Surface Active Monomers: Synthesis, Properties, and Application

78 Pages·2014·1.846 MB·English

by  Mykola Borzenkov, Orest Hevus (auth.)

SPRINGER BRIEFS IN MATERIALS
Mykola Borzenkov
Orest Hevus
Surface Active
Monomers
Synthesis,
Properties, and
Application
123
SpringerBriefs in Materials
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Mykola Borzenkov · Orest Hevus
Surface Active Monomers
Synthesis, Properties, and Application
1 3
Mykola Borzenkov Orest Hevus
Department of Physics Department of Organic Chemistry
University of Milano-Bicocca Lviv Polytechnic National University
Milan Lviv
Italy Ukraine
ISSN 2192-1091 ISSN 2192-1105 (electronic)
ISBN 978-3-319-08445-9 ISBN 978-3-319-08446-6 (eBook)
DOI 10.1007/978-3-319-08446-6
Library of Congress Control Number: 2014942708
Springer Cham Heidelberg New York Dordrecht London
© The Author(s) 2014
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Preface
The chemistry of surface active monomers is developing very rapidly. Since the
first papers devoted to the synthesis and polymerization of surface active mono-
mers were published, numerous researches in this area have been performed.
Hence, many reviews highlighting various aspects in the area of surface active
monomers were published. The research group at the Department of Organic
Chemistry (Lviv Polytechnic National University, Ukraine) has developed its own
school dedicated to surface active monomers. In present overview, the most essen-
tial information about surface active monomers is summarized. Moreover, the
emphasis was made to application of surface active monomers and corresponding
surface active polymers for different needs of medicine and biology.
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Acknowledgments
Mykola Borzenkov would like to express his gratitude to head of the research
group at the Department of Organic Chemistry (Lviv Polytechnic National
University) Prof. O. Hevus for his invaluable guidance and support. He is very
grateful to Prof. O. Zaichenko and Dr. N. Mitina for their strong assistance and
support especially during the investigation of polymerizable properties of syn-
thesized surface active monomers and characterization of resulted polymers.
Mykola Borzenkov would like to thank all the current and former members of
research group Dr. L. Vuitsyk, Dr. N. Kinash, Dr. A. Kohut, Dr. R. Fleychuk, and
Z. Nadashkevich for their cooperation and assistance.
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Contents
1 Synthesis of Surface Active Monomers .......................... 1
1.1 Basic Concept of Surfmers ................................. 1
1.2 Synthesis of Maleic Surfmers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.3 Synthesis of Surface-Active Monomers Containing
Maleimide Fragment ..................................... 9
1.4 Synthesis of (Meth)acrylate Surface-Active Monomers .......... 11
1.5 Synthesis of Surface-Active Monomers Containing
Styrene Polymerizable Fragments ........................... 15
References .................................................. 16
2 Colloidal Properties of Surface Active Monomers ................. 23
2.1 Colloidal Properties of Surfactants ........................... 23
2.2 Fundamentals of Colloidal Chemistry of Surface-Active
Monomers .............................................. 24
2.3 Properties and Polymerization of Micelles, Vesicles,
Mesophases or Lyotropic Liquid Crystals, and Microemulsions .... 27
2.3.1 Micelles ......................................... 27
2.3.2 Vesicles and Bilayers ............................... 31
2.3.3 Lyotropic Liquid Crystals ............................ 33
2.3.4 Microemulsions ................................... 34
References .................................................. 35
3 Polymerization Behavior of Surface-Active Monomers ............ 39
3.1 Emulsion Polymerization .................................. 39
3.2 Polymerization in Microemulsion ........................... 43
3.3 Radical Polymerization and Atom Transfer
Radical Polymerization ................................... 44
3.4 Reversible Addition-Fragmentation Chain Transfer
Polymerization .......................................... 47
3.5 Synthesis of Polyelectrolyte Polymers ........................ 50
References .................................................. 51
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x Contents
4 Application of Surface Active Monomers and Polymers
Containing Links of Surface Active Monomers ................... 57
4.1 The Importance of Polymers of Biomedical Application .......... 57
4.2 The Application of Surfmers for Creating Materials
of Biomedical Application. A Brief Review of Publications ....... 59
References .................................................. 63
Conclusions ................................................... 67
About the Authors
Mykola Borzenkov received his Ph.D. in Organic Chemistry at Lviv Polytechnic
National University, Lviv, Ukraine. The Ph.D. thesis “Synthesis and properties of
surface active monomers based on derivatives of hydroxy and amino carboxylic
acids” were carried out under supervision of prof. Orest Hevus. At present time
M. Borzenkov is a research assistant at Department of Physics at University of
Milan-Bicocca (Milan, Italy). His main research fields are synthesis and application
of functional surface active monomers, synthesis, functionalization and biomedical
application of gold nanoparticles.
Orest Hevus is a professor of Organic Chemistry. From 1979 to the present he has
been working at Lviv Polytechnic National University. His research field is synthe-
sis of functional surface active peroxides and monomers.
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