... 216
ITW ITQ-12 (TWelve) .................................................................................................................. 224
IWR ITQ-24 (tWenty-fouR) ......................................................................................................... 238
IWS ITQ-26 (tWenty-Six) ............................................................................................................ 247
IWV ITQ-27 (tWenty-seVen) ........................................................................................................ 254
IWW ITQ-22 (tWenty-tWo) ............................................................................................................ 261
JOZ LSJ-10 (One Zero)................................................................................................................. 272
JRY CJ-40 (foRtY) ........................................................................................................................ 278
JSN CJ-69 (Sixty-Nine) ................................................................................................................. 286
JST CJ-63 (Sixty-Three) .............................................................................................................. 293
JSW CJ-62 (Sixty-tWo) ................................................................................................................ 299
LIT LIThosite ............................................................................................................................... 305
LTF LZ-135 (hundred Thirty-Five) ............................................................................................... 316
LTJ Linde Type J ......................................................................................................................... 323
MRE ZSM-48 (foRty-Eight) ........................................................................................................... 330
MSE MCM-68 (Sixty-Eight) .......................................................................................................... 339
MVY MCM-70 (seVentY) ............................................................................................................... 348
NPT oxoNitridoPhosphate-2 (Two) ............................................................................................... 357
PCR IPC-4 (fouR) .......................................................................................................................... 364
PUN PKU-9 (Nine) ........................................................................................................................ 375
SAF STA-15 (Fifteen) .................................................................................................................... 383
SFS SSZ-56 (Fifty-Six) ................................................................................................................. 390
SFV SSZ-57 (Fifty-seVen) ............................................................................................................. 399
SOF SU-15 (One Five)................................................................................................................... 420
Errata ................................................................................................................................................ 426
Ref. p. 52] Introduction 1
Introduction
1 General remarks
This volume covers 41 framework-type codes (FTC) 1) approved by the Structure Commission of the
International Zeolite Association before the respective volumes of this series went to press since the first
volume of this series was published in 2000 [2000Bau1]. An overview of all FTC’s with the
corresponding type materials, year of approval by the IZA-SC is given in Table 1.1. Thus, all 206
framework types listed on the IZA website [2013Bae1] are described now with their standard settings in
volumes B to G. Figure 1.1 shows the increasing number of new zeolite-type frameworks which can be
compared with the corresponding diagram in Fig. 2.2.1 of volume B. Seven additional FTC’s (IFO, ITT,
JSR, OKO, SEW, SFW, SVV) have been approved in 2013, but full information was not available before
this volume went to press, thus they could not be included here.
250
200
s
C'
T
F
f
o
r 150
e
b
m
u
n
ve 100
ti
a
ul
m
u
c 50
0
1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020
year of assignment of FTC
Fig. 1.1. Cumulative number of framework type codes assigned by the IZA SC (the 1971 date refers to a
review paper by W.M. Meier and D.H. Olson [71Mei1] which precedes the series of atlases published
under the auspices of the IZA SC). It represents a first compilation of zeolite-type frameworks, though
without the assignment of framework type codes. FTC’s were assigned in [78Mei1] for the first time.
1) Abbreviations are listed in Chap. 3, p. 13.
Landolt-Börnstein DOI: 10.1007/978-3-642-41452-7_1
New Series IV/14G © Springer 2014
