Ternary Alloys Based on II-VI Semiconductor Compounds

543 Pages·2013·80.64 MB·English

by  Vasyl Tomashyk

Physics/Materials Science
Ternary Alloys Based on II-VI
Semiconductor Compounds
Tomashyk
Feychuk
Shcherbak
Doped by isovalent or heterovalent foreign impurities (F), II–VI
semiconductor compounds enable control of optical and electronic ST
properties, making them ideal in detectors, solar cells, and other
e
precise device applications. For the reproducible manufacturing e
r
of the doped materials with predicted and desired properties, m
manufacturing technologists need knowledge of appropriate ternary n
system phase diagrams.
ia
c
r
A guide for technologists and researchers at industrial and national o
laboratories, Ternary Alloys Based on II-VI Semiconductor y
n
Compounds collects all available data on ternary II–VI–F semiconductor
materials. It presents ternary phase diagrams for the systems and dA
includes data about phase equilibriums on the cross sections. The
u
book is also suitable for phase diagram researchers, inorganic l
l
chemists, and solid state physicists as well as students in materials co
science, engineering, physical chemistry, and physics.
ty
os
The authors classify all materials according to the periodic groups
of their constituent atoms (i.e., possible combinations of Zn, Cd, r
and Hg with chalcogens S, Se, and Te) and additional components B
in the order of their group number. Each ternary system database C
a
description contains the diagram type, possible phase transformation
o
and physical–chemical interaction of the components, equilibrium s
investigation methods, thermodynamic characteristics, and the me
sample preparation method. In some cases, the book illustrates
d
the solid- and liquid-phase equilibriums with vapor because of
p
their importance to crystal growth using the vapor–liquid–solid
technique. It also presents data on the homogeneity range as well oo
as baric and temperature dependences of solubility impurities in the un
semiconductor lattice and the liquid phase.
n
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dI
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I

K14242
ISBN: 978-1-4398-9566-5
90000
9 781439 895665
K14242_COVER_final.indd 1 6/20/13 10:17 AM

Ternary Alloys
Based on II-VI
Semiconductor
Compounds

Ternary Alloys
Based on II-VI
Semiconductor
Compounds
Vasyl Tomashyk
Petro Feychuk
Larysa Shcherbak
Taylor & Francis
Taylor & Francis Group
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Boca Raton, FL 33487-2742
© 2014 by Taylor & Francis Group, LLC
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No claim to original U.S. Government works
Version Date: 20130624
International Standard Book Number-13: 978-1-4398-9567-2 (eBook - PDF)
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Contents
Preface ...................................................................................................................xiii
1. Phase Equilibria in the Systems Based on ZnS .......................................1
1.1 Zinc–Sodium–Sulfur ............................................................................1
1.2 Zinc–Copper–Sulfur .............................................................................2
1.3 Zinc–Silver–Sulfur ................................................................................5
1.4 Zinc–Magnesium–Sulfur .....................................................................6
1.5 Zinc–Calcium–Sulfur ...........................................................................7
1.6 Zinc–Barium–Sulfur .............................................................................8
1.7 Zinc–Strontium–Sulfur ........................................................................8
1.8 Zinc–Cadmium–Sulfur ........................................................................8
1.9 Zinc–Mercury–Sulfur .........................................................................12
1.10 Zinc–Aluminum–Sulfur ....................................................................13
1.11 Zinc–Gallium–Sulfur .........................................................................15
1.12 Zinc–Indium–Sulfur ...........................................................................18
1.13 Zinc–Thallium–Sulfur ........................................................................22
1.14 Zinc–Scandium–Sulfur ......................................................................23
1.15 Zinc–Yttrium–Sulfur ..........................................................................24
1.16 Zinc–Lanthanum–Sulfur ...................................................................24
1.17 Zinc–Cerium–Sulfur ..........................................................................25
1.18 Zinc–Praseodymium–Sulfur .............................................................25
1.19 Zinc–Neodymium–Sulfur .................................................................25
1.20 Zinc–Samarium–Sulfur .....................................................................26
1.21 Zinc–Gadolinium–Sulfur ..................................................................27
1.22 Zinc–Terbium–Sulfur .........................................................................28
1.23 Zinc–Dysprosium–Sulfur ..................................................................28
1.24 Zinc–Holmium–Sulfur .......................................................................29
1.25 Zinc–Erbium–Sulfur ...........................................................................29
1.26 Zinc–Thulium–Sulfur .........................................................................29
1.27 Zinc–Ytterbium–Sulfur.......................................................................30
1.28 Zinc–Lutetium–Sulfur ........................................................................30
1.29 Zinc–Carbon–Sulfur ...........................................................................30
1.30 Zinc–Silicon–Sulfur ............................................................................31
1.31 Zinc–Germanium–Sulfur ..................................................................31
1.32 Zinc–Tin–Sulfur ..................................................................................32
1.33 Zinc–Lead–Sulfur ...............................................................................34
1.34 Zinc–Titanium–Sulfur ........................................................................35
1.35 Zinc–Phosphorus–Sulfur ...................................................................35
1.36 Zinc–Arsenic–Sulfur ..........................................................................36
1.37 Zinc–Antimony–Sulfur ......................................................................39
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vi Contents
1.38 Zinc–Bismuth–Sulfur .........................................................................39
1.39 Zinc–Oxygen–Sulfur ..........................................................................42
1.40 Zinc–Selenium–Sulfur .......................................................................43
1.41 Zinc–Tellurium–Sulfur .......................................................................44
1.42 Zinc–Chromium–Sulfur ....................................................................46
1.43 Zinc–Molybdenum–Sulfur ................................................................46
1.44 Zinc–Fluorine–Sulfur .........................................................................46
1.45 Zinc–Chlorine–Sulfur ........................................................................47
1.46 Zinc–Iodine–Sulfur .............................................................................47
1.47 Zinc–Manganese–Sulfur ....................................................................48
1.48 Zinc–Iron–Sulfur .................................................................................49
1.49 Zinc–Cobalt–Sulfur ............................................................................51
1.50 Zinc–Nickel–Sulfur .............................................................................51
References .......................................................................................................52
2. Systems Based on ZnSe ...............................................................................65
2.1 Zinc–Copper–Selenium .....................................................................65
2.2 Zinc–Silver–Selenium.........................................................................66
2.3 Zinc–Beryllium–Selenium .................................................................67
2.4 Zinc–Magnesium–Selenium ..............................................................67
2.5 Zinc–Cadmium–Selenium.................................................................69
2.6 Zinc–Mercury–Selenium ...................................................................70
2.7 Zinc–Aluminum–Selenium ...............................................................71
2.8 Zinc–Gallium–Selenium ....................................................................71
2.9 Zinc–Indium–Selenium .....................................................................74
2.10 Zinc–Thallium–Selenium ..................................................................76
2.11 Zinc–Lanthanum–Selenium ..............................................................76
2.12 Zinc–Carbon–Selenium .....................................................................76
2.13 Zinc–Silicon–Selenium .......................................................................76
2.14 Zinc–Germanium–Selenium .............................................................77
2.15 Zinc–Tin–Selenium .............................................................................77
2.16 Zinc–Lead–Selenium ..........................................................................80
2.17 Zinc–Phosphorus–Selenium .............................................................80
2.18 Zinc–Arsenic–Selenium .....................................................................81
2.19 Zinc–Bismuth–Selenium ....................................................................84
2.20 Zinc–Niobium–Selenium ...................................................................88
2.21 Zinc–Oxygen–Selenium .....................................................................88
2.22 Zinc–Tellurium–Selenium .................................................................90
2.23 Zinc–Chromium–Selenium ...............................................................91
2.24 Zinc–Molybdenum–Selenium ...........................................................92
2.25 Zinc–Manganese–Selenium ..............................................................92
2.26 Zinc–Iron–Selenium ...........................................................................93
2.27 Zinc–Cobalt–Selenium .......................................................................94
2.28 Zinc–Palladium–Selenium ................................................................94
References .......................................................................................................95
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Contents vii
3. Systems Based on ZnTe .............................................................................103
3.1 Zinc–Copper–Tellurium ...................................................................103
3.2 Zinc–Silver–Tellurium ......................................................................103
3.3 Zinc–Beryllium–Tellurium ..............................................................105
3.4 Zinc–Magnesium–Tellurium ...........................................................105
3.5 Zinc–Cadmium–Tellurium ..............................................................106
3.6 Zinc–Mercury–Tellurium .................................................................114
3.7 Zinc–Aluminum–Tellurium ............................................................117
3.8 Zinc–Gallium–Tellurium .................................................................118
3.9 Zinc–Indium–Tellurium ...................................................................119
3.10 Zinc–Thallium–Tellurium ................................................................121
3.11 Zinc–Lanthanum–Tellurium ...........................................................126
3.12 Zinc–Silicon–Tellurium ....................................................................126
3.13 Zinc–Germanium–Tellurium ..........................................................128
3.14 Zinc–Tin–Tellurium ..........................................................................129
3.15 Zinc–Lead–Tellurium .......................................................................129
3.16 Zinc–Arsenic–Tellurium ..................................................................132
3.17 Zinc–Antimony–Tellurium ..............................................................137
3.18 Zinc–Bismuth–Tellurium .................................................................138
3.19 Zinc–Oxygen–Tellurium ..................................................................142
3.20 Zinc–Chlorine–Tellurium ................................................................143
3.21 Zinc–Manganese–Tellurium ............................................................144
References .....................................................................................................144
4. Systems Based on CdS ...............................................................................153
4.1 Cadmium–Lithium–Sulfur ..............................................................153
4.2 Cadmium–Sodium–Sulfur ..............................................................153
4.3 Cadmium–Potassium–Sulfur ..........................................................154
4.4 Cadmium–Rubidium–Sulfur ..........................................................155
4.5 Cadmium–Copper–Sulfur ...............................................................155
4.6 Cadmium–Silver–Sulfur ..................................................................158
4.7 Cadmium–Gold–Sulfur ...................................................................161
4.8 Cadmium–Magnesium–Sulfur .......................................................162
4.9 Cadmium–Calcium–Sulfur .............................................................163
4.10 Cadmium–Strontium–Sulfur ..........................................................164
4.11 Cadmium–Barium–Sulfur ...............................................................165
4.12 Cadmium–Mercury–Sulfur .............................................................166
4.13 Cadmium–Boron–Sulfur .................................................................167
4.14 Cadmium–Aluminum–Sulfur ........................................................169
4.15 Cadmium–Gallium–Sulfur .............................................................170
4.16 Cadmium–Indium–Sulfur ...............................................................173
4.17 Cadmium–Thallium–Sulfur ............................................................178
4.18 Cadmium–Scandium–Sulfur ..........................................................182
4.19 Cadmium–Yttrium–Sulfur ..............................................................182
4.20 Cadmium–Lanthanum–Sulfur .......................................................183
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viii Contents
4.21 Cadmium–Cerium–Sulfur...............................................................184
4.22 Cadmium–Praseodymium–Sulfur .................................................184
4.23 Cadmium–Neodymium–Sulfur .....................................................185
4.24 Cadmium–Samarium–Sulfur..........................................................185
4.25 Cadmium–Gadolinium–Sulfur ......................................................185
4.26 Cadmium–Terbium–Sulfur..............................................................186
4.27 Cadmium–Dysprosium–Sulfur ......................................................187
4.28 Cadmium–Holmium–Sulfur ...........................................................187
4.29 Cadmium–Erbium–Sulfur ...............................................................188
4.30 Cadmium–Thulium–Sulfur .............................................................189
4.31 Cadmium–Ytterbium–Sulfur ...........................................................189
4.32 Cadmium–Lutecium–Sulfur ...........................................................190
4.33 Cadmium–Silicon–Sulfur ................................................................190
4.34 Cadmium–Germanium–Sulfur ......................................................193
4.35 Cadmium–Tin–Sulfur ......................................................................201
4.36 Cadmium–Lead–Sulfur ...................................................................206
4.37 Cadmium–Phosphorus–Sulfur .......................................................207
4.38 Cadmium–Arsenic–Sulfur ..............................................................209
4.39 Cadmium–Antimony–Sulfur ..........................................................212
4.40 Cadmium–Bismuth–Sulfur .............................................................215
4.41 Cadmium–Oxygen–Sulfur ..............................................................218
4.42 Cadmium–Selenium–Sulfur ...........................................................220
4.43 Cadmium–Tellurium–Sulfur ...........................................................221
4.44 Cadmium–Chromium–Sulfur ........................................................223
4.45 Cadmium–Molybdenum–Sulfur ....................................................224
4.46 Cadmium–Chlorine–Sulfur ............................................................224
4.47 Cadmium–Bromine–Sulfur .............................................................226
4.48 Cadmium–Iodine–Sulfur .................................................................226
4.49 Cadmium–Manganese–Sulfur ........................................................227
4.50 Cadmium–Iron–Sulfur .....................................................................228
4.51 Cadmium–Cobalt–Sulfur ................................................................229
References .....................................................................................................229
5. System Based on CdSe...............................................................................243
5.1 Cadmium–Sodium–Selenium .........................................................243
5.2 Cadmium–Potassium–Selenium ....................................................243
5.3 Cadmium–Rubidium–Selenium .....................................................243
5.4 Cadmium–Copper–Selenium .........................................................244
5.5 Cadmium–Silver–Selenium .............................................................246
5.6 Cadmium–Magnesium–Selenium ..................................................248
5.7 Cadmium–Barium–Selenium .........................................................249
5.8 Cadmium–Mercury–Selenium .......................................................249
5.9 Cadmium–Boron–Selenium ............................................................250
5.10 Cadmium–Aluminum–Selenium ...................................................252
5.11 Cadmium–Gallium–Selenium ........................................................252
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