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About Summary FMCP: 1 Statistical Mechanics
1. Statistical mechanics uses partition functions (Q) to calculate the probability of systems occupying different energy states. Q gives the probability of molecules occupying single microstates. 2. The isothermal-isobaric ensemble accounts for constraints on both temperature and pressure, unlike the canonical ensemble which only considers temperature. 3. The rotational partition function depends on rotational constants that can be calculated based on molecular geometry and moments of inertia. 4. Mean energies of different modes like translation, rotation, and vibration can be calculated from partial derivatives of the partition function with respect to inverse temperature.
Detailed Information
| Author: | ['shreyash'] |
|---|---|
| Publication Year: | 2021 |
| Pages: | 17 |
| Language: | English |
| Format: | |
| Price: | FREE |
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