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About SummaryNotes L7 PDF
This document outlines the grand canonical ensemble, which describes systems that can exchange both energy and particles with a heat bath. The probability of a system being in a microstate with energy E and particle number N is proportional to e^(-E/kT - μN/kT), where T is the temperature, k is Boltzmann's constant, and μ is the chemical potential. The grand partition function Z is analogous to the canonical partition function and relates the grand potential Φ to thermodynamic variables through Φ = -kTZ. This allows thermodynamic properties like entropy, pressure, and number of particles to be calculated from Z.
Detailed Information
| Author: | ['Ioana Pinzaru'] |
|---|---|
| Publication Year: | 2019 |
| Pages: | 3 |
| Language: | English |
| Format: | |
| Price: | FREE |
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