Wetting: Theory and Experiments, Two-Volume Set

1251 Pages·2019·214.614 MB·\1251

by  Eli Ruckenstein (Author), Gersh Berim (Author)

Wetting Theory
Wetting: Theory and Experiments
Two-Volume Set
Eli Ruckenstein
Gersh Berim
Volumes in the Set:
Wetting Theory (ISBN: 9781138393301)
Wetting Experiments (ISBN: 9781138393332)
Wetting Theory
Eli Ruckenstein
Gersh Berim
CRC Press
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Library of Congress Cataloging-in-Publication Data
Names: Ruckenstein, Eli, 1925- author. | Berim, G. O. (Gersh Osievich),
author.
Title: Wetting theory / Eli Ruckenstein and Gersh Berim.
Description: Boca Raton : Taylor & Francis, a CRC title, part of the Taylor &
Francis imprint, a member of the Taylor & Francis Group, the academic
division of T&F Informa, plc, 2018. | Includes bibliographical references
and index.
Identifiers: LCCN 2018034120| ISBN 9781138393301 (hardback : alk. paper) |
ISBN 9780429401848 (ebook)
Subjects: LCSH: Wetting. | Surface chemistry.
Classification: LCC QD506 .R83 2018 | DDC 541/.33--dc23
LC record available at https://lccn.loc.gov/2018034120
Visit the Taylor & Francis Web site at
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Contents
Preface...............................................................................................................................................ix
Authors ..............................................................................................................................................xi
Chapter 1 Wetting of Solid by Liquid: Dynamics and Statics ......................................................1
Eli Ruckenstein and Gersh Berim
1.1 The Origin of Flow during Wetting of Solids ...................................................2
Clarence A. Miller and Eli Ruckenstein
1.2 The Appearance of Dry Patches on a Wetted Wall ...........................................9
Bryon E. Anshus and Eli Ruckenstein
1.3 Spreading Kinetics of Liquid Drops on Solids ................................................24
Jaime Lopez , Clarence A. Miller and Eli Ruckenstein
1.4 Concerning the Driving Force for Wetting .....................................................34
Eli Ruckenstein and P. S. Lee
1.5 Slip Velocity during Wetting of Solids ............................................................40
Eli Ruckenstein and C. S. Dunn
1.6 On the No-Slip Boundary Condition of Hydrodynamics ................................45
Eli Ruckenstein and P. Rajora
1.7 Dynamics of Partial Wetting ...........................................................................50
Eli Ruckenstein
1.8 Slip Velocity during the Flow of a Liquid over a Solid Surface ......................54
Eli Ruckenstein
1.9 Sorption on Deformable Solids: Density Functional Theory Approach .........61
Gersh Berim and Eli Ruckenstein
Chapter 2 Fluid in a Nanoslit: Symmetry Breaking ...................................................................69
Eli Ruckenstein and Gersh Berim
2.1 Fluid Density Profile Transitions and Symmetry Breaking in a Closed
Nanoslit ............................................................................................................70
Gersh Berim and Eli Ruckenstein
2.2 Symmetry Breaking of the Fluid Density Profiles in Closed Nanoslits..........87
Gersh Berim and Eli Ruckenstein
2.3 Effect of Fluid-Solid Interactions on Symmetry Breaking in Closed
Nanoslits ........................................................................................................103
Gersh Berim and Eli Ruckenstein
2.4 Two-Dimensional Symmetry Breaking of Fluid Density Distribution in
Closed Nanoslits ............................................................................................116
Gersh Berim and Eli Ruckenstein
v
vi Contents
2.5 Symmetry Breaking in Binary Mixtures in Closed Nanoslits ......................129
Gersh Berim and Eli Ruckenstein
2.6 Symmetry Breaking of the Density Distribution of a Quantum Fluid in
a Nanoslit .......................................................................................................142
Gersh Berim and Eli Ruckenstein
2.7 Symmetry Breaking in Confined Fluids .......................................................154
Eli Ruckenstein and Gersh Berim
Chapter 3 Macroscopic Drop on a Solid Surface ......................................................................197
Eli Ruckenstein and Gersh Berim
3.1 The Wetting Angle of Very Small and Large Drops .....................................198
Eli Ruckenstein and P. S. Lee
3.2 On the Shape and Stability of a Drop on a Solid Surface .............................210
Gersh Berim and Eli Ruckenstein
3.3 Microcontact and Macrocontact Angles and the Drop Stability on a
Bare Surface ..................................................................................................228
Gersh Berim and Eli Ruckenstein
3.4 Microscopic Treatment of a Barrel Drop on Fibers and Nanofibers .............247
Gersh Berim and Eli Ruckenstein
3.5 Cylindrical Droplet on Nanofibers: A Step toward the Clam-Shell Drop
Description ....................................................................................................272
Gersh Berim and Eli Ruckenstein
3.6 Microscopic Interpretation of the Dependence of the Contact Angle on
Roughness ......................................................................................................293
Gersh Berim and Eli Ruckenstein
3.7 Nanodroplets on a Planar Solid Surface: Temperature, Pressure,
and Size Dependence of Their Density and Contact Angles ........................311
Gersh Berim and Eli Ruckenstein
3.8 Dependence of the Macroscopic Contact Angle on the Liquid-Solid
Interaction Parameters and Temperature.......................................................333
Gersh Berim and Eli Ruckenstein
Chapter 4 Nanodrops on the Solid Surface: Contact Angle, Sticking Force ............................345
Eli Ruckenstein and Gersh Berim
4.1 Simple Expression for the Dependence of the Nanodrop Contact Angle
on Liquid-Solid Interactions and Temperature ..............................................347
Gersh Berim and Eli Ruckenstein
4.2 Universality in the Dependence of the Drop Contact Angle on
Liquid-Solid Interactions and Temperature Obtained by the Density
Functional Theory .........................................................................................359
Gersh Berim and Eli Ruckenstein
Contents vii
4.3 Nanodrop of an Ising Magnetic Fluid on a Solid Surface .............................375
Gersh Berim and Eli Ruckenstein
4.4 Nanodrop on a Nanorough Solid Surface: Density Functional Theory
Considerations ...............................................................................................390
Gersh Berim and Eli Ruckenstein
4.5 Nanodrop on a Nanorough Hydrophilic Solid Surface: Contact Angle
Dependence on the Size, Arrangement, and Composition of the Pillars ......408
Gersh Berim and Eli Ruckenstein
4.6 Contact Angle of a Nanodrop on a Nanorough Solid Surface ......................420
Gersh Berim and Eli Ruckenstein
4.7 Contact Angles of Nanodrops on Chemically Rough Surfaces ....................439
Gersh Berim and Eli Ruckenstein
4.8 Nanodrop on a Smooth Solid Surface with Hidden Roughness:
Density Functional Theory Considerations ...................................................448
Gersh Berim and Eli Ruckenstein
4.9 A Nanodrop on the Surface of a Lubricating Liquid Covering a Rough
Solid Surface .................................................................................................466
Gersh Berim and Eli Ruckenstein
4.10 Size Dependence of the Contact Angle of a Nanodrop in a Nanocavity:
Density Functional Theory Considerations ...................................................480
Gersh Berim and Eli Ruckenstein
4.11 Microscopic Calculation of the Sticking Force for Nanodrops on an
Inclined Surface .............................................................................................489
Gersh Berim and Eli Ruckenstein
4.12 Calculation of Nanodrop Profile from Fluid Density Distribution ...............505
Gersh Berim and Eli Ruckenstein
4.13 Microscopic Description of a Drop on a Solid Surface .................................519
Eli Ruckenstein and Gersh Berim
Chapter 5 Theory of the Liquid and Solid Films Rupture ........................................................587
Eli Ruckenstein and Gersh Berim
5.1 Spontaneous Rupture of Thin Liquid Films ..................................................588
Eli Ruckenstein and Rakesh K. Jain
5.2 Stability of Thin Solid Films .........................................................................604
Eli Ruckenstein and C. S. Dunn
5.3 Stability of Symmetric and Unsymmetric Thin Liquid Films to Short
and Long Wavelength Perturbations .............................................................637
Charles Maldarelli, Rakesh K. Jain, Ivan B. Ivanov, and Eli Ruckenstein
5.4 An Analytical Nonlinear Theory of Thin Film Rupture and Its
Application to Wetting Films ........................................................................667
Ashutosh Sharma and Eli Ruckenstein
viii Contents
5.5 Finite-Amplitude Instability of Thin Free and Wetting Films:
Prediction of Lifetimes ..................................................................................698
Ashutosh Sharma and Eli Ruckenstein
5.6 Stability, Critical Thickness, and the Time of Rupture of Thinning
Foam and Emulsion Films .............................................................................728
Ashutosh Sharma and Eli Ruckenstein
5.7 Nonlinear Stability and Rupture of Ultrathin Free Films .............................746
Ashutosh Sharma, C. S. Kishore, S. Salaniwal, and Eli Ruckenstein
5.8 Dewetting of Solids by the Formation of Holes in Macroscopic
Liquid Films ..................................................................................................761
Ashutosh Sharma and Eli Ruckenstein
5.9 Energetic Criteria for the Breakup of Liquid Films on Nonwetting
Solid Surfaces ................................................................................................775
Ashutosh Sharma and Eli Ruckenstein
5.10 Mechanism of Tear Film Rupture and Formation of Dry Spots on Cornea ....790
Ashutosh Sharma and Eli Ruckenstein
5.11 The Role of Lipid Abnormalities, Aqueous and Mucus Deficiencies
in the Tear Film Breakup, and Implications for Tear Substitutes and
Contact Lens Tolerance .................................................................................810
Ashutosh Sharma and Eli Ruckenstein
Index ..............................................................................................................................................843