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Proceedings of the 13th Asian Conference on
IonIcs for sustaInable World
Sendai, Japan 17 – 20 July 2012
Editors
B V R Chowdari
National University of Singapore, Singapore
J Kawamura
J Mizusaki
K Amezawa
Tohoku University, Japan
World Scientific
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British Library Cataloguing-in-Publication Data
A catalogue record for this book is available from the British Library.
SOLID STATE IONICS
Ionics for Sustainable World
Proceedings of the 13th Asian Conference
Copyright © 2013 by World Scientific Publishing Co. Pte. Ltd.
All rights reserved. This book, or parts thereof, may not be reproduced in any form or by any means,
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ISBN 978-981-4439-90-9
Printed in Singapore.
Rhaimie - Solid State Ionics (Procs---Book).pmd1 9/3/2012, 10:56 AM
iii
PREFACE
Solid state ionics is a multidisciplinary scientific field to deal with ionic
transport in a variety of solids including ceramics, glasses, polymers,
composites, nano-scale materials, and biomaterials. In a couple of decades, solid
state ionics grew up to one of the most attractive scientific fields because of its
useful technological applications such as batteries, fuel cells, sensors, solar
cells, capacitors, and electrochromic displays. So far, a large number of
scientists and engineers in all over the world are engaged in the research in solid
state ionics. Their missions will become increasingly important in future to
satisfy social needs solving energy issue and achieving environmental
sustainability.
Historically, Asia has taken an indispensable role for the developments of
solid state ionics. The term of “solid state ionics” was originally established by a
Japanese professor, Takehiko Takahashi, in 1970s. The Asian Society for Solid
State Ionics was founded in 1986. A series of the academic conference has been
biennially held since 1988, in order to enhance the scientific level and to
promote friendship and collaboration between the researchers in the Asian
society. The present conference is the 13th conference in the series, and held in
Japan for the first time.
The conference venue Sendai is known as the city where was seriously
damaged by the large earthquake and the subsequent Tsunami on 11 March
2011. The city is still under reconstruction even one year after the horrible
disasters. Our cordial thanks are devoted to all the participants in the conference
for their kind participations in spite of such a situation.
The 13th Asian Conference on Solid State Ionics covers all the practical,
fundamental, conventional, and groundbreaking aspects of solid state ionics for
establishing a sustainable world. We hope the conference will be a milestone
toward achieving reconstruction of our mother earth from environmental
destruction as well as of Sendai city from earthquake damages. This
proceedings book contains research papers on the latest developments and
findings in solid state ionics, which are presented at the conference. We express
gratitude to the authors for submitting the manuscripts before the deadline and
to the publishers for supplying this proceedings book in time for the conference.
We are also thankful to the sponsors for their interests in the conference.
Last, but not least, we are grateful to the members of the International, the
Domestic and the Local Organizing Committees for their untiring efforts in
making the conference successful.
7 May 2012 Editors
iv
ORGANIZATION
Organizers
Asian Society for Solid State Ionics
IMRAM, Tohoku University
The Solid State Ionics Society of Japan
Conference Chairs
Prof. Junichi Kawamura IMRAM, Tohoku University
Prof. Junichiro Mizusaki IMRAM, Tohoku University
International Organizing Committee
Prof. Stefan Adams National University of Singapore, Singapore
Prof. B.V.R. Chowdari National University of Singapore, Singapore
Prof. M.A.K.L. Dissanayake University of Peradeniya, Sri Lanka
Prof. Liu Hanxing Wuhan University & Technology, China
Prof. Xuejie Huang Center for Clean Energy, Institute of Physics,
CAS, China
Prof. Evvy Kartini National Nuclear Energy Agency, Indonesia
Prof. Ajit Kulkarni Indian Institute of Technology Bombay, India
Prof. Jong-Sook Lee Chonnam National University, Korea
Prof. S.R.S. Prabaharan Manipal International University, Malaysia
Prof. S. Selvasekarapandian Kalasaringam University, India
Prof. V.A. Seneviratne University of Peradeniya, Sri Lanka
Prof. Zhaoyin Wen Shanghai Institute of Ceramics, CAS, China
Prof. Han-Ill Yoo Seoul National University, Korea
Domestic Organizing Committee
Prof. Masaru Aniya Grad. Sch. of Sci. and Tech., Kumamoto University
Prof. Ryoji Kanno Grad. Sch. of Eng., Tokyo Institute of Technology
Prof. Junichi Kawamura IMRAM, Tohoku University
Dr. Tetsuro Kobayashi Toyota Central R&D Labs. Inc.
Prof. Junichiro Mizusaki IMRAM, Tohoku University
Prof. Takashi Sakuma Grad. Sch. of Sci. and Eng., Ibaraki University
v
Dr. Kazunori Takada National Institute for Materials Science (NIMS)
Prof. Masahiro Tatsumisago Grad. Sch. of Eng., Osaka Prefecture University
Prof. Masayoshi Watanabe Grad. Sch. of Eng., Yokohama National University
Prof. Shu Yamaguchi Grad. Sch. of Eng., The University of Tokyo
Local Organizing Committee
Prof. Koji Amezawa IMRAM, Tohoku University
Prof. Masatoshi Arai Japan Proton Accelerator Research Complex
(JPARC)
Prof. Shinichi Hashimoto Grad. Sch. of Envi. Stud., Tohoku University
Prof. Itaru Honma IMRAM, Tohoku University
Prof. Fumitada Iguchi Grad. Sch. of Eng., Tohoku University
Prof. Tamio Ikeshoji IMR, Tohoku University
Dr. Yoshiki Iwai IMRAM, Tohoku University
Prof. Tatsuya Kawada Grad. Sch. of Envi. Stud., Tohoku University
Prof. Naoaki Kuwata IMRAM, Tohoku University
Prof. Hideki Maekawa Grad. Sch. of Eng., Tohoku University
Prof. Shinichi Orimo IMR, Tohoku University
Prof. Noriko Sata Grad. Sch. of Eng., Tohoku University
Prof. Kazuhisa Sato Grad. Sch. of Eng., Tohoku University
Prof. Hitoshi Takamura Grad. Sch. of Eng., Tohoku University
Dr. Reiji Takekawa IMRAM, Tohoku University
Prof. Atsushi Unemoto IMRAM, Tohoku University
Prof. Takeshi Usuki Grad. Sch. of Sci. and Eng., Yamagata University
Prof. Keiji Yashiro IMRAM, Tohoku University
Prof. Hiroo Yugami Grad. Sch. of Eng., Tohoku University
Local staff
Katsuko Abe IMRAM, Tohoku University
Yoko Arai IMRAM, Tohoku University
Yuki Chiba IMRAM, Tohoku University
Emi Hashimoto IMRAM, Tohoku University
Sayuri Hayasaka IMRAM, Tohoku University
Dr. Hellar Nithya IMRAM, Tohoku University
Dr. Jeyapandian Malathi IMRAM, Tohoku University
Yasutaka Matsuda IMRAM, Tohoku University
Hiroe Shoji IMRAM, Tohoku University
vi
Sponsored By
Asian Society for Solid State Ionics
The Solid State Ionics Society of Japan
IMRAM, Tohoku University
Sendai Tourism & Convention Bureau (STCB)
Aoba Foundation for The Promotion of Engineering
Res. Cen. for Sustainable Sci. & Eng., IMRAM, Tohoku University
Nano-Macro Materials, Devices and System Research Alliance
The SOFC Society of Japan
The Committee of Battery Technology, The Electrochemical Society of Japan
vii
Wednesday, 18 July
Plenary Talk
9:00- 9:30 Opening Session
9:30-10:20 SOLID STATE IONIC MATERIALS: PAST, PRESENT & FUTURE
PL-1 B. V. R. Chowdari
10:20-10:35 Coffee break
10:35-11:25 EXCHANGE AND INTERCALATION REACTION FROM SODIUM BASED AxMO2 LAYERED OXIDES
PL-2 C. Delmas, R. Berthelot, D. Carlier, M. Pollet, C. Didier, M. Guignard, J. Darriet and F. Weill
11:25-12:15 HIGH POWER DENSITY SOLID OXIDE FUEL CELLS USING LaGaO3 PEROSKITE OXIDE THIN
PL-3 FILM PREPARED BY PLD METHOD
Tatsumi Ishihara 21
12:15-13:45 Lunch
Session A
Solid Electrolytes
13:45-14:10 WATER STABLE LITHIUM ION CONDUCTING SOLID ELECTROLYTE FOR LITHIUM-AIR
Inv-A1 RECHARGEABEL BATTERY
O. Yamamoto, N. Imanishi, Y. Takeda, K. Ishiguro, Y. Nakata, Y. Takahashi, and M. Zhang
14:10-14:25 CORRELATION BETWEEN ELECTRICAL CONDUCTIVITY AND GLASS TRANSITION
Oral-A1 TEMPERATURE OF Li2O:B2O3:SiO2:TiO2:Li2SO4 GLASSES
A. V. Deshpande, N. S. Satpute 33
14:25-14:40 INTERFACE RESISTANCE AT THE SINGLE GRAIN BOUNDARY OF LiCoO2 EPITAXIAL THIN
Oral-A2 FILMS
A. Kumatani, T. Ohsawa, T. Suzuki, Y. Takagi, S. Shiraki, H. Oki, H. Moriwake, Y. Ikuhara,
T. Hitosugi
14:40-14:55 STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF LAYERED STRUCTURE
Oral-A3 La2Li2x(CO)1-xO4
Muhammad Iqbal, Genki Kobayashi, Masaaki Hirayama, Ryoji Kanno 41
14:55-15:10 GEL MEMBRANE AS A KEY CHOICE TO ENSURE THE SAFETY PROBLEM OF LITHIUM ION
Oral-A4 BATTERIES FOR ELECTRIC VEHICLES
Y. S. Zhu, Y. Y. Hou, X. J. Hou, Y. P. Wu
15:10-15:30 Coffee break
SE calculations
15:30-15:55 STRUCTURE – CONDUCTIVITY CORRELATIONS IN BATTERY MATERIALS
Inv-A2 S. Adams 76
15:55-16:10 FIRST PRINCIPLES CALCULATION OF ELECTRONIC STRUCTURES AND THEORETICAL
Oral-A5 POTENTIALS OF SPINEL LiNi0.5Mn1.5O4
A. Kuwabara, C. A. J. Fisher, Y. H. Ikuhara, H. Moriwake, Y. Ikuhara, H. Oki
16:10-16:25 VARIATION OF IONIC CODUCTIVITY WITH ANNEALING TEMPERATURE IN ARGYRODITE
Oral-A6 SOLID ELECTROLYTES
R. Prasada Rao, Chen Maohua, S. Adams 3
16:25-16:40 THEORETICAL AND EXPERIMENTAL STUDIES OF CONDUCTION PATHWAYS IN IONIC
Oral-A7 CONDUCTORS
Max Avdeev, Matthew Sale
16:40-16:55 FAST Li-ION CONDUCTOR: HOW THE IONS MOVE IN SOLID ELECTROLYTE LiBH4
Oral-A8 Tamio Ikeshoji, Eiji Tsuchida, Tetsuya Morishita, Kazutaka Ikeda, Motoaki Matsuo,
Yoshiyuki Kawazoe, and Shin-ichi Orimo
17:00-19:00
Poster session
Poster
