The philosopher's stone and the rise of alchemy

86 Pages·2011·4.31 MB·English

Revised Edition: 2016
ISBN 978-1-280-29419-8
© All rights reserved.
Published by:
Learning Press
48 West 48 Street, Suite 1116,
New York, NY 10036, United States
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Table of Contents

Chapter 1 - History of Chemistry
Chapter 2 - History of Ferrous Metallurgy
Chapter 3 - Rise in Alchemy
Chapter 4 - Alchemy and Chemistry in Medieval Islam
Chapter 5 - History of Biochemistry
Chapter 6 - Chemical Industry and its History
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Chapter- 1
History of Chemistry

By 1000 BC, ancient civilizations used technologies that would eventually form the basis of the
various branches of chemistry. Examples include extracting metals from ores, making pottery
and glazes, fermenting beer and wine, making pigments for cosmetics and painting, extracting
chemicals from plants for medicine and perfume, making cheese, dying cloth, tanning leather,
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rendering fat into soap, making glass, and making alloys like bronze.
Early attempts to explain the nature of matter and its transformations failed. The protoscience of
chemistry, Alchemy, was also unsuccessful in explaining the nature of matter. However, by
performing experiments and recording the results the alchemist set the stage for modern
chemistry. This distinction begins to emerge when a clear differentiation was made between
chemistry and alchemy by Robert Boyle in his work The Sceptical Chymist (1661). Chemistry
then becomes a full-fledged science when Antoine Lavoisier develops his law of conservation of
mass, which demands careful measurements and quantitative observations of chemical
phenomena. So, while both alchemy and chemistry are concerned with the nature of matter and
its transformations, it is only the chemists who apply the scientific method. The history of
chemistry is intertwined with the history of thermodynamics, especially through the work of
Willard Gibbs.
From fire to atomism
Arguably the first chemical reaction used in a controlled manner was fire. However, for
millennia fire was simply a mystical force that could transform one substance into another
(burning wood, or boiling water) while producing heat and light. Fire affected many aspects of
early societies. These ranged from the most simple facets of everyday life, such as cooking and
habitat lighting, to more advanced technologies, such as pottery, bricks, and melting of metals to
make tools.
Philosophical attempts to rationalize why different substances have different properties (color,
density, smell), exist in different states (gaseous, liquid, and solid), and react in a different
manner when exposed to environments, for example to water or fire or temperature changes, led
ancient philosophers to postulate the first theories on nature and chemistry. The history of such
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philosophical theories that relate to chemistry, can probably be traced back to every single
ancient civilization. The common aspect in all these theories was the attempt to identify a small
number of primary elements that make up all the various substances in nature. Substances like
air, water, and soil/earth, energy forms, such as fire and light, and more abstract concepts such as
ideas, aether, and heaven, were common in ancient civilizations even in absence of any cross-
fertilization; for example in Greek, Indian, Mayan, and ancient Chinese philosophies all
considered air, water, earth and fire as primary elements.
Atomism can be traced back to ancient Greece and ancient India. Greek atomism dates back to
440 BC, as what might be indicated by the book De Rerum Natura (The Nature of Things)
written by the Roman Lucretius in 50 BC. In the book was found ideas traced back to
Democritus and Leucippus, who declared that atoms were the most indivisible part of matter.
This coincided with a similar declaration by Indian philosopher Kanada in his Vaisheshika sutras
around the same time period. In much the same fashion he discussed the existence of gases.
What Kanada declared by sutra, Democritus declared by philosophical musing. Both suffered
from a lack of empirical data. Without scientific proof, the existence of atoms was easy to deny.
Aristotle opposed the existence of atoms in 330 BC.
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Much of the early development of purification methods is described by Pliny the Elder in his
Naturalis Historia. He made attempts to explain those methods, as well as making acute
observations of the state of many minerals.
The rise of metallurgy
It was fire that led to the discovery of glass and the purification of metals which in turn gave way
to the rise of metallurgy. During the early stages of metallurgy, methods of purification of metals
were sought, and gold, known in ancient Egypt as early as 2600 BC, became a precious metal.
The discovery of alloys heralded the Bronze Age. After the Bronze Age, the history of
metallurgy was marked by which army had better weaponry. Countries in Eurasia had their
heyday when they made the superior alloys, which, in turn, made better armour and better
weapons. This often determined the outcomes of battles. Significant progress in metallurgy and
alchemy was made in ancient India.

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The philosopher's stone and the rise of alchemy
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"Renel the Alchemist", by Sir William Douglas, 1853
Many people were interested in finding a method that could convert cheaper metals into gold.
The material that would help them do this was rumored to exist in what was called the
philosopher's stone. This led to the protoscience called alchemy. Alchemy was practiced by
many cultures throughout history and often contained a mixture of philosophy, mysticism, and
protoscience.
Alchemy not only sought to turn base metals into gold, but especially in a Europe rocked by
bubonic plague, there was hope that alchemy would lead to the development of medicines to
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improve people's health. The holy grail of this strain of alchemy was in the attempts made at
finding the elixir of life, which promised eternal youth. Neither the elixir nor the philosopher's
stone were ever found. Also, characteristic of alchemists was the belief that there was in the air
an "ether" which breathed life into living things. Practitioners of alchemy included Isaac Newton,
who remained one throughout his life.
Problems encountered with alchemy
There were several problems with alchemy, as seen from today's standpoint. There was no
systematic naming system for new compounds, and the language was esoteric and vague to the
point that the terminologies meant different things to different people. In fact, according to The
Fontana History of Chemistry (Brock, 1992):
The language of alchemy soon developed an arcane and secretive technical vocabulary designed
to conceal information from the uninitiated. To a large degree, this language is incomprehensible
to us today, though it is apparent that readers of Geoffery Chaucer's Canon's Yeoman's Tale or
audiences of Ben Jonson's The Alchemist were able to construe it sufficiently to laugh at it.
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Chaucer's tale exposed the more fraudulent side of alchemy, especially the manufacture of
counterfeit gold from cheap substances. Less than a century earlier, Dante Alighieri also
demonstrated an awareness of this fraudulence, causing him to consign all alchemists to the
Inferno in his writings. Soon after, in 1317, the Avignon Pope John XXII ordered all alchemists
to leave France for making counterfeit money. A law was passed in England in 1403 which made
the "multiplication of metals" punishable by death. Despite these and other apparently extreme
measures, alchemy did not die. Royalty and privileged classes still sought to discover the
philosopher's stone and the elixir of life for themselves.
There was also no agreed-upon scientific method for making experiments reproducible. Indeed
many alchemists included in their methods irrelevant information such as the timing of the tides
or the phases of the moon. The esoteric nature and codified vocabulary of alchemy appeared to
be more useful in concealing the fact that they could not be sure of very much at all. As early as
the 14th century, cracks seemed to grow in the facade of alchemy; and people became sceptical.
Clearly, there needed to be a scientific method where experiments can be repeated by other
people, and results needed to be reported in a clear language that laid out both what is known and
unknown.

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From alchemy to chemistry

Ambix, cucurbit and retort of Zosimus, from Marcelin Berthelot, Collection des anciens alchimistes grecs
(3 vol., Paris, 1887-1888).
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Early chemists

Jābir ibn Hayyān (Geber), a Persian alchemist whose experimental research laid the foundations for
chemistry.
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In the Arab World, the Muslims were translating the works of the ancient Greeks and Egyptians
into Arabic and were experimenting with scientific ideas. The development of the modern
scientific method was slow and arduous, but an early scientific method for chemistry began
emerging among early Muslim chemists, beginning with the 9th century chemist Jābir ibn
Hayyān (known as "Geber" in Europe), who is "considered as the father of chemistry". He
introduced a systematic and experimental approach to scientific research based in the laboratory,
in contrast to the ancient Greek and Egyptian alchemists whose works were largely allegorical
and often unintelligble. He also invented and named the alembic (al-anbiq), chemically analyzed
many chemical substances, composed lapidaries, distinguished between alkalis and acids, and
manufactured hundreds of drugs. He also refined the theory of five classical elements into the
theory of seven alchemical elements after identifying mercury and sulfur as chemical elements.
Among other influential Muslim chemists, Ja'far al-Sadiq, Alkindus, Abū al-Rayhān al-Bīrūnī,
Avicenna and Ibn Khaldun refuted the theories of alchemy, particularly the theory of the
transmutation of metals; and al-Tusi described a version of the conservation of mass, noting that
a body of matter is able to change but is not able to disappear. Rhazes refuted Aristotle's theory
of four classical elements for the first time and set up the firm foundations of modern chemistry,
using the laboratory in the modern sense, designing and describing more than twenty
instruments, manWy parts of which are still in use today, Tsuch as a crucible, decensory, cucurbit or
retort for distillation, and the head of a still with a delivery tube (ambiq, Latin alembic), and
various types of furnace or stove.

Agricola, author of De re metallica
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For the more honest practitioners in Europe, alchemy became an intellectual pursuit after early
Arabic alchemy became available through Latin translation, and over time, they got better at it.
Paracelsus (1493–1541), for example, rejected the 4-elemental theory and with only a vague
understanding of his chemicals and medicines, formed a hybrid of alchemy and science in what
was to be called iatrochemistry. Paracelsus was not perfect in making his experiments truly
scientific. For example, as an extension of his theory that new compounds could be made by
combining mercury with sulfur, he once made what he thought was "oil of sulfur". This was
actually dimethyl ether, which had neither mercury nor sulfur.
Practical attempts to improve the refining of ores and their extraction to smelt metals was an
important source of information for early chemists, among them Georg Agricola (1494–1555),
who published his great work De re metallica in 1556. His approach removed the mysticism
associated with the subject, creating the practical base upon which others could build. The work
describes the many kinds of furnace used to smelt ore, and stimulated interest in minerals and
their composition. It is no coincidence that he gives numerous references to the earlier author,
Pliny the Elder and his Naturalis Historia.
In 1605, Sir Francis Bacon published The Proficience and Advancement of Learning, which
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contains a description of what would later be known as the scientific method. In 1615 Jean
Beguin publishes the Tyrocinium Chymicum, an early chemistry textbook, and in it draws the
first-ever chemical equation.
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