Table Of Contentiiv
PREFACE
The 42nd Yamada Conference on "Structure, Fluctuation, and
Relaxation in Solution" was held at Nagoya Trade and Industry
Center (Fukiage Hall), Nagoya, Japan from December 11 to
December 15, 1994. The meeting was attended by more than 110
scientists from nine countries.
During last four years(1990-1993) the special research project
"Molecular Approaches to Non-equilibrium Process in Solutions"
was carried out in Japan under the financial support of the Ministry
of Education of Science and Culture. After the successful ending of
this research project we have recognized that it is now our duty to
tackle the problems emerged form these resent results. These are
summarized as follows: (1) solvation dynamics, (2) Relaxation,
fluctuation, and reaction dynamics, and (3) dynamic structure and
reaction mechanisms in solutions. These topics are the main
concern of this conference.
In planning this conference with my colleagues of the organizing
committee, we have hoped that this conference be an opportunity
to find out a break-through in theories and experimental
techniques of the solution chemistry for the coming century. On
this intention the organizing committee has arranged the program
to be composed of as wide fields as possible. In addition, the
general discussion session was set after several presentations of the
related subjects.
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In this publication the order of the papers follows the program of
the Conference. This is because we would like the readers of this
Proceedings to understand our above-mentioned intention to open
this conference at this time as well as to feel the atmosphere of the
Conference.
This Conference could only be possible with the support of
Yamada Science Foundation in financial and moral aspects. His
support has led us to the success of this international meeting. All
the participants will never forget the generosity of Yamada Science
Foundation.
Finally, I would like to express my sincere thanks to all invited
speakers who gave excellent lectures, those who presented very
interesting posters, chairpersons and discussion leaders who
conducted the general discussion section in marvelous fashion, and
those who contributed to the vigorous discussion in the Conference.
I must add also my deep appreciation to the cooperation of all the
participants not only in the running of the Conference itself but also
in submitting and revising their manuscript for this Proceedings in
due time as requested by the organizing committee in spite of their
very heavy schedule.
The Organizing Committee of the 42nd Yamada Conference
Syflz6 SEKl(Advisory), Hitoshi OHTAKI(Advisory)
Hiroyasu NOMURA (Chairman), Fumio KAWAIZUMI (Secretary)
Shinobu KODA, Fumio HIRATA,
Masaharu NAKAHARA, Tadashi OKADA
Kiyoshi SAWADA, Toshio YAMAGUCHI
LIST OF PARTICIPANTS
Barnes, A. .C University of Bristol
Barthel, Josef University of Regensburg
Buchner, Michael University of Bielefeld
Burger, ni~ml~K A.Jozsef University
Button, Joanne Kyoto University
Chong, Song-Ho Kyoto University
Dore, John University of Kent at Canterbury
Elich, Karsten Osaka University
Espenson, James .H Iowa State University
Fujimura, Yuichi Tohoku University
Fujita, Yoshitaka National Research Laboratory of Metrology
Fushiki, Makoto National Institute of Materials and Chemical Research
Harada, Makoto Osaka University
Haymet, A.D.J. University of Sydney
Heinzinger, Karl Max-Planck Institute for Chemistry
Hiram, Fumio Kyoto University
Hiram, Yoshinori Osaka University
Hirota, Noboru Kyoto University
Hiwatari, Yasuaki Kanazawa University
Ibuki, Kazuyasu Doshisya University
Iida, Masayasu Nara Women's University
Ikawa, Shunichi Hokkaido University
Ikeuchi, Haruko Sophia University
Irisa, Masayuki ERATO JRDC
Itoh, Sumiko Cavendish Laboratory
Iwadate, Yasuhiko Chiba University
Iwata, Koichi Kanagawa Academy of Science and Technology
Kai, Yasunobu Osaka University
Kameda, Yasuo Yamagata University
Kaneko, Yutaka Kyoto University
Kanekubo, Mitsuhiro Sophia University
Kaneto, Hirotaka Kyoto Institute of Technology
,StaK Minoru Ritsumeikan University
Kato, Satoko Seibo Jogakuin .rJ College
Kawaizumi, Fumio Nagoya University
Kimum, Yoshifumi Kyoto University
Kinoshita, ihciuhS Osaka University
Kinugawa, ihcineK University of Osaka Prefecture
Kitazawa, Minoru Osaka University
Koda, Shinobu Nagoya University
Komatsuzaki, Tamiki Institute for Fundamental Chemistry
,aM Jangseok University of South Carolina
Maeda, Hiroshi Kyushu University
Maroncelli, Mark University of Pennsylvania
,adusaM Akiko Tokyo Institute of Technology
,adusaM Yuichi Ochanomizu Women's University
,agataM Noboru Insitute for Laser Technology
Matsumoto, Mitsuru Nagoya University
Matsuoka, Tatsuro Nagoya University
Matsuura, Hiroatsu Hiroshima University
Miyasaka, ihsoriH Kyoto Institute of Technology
,atiroM Akio University of Tokyo
,atakanuM Toyonori Kyoto University
,imakaruM Masataka Natinal Institute rof Physiological Science
Muranaka, isadaT Aichi Institute of Technology
Nagaoka, Masataka Institute for Fundamental Chemistry
,mahakaN Masaru Kyoto University
,iakaN Takehiro Ritsumeikan University
Nakanishi, Koichiro Kyoto University
Nakashima, Satoru Osaka University
Nomura, Hiroyasu Nagoya University
,ikathO Hitoshi Ritsumeikan University
Okada, Isao Tokyo Insitute of Technology
Okada, ihsadaT Osaka University
,ikazakO Susumu Tokyo Insitute of Technology
Okuyama, Naoto leciD Chemicals
Olsson, Lars-Fride Gambro BA
Ozutsumi, Kazuhiko University of Tsukuba
Radnai, Tamas Hungarian Academy of Science
Raineri, Fernando .O State University of New York
Rick, Steven Columbia University
Rossky, Peter .J University of Texas at Austin
,zecmfS Francisco Seville University
Sasaki, Yoichi Hokkaido University
Sato, Gen Sophia University
Sawada, Kiyoshi Niigata University
Seki, Kazuhiko National Institute of Materials and Chemical Research
Seki, Syflz6 The Japan Academy
,)xeS Yoshiteru Natinal Institute for Physiological Scicnce
Shushin, Anatoli .I Kyoto University
Suga, Hiroshi Kinki University
Sumi, Hitoshi University of Tsukuba
Suzuki, Satoshi University of Tokyo
Swaddle, Thomas .W University of Calgary
Tabata, Masaaki Saga University
Takagi, Hideo Nagoya University
Takasu, Masako Kanazawa University
Tanaka, Hideki Kyoto University
Tanaka, Motoharu Nagoya University
Tanida, Hajime Osaka University
Taniguchi, Yoshihiro Ritsumeikan University
Tarumi, Toshiyasu Nagoya University
Terazima, Masahide Kyoto University
Tominaga, Keisuke Institute for Molecular Science
Tominaga, Toshihiro Okayama University of Science
Tominaga, Yasunori Ochanomizu Women's University
Tran-Cong, Qui Kyoto Institute of Technology
Troe, Jurgen University of Gt)ttingen
Tsukahara, Keiichi Nara Women's University
,llarreV Ronaid .E University of Saskatoon
Watanabe, Iwao Osaka University
Weing~rtner, Hermann University of Karlsruhe
Yamabe, Tokio Kyoto University
Yamada, Shinkichi Shizuoka University
Yamaguchi, Toshio Fukuoka University
Yamatera, Hideo Daido Institute of Technology
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Y ano, Y os ih ko Tokyo National College of Technology
Yasuoka, Kenji Nagoya University
Yokoyama, Haruhiko Yokohama City University
Yoshida, Naoto Institute for Fundamental Chemistry
Yoshiham, Keitaro Institute for Molecular Science
Yoshimori, Akim Nagoya University
iiix
Welcome Address
December 14,1994
Good Evening, Ladies and Gentlemen!
It is my great honor and pleasure to extend the most cordial welcome address
to all the participants of this meeting, the 42nd Yamada Conference on "Structure,
Fluctuation and Relaxation in Solutions". In particular my special gratitude must
go to those who traveled long distances to here from overseas; Australia, Canada,
Germany, Hungary, Russia, Spain, Sweden, United Kingdom and United States of
America.
On behalf of Yamada Science Foundation we are very happy and privileged to
sponsor the present Conference. Yamada Science Foundation was established in
1977 as a result of the donation of the private holding of the late Kiro Yamada who
was the former President of Rhoto Pharmaceutical Company in Osaka. Mr. Yamada
recognized that creative basic research in Natural Science is indispensable for the
welfare and prosperity of mankind. Hence, the Foundation has been supporting
innovative research project in physics, chemistry and biology, assisting the
international exchange of scientists and also the international conference called
Yamada Conference with full financial support, two times every year recently. We
are convinced that all the past conferences have been rewarding, stimulating and
successful.
Unfortunately I could not give a welcome address at the opening session, the day
before yesterday, clue to inevitable circumstances. This evening, however, I am
very happy to be here with all the participants.
Incidentally, I had been an experimental physical chemist in the field of
structural chemical thermodynamics and working, for a long time on phase
transitions in the solid by main use of calorimetry. Although I am not the specialist
in the field of Solution Chemistry discussed in the present conference, I am very
much convinced that the selected subjects of "Structure, Fluctuation and Relaxation
xiv
in Solutions" are one of the most fundamental, fascinating and frontier topics for
the essential progress of liquid and solution science which is associated with physics,
chemistry and also biology interdisciprinarily. This is just in accordance with the
original aim of Yamada Conference.
I hear from Professor Ohtaki and Professor Nomura that the Conference si
going in quite an active and marvelous fashion up to now. I do hope such a
wonderful situation will continue and that Ha the participants will enjoy a friendly
and free contact to cherish mutual friendship with each other and have successful
final results for the conference.
Last but not least, I would like to express my thanks to the member of the
organizing committee, particularly to Professor Nomura, who have made excellent
arrangements for the success of the Conference.
Thank you for your attention. ~ ~
Syuzo Seki
Director General of
Yamada Science Foundation
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YAMADA SCIENCE FOUNDATION
AND
THE SCOPE OF YAMADA CONFERENCE
Yamada Science Foundation was established in February 1977 in Osaka through the
generosity of Mr. Kiro Yamada. Mr. Yamada was President of Rohto Pharmaceutical
Company, Limited, a well-known manufacturer of medicines in Japan. He recognized
that creative, unconstrained, basic research is indispensable for the future welfare and
~p
spenty of mankind and he has been deeply concerned with its promotion.
erefore, funds for this Foundation were donated from his private holdings.
The principal activity of the Yamada Science Foundation is to offer financial
assistance to creative research in the basic natural sciences, particularly in
!nterdisciplinary domains that brid e established fields. Projects which ...etomorp
international cooperation are also ~avored. By assisting the exchange of vmmng
scientists and encouraging international meetings, this Foundation intends to greatly
further the progress of science in the global environment.
nI this context, Yamada Science Foundation sponsors international Yamada
Conferences once or twice a year in Japan. Subjects to be selected by the Foundation
should be most timely and stimulating. These conferences are expected ot be of the
highest international standard so as to significantly foster advances in their respective
fields.
ivx
Executive Members of Foundation
Officers:
Board of Directors
Leo iKASE
Kenichi IUKUF
Osamu IHSIAYAH
Junjiro IROMANAK
Kiyoshi tMAG-FS Standing Director
6zOyS IKES Director General
metuo ABIHS
Tomoji IKUZUS
Ikuo iHCUEKAT
Yasusada ADAMAY
Auditors
Seturo !HSABE
Hisaya ARAN
Advisors:
Nobur6 AYIMAK
Takeo AYIMAGAN
Shuntaro AWAGO
