Table Of ContentNIMS Monographs
Yutaka Wakayama
Katsuhiko Ariga Editors
System-Materials
Nanoarchitectonics
NIMS Monographs
SeriesEditor
NaokiOHASHI,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan
EditorialBoard
MikikoTANIFUJI,NationalInstituteforMaterialsScience,Tsukuba,Japan
TakahitoOHMURA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,
Japan
YoshitakaTATEYAMA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,
Japan
TakashiTANIGUCHI,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,
Japan
KazuyaTERABE,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan
MasanobuNAITO,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,
Japan
NobutakaHANAGATA,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,
Japan
KenjiroMIYANO,NationalInstituteforMaterialsScience,Tsukuba,Ibaraki,Japan
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·
Yutaka Wakayama Katsuhiko Ariga
Editors
System-Materials
Nanoarchitectonics
Editors
YutakaWakayama KatsuhikoAriga
NationalInstituteforMaterialsScience NationalInstituteforMaterialsScience
Tsukuba,Ibaraki,Japan Tsukuba,Ibaraki,Japan
ISSN2197-8891 ISSN2197-9502 (electronic)
NIMSMonographs
ISBN978-4-431-56911-4 ISBN978-4-431-56912-1 (eBook)
https://doi.org/10.1007/978-4-431-56912-1
©NationalInstituteforMaterialsScience,Japan2022
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Preface
Nanoarchitectonics is a new term for a new concept beyond nanotechnology. In
nanoarchitectonics,nanoscalematerialsareassembledinsystematicwaystogenerate
newfunctionalities,whichcannotbeattainedsolelybyeachmaterial.Thematerials
are well designed and synthesized. However, synergetic effects are key factors for
deviceperformanceratherthanthepropertiesofindividualmaterials.Thatis,each
materialworksasabuildingblockasamemberofananoscalearchitecture.Werefer
tosuchresearchconceptas“nanoarchitectonics.”
Toexplorethisnewresearchfield,theInternationalCenterforMaterialsNanoar-
chitectonics (WPI-MANA) was founded in 2007 as one of the first five research
centers within the framework of the World Premier International Research Center
Initiative (WPI), which is sponsored by Japan’s Ministry of Education, Culture,
Sports,ScienceandTechnology.Inthisproject,wehaveproducednanoscalecompo-
nentsandintegratedthemintovariousdimensionalsystemsthatexhibitcutting-edge
functions.Here,weexpectthattheseeffortswillleadtoscientificbreakthroughsand
technologicalinnovations.
Inthisbook,wepresentthestate-of-the-artachievements ofthematerialarchi-
tects in MANA, including supramolecules, one- or two-dimensionally controlled
semiconductors, optically and catalytically active nanomaterials, atomic switches,
and molecular assemblies for electronic applications. We hope that this book will
arouseafeelingofcuriosityandprovideanexcellentspringboardforyoungmaterials
scientistsinparticular.
Tsukuba,Japan YutakaWakayama
v
Contents
WhatisNanoarchitectonics?
WhatisNanoarchitectonics? ....................................... 3
KatsuhikoArigaandMasakazuAono
NanostructuredMaterialsandTheirConstruction
SynthesisofSemiconductorNanowires .............................. 9
KenC.PradelandNaokiFukata
NanoparticleBiomarkersAdaptedforNear-InfraredFluorescence
Imaging .......................................................... 27
NaotoShirahata
FrontiersinMesoscaleMaterialsDesign ............................. 51
YusukeIde,JoelHenzie,KenyaKani,andYusukeYamauchi
Wavelength-SelectivePhotothermalInfraredSensors ................. 71
TadaakiNagao, DaoDuyThang, DoanTungAnh, SatoshiIshii,
andToshihideNabatame
FunctionalMolecularLiquids ...................................... 93
EdwardA.NealandTakashiNakanishi
DevicesandComputationbyNanoarchitectonics
Ionic Nanoarchitectonics: Creation of Polymer-Based Atomic
SwitchandDecision-MakingDevice ................................. 113
KazuyaTerabe,TohruTsuruoka,andTakashiTsuchiya
Oxoporphyrinogens: Novel Dyes Based on the Fusion
ofCalix[4]pyrrole,QuinonoidsandPorphyrins ....................... 127
JonathanP.HillandJanLabuta
vii
viii Contents
GrowthandElectronicandOptoelectronicApplicationsofSurface
OxidesonAtomicallyThinWSe ................................... 149
2
MahitoYamamotoandKazuhitoTsukagoshi
Portable Toxic Gas Sensors Based on Functionalized Carbon
Nanotubes ........................................................ 161
ShinsukeIshihara
AdvancedNanomechanicalSensorforArtificialOlfactorySystem:
Membrane-TypeSurfaceStressSensor(MSS) ........................ 169
HuynhThienNgo,KosukeMinami,KotaShiba,andGenkiYoshikawa
QuantumMolecularDevicesTowardLarge-ScaleIntegration ......... 181
RyomaHayakawa,ToyohiroChikyow,andYutakaWakayama
EnergyandLifewithNanoarchiteconics
Nanostructured Bulk Thermoelectric Materials for Energy
Harvesting ........................................................ 199
ZihangLiuandTakaoMori
Artificial Photosynthesis: Fundamentals, Challenges,
andStrategies ..................................................... 233
DavinPhilo, HamzaEl-Hosainy, ShunqinLuo, HaoHuang,
FumihikoIchihara,andJinhuaYe
SmartPolymersforBiomedicalApplications ......................... 265
MitsuhiroEbara
GeometricalandMechanicalNanoarchitectonicsatInterfaces
BridgingMoleculeswithCellPhenotypes ............................ 275
JunNakanishiandShotaYamamoto
EmergingMethods
Electrical Measurement by Multiple-Probe Scanning Probe
Microscope ....................................................... 289
YoshitakaShingayaandTomonobuNakayama
Large-Scale First-Principles Calculation Technique
for Nanoarchitectonics: Local Orbital and Linear-Scaling
DFTMethodswiththeCONQUESTCode ........................... 303
TsuyoshiMiyazaki,AyakoNakata,andDavidR.Bowler
MachineLearningApproachesinNanoarchitectonics ................. 319
RyoTamuraandGakuImamura
Epilogue:Today’sNanotechnology,FutureNanoarchitectonics ........ 337
What is Nanoarchitectonics?
What is Nanoarchitectonics?
KatsuhikoArigaandMasakazuAono
1 InitiationofNanoarchitectonics
Thesedays,scientistsandengineersarerequestedtosolvemanyproblemsincluding
howtosaveresources,howtocreateenergy,howtoreduceemissions,howtoreduce
environmentalimpact,andhowtoefficientlyhandleinformation.Alltheseproblems
canbesolvedwithonecommonconcept,controlofNANOandtherelatedfunctional
structures. Developing functional materials and systems rationally fabricated with
nanoscalestructuralprecisioncansaveresources,createenergy,reduceemissions,
reduceenvironmentalimpact,andefficientlyhandleinformation.Inthecomingdays,
human society will be supported by science and technology capable of regulating
nanoscalestructures.Thecorrespondingmethodologystartedasnanotechnologyand
hasnowevolvedtonanoarchitectonics.
ItissaidthatthetermnanotechnologywasinitiallyproposedbyRichardFeynman,
whoforesawhugepossibilitiesforscienceandtechnologyinnanoscalespaces[1].
Thesocialimpactsofnanotechnologywereagainbroughtupinthe2001declaration,
the National Nanotechnology Initiative, made by the US president Bill Clinton, in
ordertopromotethenanotechnologicalapproachinindustrialdevelopments.Such
social and political flows have, of course, been supported by various innovations
in instrumental developments for nanoscale observation, such as the invention of
thescanningtunnelingmicroscope(STM)andotherscanningprobemicroscopes,as
wellasrapiddevelopmentsinmicro-andnanofabrication.Scientistsarenowcapable
ofdirectlywatchingandhandlingnanoscaleobjects.
B
K.Ariga( )·M.Aono
InternationalCenterforMaterialsNanoarchitectonics(WPI-MANA),NationalInstitutefor
MaterialsScience(NIMS),1–1Namiki,Tsukuba305-0044,Ibaraki,Japan
e-mail:[email protected]
K.Ariga
GraduateSchoolofFrontierSciences,TheUniversityofTokyo,5-1-5Kashiwanoha,Kashiwa
277-8561,Chiba,Japan
©NationalInstituteforMaterialsScience,Japan2022 3
Y.WakayamaandK.Ariga(eds.),System-MaterialsNanoarchitectonics,
NIMSMonographs,https://doi.org/10.1007/978-4-431-56912-1_1
