Spectroscopic properties of inorganic and organometallic compounds : Volume 23.

514 Pages·2007·23.436 MB·English

by  G Davidson, E A V Ebsworth

Spectroscopic Properties of
Inorganic and Organometallic
Comp oun ds
Volume 23

A Specialist Periodical Report
Spectroscopic Properties of
Inorganic and Organometallic
Compounds
Volume 23
A Review of the Recent Literature Published
up to Late 1989
Senior Reporters
G. Davidson, Department of Chemistry, University of
Nottingham
E. A. V. Ebsworth, F.R.S.E., Department of Chemistry,
University of Edinburgh
Reporters
J. H. Carpenter, University of Newcastle upon Tyne
S. J. Clark, City University, London
K. B. Dillon, University of Durham
J. D. Donaldson, City University, London
S. M. Grimes, City University, London
6. E. Mann, University of Sheffield
D. W. H. Rankin, University of Edinburgh
H. E. Robertson, University of Edinburgh
M. J. K. Thomas, Thames Polytechnic, London
SOCIETYOF
HE M IS T RY
ISBN 0-85186-213-6
ISSN 0584-8555
Published by The Royal Society of Chemistry,
Thomas Graham House, The Science Park, Cambridge CB4 4WF
Copyright 0 1990
The Royal Society of Chemistry
All Rights Reserved
No part of this book may be reproduced or transmitted in any form or by any
means-graphic, electronic, including photocopying, recording, taping, or
information storage and retrieval systems-without written permission from The
Royal Society of Chemistry
Printed and bound by Bookcraft (Bath) Ltd.
Preface
There are no substantial changes in this year's volume. The
topics covered are the same as in recent years, and the Reporters
have as always done wonders in covering so much material in so
compressed a way. I am sorry that Dr. S. Cradock can no longer
contribute the chapter on Microwave Spectroscopy, for he has been
a most efficient and reliable colleague, but I am very grateful
indeed to Dr. Carpenter for taking over from him so well.
This is the last volume for which I shall act as Senior
Reporter; from next year Dr. G. Davidson will be in sole charge.
I have overseen the production of fourteen volumes in the series.
I believe that these reviews, so well established by my
predecessor, Professor N.N. Greenwood, are valuable to the
community of inorganic chemists; I certainly use them, and I am
delighted to see how they have continued despite uncertainties
from one year to another. In the long term, the future of such
publications as these will depend on developments in the form of
scientific literature and on the impact of developing technology
on the retrieval of information; for the present, I only wish
that the price could be lower. I have enjoyed working with the
Reporters and the staff of the Royal Society of Chemistry, and I
wish the series well.
E.A.V. Ebsworth
August 1990

Contents
Chapter 1 Nuclear Magnetic Resonance Spectroscopy 1
By B.E. Mann
1 Introduction 1
2 Stereochemistry 2
Complexes of Groups IA and IIA 2
Complexes of Groups IIIA and IVA, the
Lanthanides and Actinides 5
Complexes of V, Nb, and Ta 10
Complexes of Cr, Mo, and W 11
Complexes of Mn, Tc, and Re 23
Complexes of Fe, Ru, and 0s 26
Complexes of Co, Rh, and Ir 38
Complexes of Ni, Pd, and Pt 45
Complexes of Cu, Ag, and Au 52
Complexes of Zn, Cd, and Hg 53
3 Dynamic Systems 55
Fluxional Molecules 56
Lithium 56
Sodium 56
Beryl 1i um 56
Calcium, Strontium, Barium,
and Lanthanum 56
Yttrium 56
The Lanthanides 56
Thorium 56
Titanium, Zirconium, and Hafnium 57
Vanadium 57
Niobium and Tantalum 58
Chromium, Molybdenum, and Tungsten 58
Many ane se 61
Rhenium 61
Iron and Ruthenium 62
Osmium 64
Cobalt 64
Rhodium and Iridium 65
Nickel 66
Palladium and Platinum 67
Copper 69
Cadmium 69
Mercury 69
Boron 69
A1 uminiu m 70
Indium 70
Thal 1i um 70
Silicon, Germanium, Tin, and Lead 70
Nitrogen 72
Phosphorus 72
viii Contents
Selenium 72
Tellurium 72
Equilibria 73
Solvation Studies of Ions 73
Group 1A 73
Magnesium 73
Yttrium 73
Lanthanum 74
Chromium 74
Molybdenum 74
Manganese 74
Cobalt 74
Nickel 74
Palladium 75
P1a ti num 75
Zinc 75
Aluminium 75
Gal1 i um 75
Silicon, Germanium, and Tin 75
Nitrogen 75
Ionic Equilibria 75
Group 1A 76
Group IIA 79
Scandium 80
The Lanthanides 80
Titanium 81
Zirconium 81
Vanadium 81
Niobium and Tantalum 81
Chromium 81
Molybdenum 82
Tungsten 82
Manganese 82
Iron 82
Ruthenium 82
Cobalt 82
Rhodium 83
Nickel, Palladium, and Platinum 83
Copper 83
Silver 84
Gold 84
Zinc 84
Cadmium 85
Mercury 85
Boron 85
Aluminium and Gallium 85
Thalli um 86
Si 1i con 86
Germanium 87
Tin a7
Lead 87
Nitrogen 87
Phosphorus 87
Arsenic 87
Tellurium 87
Chlorine 88
Equilibria among Uncharged Species 88
Lithium 88
Europium 88
Uranium 88
Titanium 88
Zirconium and Hafnium 88
Chromium 88
Molybdenum 89