The Chemistry of the Actinide and Transactinide Elements, 4th Edition (Volumes 1–6)

4521 Pages·2011·97.62 MB·English

by  Lester R. Morss

THE CHEMISTRY OF THE
ACTINIDE AND
TRANSACTINIDE ELEMENTS
Joseph J. Katz Glenn T. Seaborg
This work is dedicated to
Joseph J. Katz and Glenn T. Seaborg,
authors of the first and second editions of
The Chemistry of the Actinide Elements
and leaders in the field of actinide chemistry.
THE CHEMISTRY OF THE
ACTINIDE AND
TRANSACTINIDE ELEMENTS
FOURTH EDITION
Volumes 1–6
EDITED BY
Lester R. Morss
ArgonneNationalLaboratory,
Argonne,Illinois,USA
Norman M. Edelstein
LawrenceBerkeleyNationalLaboratory,
Berkeley,California,USA
Jean Fuger
UniversityofLie`ge,
Lie`ge,Belgium
AC.I.P.CataloguerecordforthisbookisavailablefromtheLibraryofCongress:2010931441
ISBN:978-94-007-0210-3(HB)6Volumeset
ISBN:978-94-007-0211-0(e-book)6Volumeset
PublishedbySpringer,
P.O.Box17,3300AADordrecht,TheNetherlands.
www.springer.com
Printedonacid-freepaper
Chapters33and36werecreatedwithinthecapacityofanUSgovernmental
employmentandthereforeareinthepublicdomain.
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#2010Springer
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inanyformorbyanymeans,electronic,mechanical,photocopying,microfilming,recording
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PrintedintheNetherlands.
CONTENTS
Volume 1
Contributors ix
Preface xv
1. Introduction 1
JosephJ.Katz,LesterR.Morss,NormanM.Edelstein,
andJeanFuger
2. Actinium 18
H.W.KirbyandL.R.Morss
3. Thorium 52
MathiasS.Wickleder,BlandineFourest,andPeterK.Dorhout
4. Protactinium 161
BorisF.Myasoedov,H.W.Kirby,andIvanG.Tananaev
5. Uranium 253
IngmarGrenthe,JanuszDroz˙dz˙yn´ski,TakeoFujino,
EdgarC.Buck,ThomasE.Albrecht-Schmitt,andStephenF.Wolf
SubjectIndex(Volumes1,2,3,4,5,6) I-1
Volume 2
Contributors ix
Preface xv
6. Neptunium 699
ZenkoYoshida,StephenG.Johnson,TakaumiKimura,and
JohnR.Krsul
7. Plutonium 813
DavidL.Clark,SiegfriedS.Hecker,GordonD.Jarvinen,and
MaryP.Neu
8. Americium 1265
WolfgangH.RundeandWallaceW.Schulz
SubjectIndex(Volumes1,2,3,4,5,6) I-1
v
vi Contents
Volume 3
Contributors ix
Preface xv
9. Curium 1397
GreggJ.Lumetta,MajorC.Thompson,
RobertA.Penneman,andP.GaryEller
10. Berkelium 1444
DavidE.HobartandJosephR.Peterson
11. Californium 1499
RichardG.Haire
12. Einsteinium 1577
RichardG.Haire
13. Fermium,Mendelevium,Nobelium,andLawrencium 1621
RobertJ.Silva
14. TransactinideElementsandFutureElements 1652
DarleaneC.Hoffman,DianaM.Lee,andValeriaPershina
15. SummaryandComparisonofPropertiesoftheActinideand
TransactinideElements 1753
NormanM.Edelstein,JeanFuger,JosephJ.Katz,and
LesterR.Morss
16. SpectraandElectronicStructuresofFreeActinide
AtomsandIons 1836
EarlF.Worden,JeanBlaise,MarkFred,NorbertTrautmann,
andJean-Franc¸oisWyart
17. TheoreticalStudiesoftheElectronicStructureofCompounds
oftheActinideElements 1893
NikolasKaltsoyannis,P.JeffreyHay,JunLi,Jean-PhilippeBlaudeau,
andBruceE.Bursten
18. OpticalSpectraandElectronicStructure 2013
GuokuiLiuandJamesV.Beitz
SubjectIndex(Volumes1,2,3,4,5,6) I-1
Volume 4
Contributors ix
Preface xv
19. ThermodynamicPropertiesofActinidesandActinideCompounds 2113
RudyJ.M.Konings,LesterR.Morss,andJeanFuger
20. MagneticProperties 2225
NormanM.EdelsteinandGerardH.Lander
Contents vii
21. 5f-ElectronPhenomenaintheMetallicState 2307
A.J.Arko,JohnJ.Joyce,andLadiaHavela
22. ActinideStructuralChemistry 2380
KeithE.Gutowski,NicholasJ.Bridges,andRobinD.Rogers
23. ActinidesinSolution:ComplexationandKinetics 2524
GregoryR.ChoppinandMarkP.Jensen
24. ActinideSeparationScienceandTechnology 2622
KennethL.Nash,CharlesMadic,JagdishN.Mathur,
andJe´roˆmeLacquement
SubjectIndex(Volumes1,2,3,4,5,6) I-1
Volume 5
Contributors ix
Preface xv
25. OrganoactinideChemistry:SynthesisandCharacterization 2799
CarolJ.BurnsandMorisS.Eisen
26. HomogeneousandHeterogeneousCatalyticProcesses
PromotedbyOrganoactinides 2911
CarolJ.BurnsandMorisS.Eisen
27. IdentificationandSpeciationofActinidesintheEnvironment 3013
ClaudeDegueldre
28. X-rayAbsorptionSpectroscopyoftheActinides 3086
MarkR.AntonioandLyndaSoderholm
29. Handling,Storage,andDispositionofPlutoniumandUranium 3199
JohnM.HaschkeandJerryL.Stakebake
30. TraceAnalysisofActinidesinGeological,Environmental,
andBiologicalMatrices 3273
StephenF.Wolf
31. ActinidesinAnimalsandMan 3339
PatriciaW.Durbin
AppendixI
NuclearSpinsandMomentsoftheActinides 3441
IrshadAhmad
AppendixII
NuclearPropertiesofActinideandTransactinideNuclides 3442
IrshadAhmad
SubjectIndex(Volumes1,2,3,4,5,6) I-1
viii Contents
Volume 6
Contributors ix
Preface xvii
32. ActinidesintheGeosphere 3475
WolfgangRundeandMaryP.Neu
33. SubsurfaceInteractionsofActinideSpecieswithMicroorganisms 3595
DonaldT.Reed,RandhirP.Deo,andBruceE.Rittmann
34. NuclearFuels 3665
RudyJ.M.Konings,ThierryWiss,andChristineGue´neau
35. ActinideWasteFormsandRadiationEffects 3813
R.C.EwingandW.J.Weber
36. AnalyticalChemistryofPlutonium 3889
KentonJ.Moody,DawnA.Shaughnessy,KarinCasteleyn,
HerbertOttmar,KlausLu¨tzenkirchen,MariaWallenius,
andThierryWiss
37. ActinideChalcogenideCompounds 4005
EmmanouilManos,MercouriG.Kanatzidis,andJamesA.Ibers
38. MolecularSpectroscopyandReactionsofActinidesintheGas
PhaseandCryogenicMatrices 4079
MichaelC.Heaven,JohnK.Gibson,andJoaquimMarc¸alo
39. HydrothermalSynthesisandCrystalStructuresof
ActinideCompounds 4157
ThomasE.Albrecht-Schmitt,PeterC.Burns,
andSergeyV.Krivovichev
SubjectIndex(Volumes1,2,3,4,5,6) I-1
AuthorIndex(Volumes1,2,3,4,5,6) I-159
CONTRIBUTORS
IrshadAhmad
ArgonneNationalLaboratory,Argonne,Illinois,USA
ThomasE.Albrecht-Schmitt
UniversityofNotreDame,NotreDame,Indiana,USA
MarkR.Antonio
ArgonneNationalLaboratory,Argonne,Illinois,USA
A.J.Arko
LosAlamosNationalLaboratory,LosAlamos,NewMexico,USA(retired)
JamesV.Beitz
ArgonneNationalLaboratory,Argonne,Illinois,USA(retired)
JeanBlaise
LaboratoireAime´Cotton,Orsay,France
Jean-PhilippeBlaudeau
HighPerformanceTechnologies,Inc.,Wright–PattersonAirForceBase,Ohio,USA
NicholasJ.Bridges
TheUniversityofAlabama,Tuscaloosa,Alabama,USA
EdgarC.Buck
PacificNorthwestNationalLaboratory,Richland,Washington,USA
CarolJ.Burns
LosAlamosNationalLaboratory,LosAlamos,NewMexico,USA
PeterC.Burns
UniversityofNotreDame,NotreDame,Indiana,USA
BruceE.Bursten
TheUniversityofTennessee,Knoxville,Tennessee,USA
KarinCasteleyn
European Commission, Joint Research Centre, Institute for Transuranium Elements,
Karlsruhe,Germany
ix