Table Of ContentGangfeng Ouyang · Ruifen Jiang E ditors
Solid Phase
Microextraction
Recent Developments and Applications
Solid Phase Microextraction
Gangfeng Ouyang Ruifen Jiang
(cid:129)
Editors
Solid Phase Microextraction
Recent Developments and Applications
123
Editors
Gangfeng Ouyang RuifenJiang
Schoolof Chemistry Schoolof Environment
SunYat-sen University Jinan University
Guangzhou, Guangdong Guangzhou, Guangdong
China China
ISBN978-3-662-53596-7 ISBN978-3-662-53598-1 (eBook)
DOI 10.1007/978-3-662-53598-1
LibraryofCongressControlNumber:2016953638
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Preface
Solid-phase microextraction (SPME) is a sample preparation technique introduced
by Dr. Janusz Pawliszyn, professor of University of Waterloo, in 1990. Compared
with traditional sample preparation techniques, SPME combines sampling,
enrichment, separation, and introduction into one step and becomes a simple, fast,
efficient, and green sample preparation technique. Since its inception, SPME has
been widely used in environmental, pharmaceutical, food, and aroma analyses, as
well as the studies of chemistry, materials, biology, medicine, etc. In recent
10 years, the hot research areas of SPME include developing novel fiber coatings
based on nano or porous materials, detecting free concentration of analyte in
complex sample matrices, and nondestructive sampling of living systems using
invivoSPME.ThepurposeofthisbookistosummarizetheapplicationsofSPME
in recent years.
In this book, 10 representative chapters cover the recent development of SPME
in coating preparation, environmental analysis, in vivo sampling, etc. Chapter 1
briefly introduces the fundamental knowledge of SPMEtechnique. In Chap. 2, the
progresses of the new SPME coating preparation in recent years are summarized.
Then, from Chaps. 3 to 7, the applications of SPME for environmental samples,
including aerosol particulate in air, complex water sample, and soil/sediment, are
reviewed. The main feature of SPME for sensing the freely dissolved organic
compounds in complex environmental samples using active and passive SPME
sampler is highlighted in these chapters. In addition, SPME combined with
derivatization techniques to overcome the challenge of polar compounds' analysis
in environmental samples is also summarized and discussed. In the last three
chapters,themostdistinguishedapplicationofinvivoSPMEtechniqueisreviewed
and discussed, including tracing volatile organic compounds' emission from plant
and analyzing the metabolites of pharmaceuticals.
v
vi Preface
I believe this book will be useful to the researchers in the fields of chemistry,
materials, environment, etc., especially who are doing works relative to SPME as
well asthenewcomerswhowanttoemploytheSPMEtechniques. Iamespecially
grateful to the authors and my colleagues. This book cannot be done without their
outstanding contributions.
Guangzhou, China Gangfeng Ouyang
Ruifen Jiang
Contents
1 Introduction of Solid-Phase Microextraction.. .... .... ..... .... 1
Shuqin Liu and Gangfeng Ouyang
2 Development of Novel Solid-Phase Microextraction Fibers ... .... 17
Jianqiao Xu and Gangfeng Ouyang
3 Application of Solid-Phase Microextraction in Gas Sampling . .... 63
Xiang Li
4 Solid Phase Microextraction for Sensing Freely Dissolved
Analytes in Complex Water Sample .... .... .... .... ..... .... 75
Ruifen Jiang, Jianqiao Xu and Gangfeng Ouyang
5 Application of Solid Phase Microextraction
in Aqueous Sampling ... ..... .... .... .... .... .... ..... .... 113
Siming Huang, Juan Zheng and Gangfeng Ouyang
6 Application of Solid-Phase Microextraction in Soil
and Sediment Sampling . ..... .... .... .... .... .... ..... .... 141
Ruifen Jiang and Gangfeng Ouyang
7 Application of Solid-Phase Microextraction Combined
with Derivatization for Polar Compound Sampling
in Environmental Analysis .... .... .... .... .... .... ..... .... 177
Lihua Yang and Tiangang Luan
8 Application of Solid Phase Microextraction in Food
Analysis—Flavor and Off-Flavor Sampling... .... .... ..... .... 223
Henryk Jeleń, Małgorzata Majcher and Anna Gracka
vii
viii Contents
9 Applications of In Vivo and In Vitro Solid-Phase
Microextraction Techniques in Plant Analysis .... .... ..... .... 247
Fang Zhu and Guosheng Chen
10 Solid-Phase Microextraction in Binding Studies... .... ..... .... 287
Dajana Vuckovic
Contributors
Guosheng Chen MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, China
Anna Gracka Faculty of Food Science and Nutrition, Poznań University of Life
Sciences, Poznań, Poland
Siming Huang MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, People’s Republic of China
Henryk Jeleń Faculty of Food Science and Nutrition, Poznań University of Life
Sciences, Poznań, Poland
Ruifen Jiang School of Environment, Guangzhou Key Laboratory of
Environmental Exposure and Health, and Guangdong Key Laboratory of
Environmental Pollution and Health, Jinan University, Guangzhou, People’s
Republic of China
Xiang Li Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention(LAP3),DepartmentofEnvironmentalScienceandEngineering,Fudan
University, Shanghai, China
Shuqin Liu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, People’s Republic of China
Tiangang Luan MOE Key Laboratory of Aquatic Product Safety, School of
Marine Sciences, Sun Yat-Sen University, Guangzhou, China
Małgorzata Majcher Faculty of Food Science and Nutrition, Poznań University
of Life Sciences, Poznań, Poland
ix
x Contributors
Gangfeng Ouyang MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, People’s Republic of China
Dajana Vuckovic Department of Chemistry and Biochemistry and PERFORM
Centre, Concordia University, Montreal, Canada
Jianqiao Xu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, China
Lihua Yang MOE Key Laboratory of Aquatic Product Safety, School of Marine
Sciences, Sun Yat-Sen University, Guangzhou, China
Juan Zheng MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, PR, China
Fang Zhu MOE Key Laboratory of Aquatic Product Safety/KLGHEI of
EnvironmentandEnergyChemistry,SchoolofChemistry,SunYat-SenUniversity,
Guangzhou, China
