Table Of Content2 Hel 10 Ne I 18 Ar I 36 Kr I 54 Xe I 86 Rn I H.'31
~
I
2 5 6 7 8 a
I H 9 F 17 CI 35 Br 53 I 85 8At
8 o 3 16 S 9 34 Se 10 52 Te II 84 Pl2 o 71 Lu 03 Lr 71
1
7 N 4 15 P 16 33 As 17 51 Sb 18 83 Bi 19 70 Yb 102 No 71
bers ! ! I 6 5 B 13 C 14 13 14 Ala5 Si 15 31 32 36 45 GaGe 49 50 In 37 S046 81 82 TI38 Pb 47 68 69 Er Tm 100 101 Fm 71 Md 71
n System Num , I I I I I I I I I I I I I I 29 30 Cu 60 Zn 32 47 48 Ag 61 Cd 33 79 80 H34 gAu 62 66 67 Dy Ho 98 99 Cf 71 Es 71
meli 57 65 68 71
e G 28 Ni 46 Pd 78 Pt 65 Tb 97 Bk
with th 27 Co 58 45 64 Rh 77 Ir 67 64 Gd 96 71 Cm
ments 26 Fe 59 44 Ru 63 76 Os 66 63 Eu 95 Am7!
the Ele i i 25 56 Mn 43 Te 69 75 Re 70 62 Sm 94 Pu 71
of
Table 24 Cr 52 42 M53 0 74 W 54 61 Pm 93 Np 71
eriodic I 23 V 48 41 49 Nb 73 50 Ta 105 71 60 Nd 92 U 55
P
22 Ti 41 40 Zr 42 72 43 Hf 104 71 59 Pr 91 Pa 51
21 Se 39 39 Y 39 57** La 39 89*** 40 Ac 58 Ce 90 Th44
26 27 28 29 30 31 es 9 s
4 Be 12 Mg 20 Ca 38 Sr 56 Ba 88 Ra an id 3 nide
I H 2 3 li 20 II 21 Na 19 * K 22 37 24 Rb 55 Cs 25 87 Fr25a *Lanth <**Acti
* 1
I
~ l ... co =t-O> CO) t :ii' j 3 iii' .., c' !ll g =t-O> i c: ... 0> '" ,.. n n co '" ~
Gmelin Handbook of Inorganic Chemistry
8th Edition
Gmelin Handbook
of Inorganic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, vollig neu bearbeitete Auflage
Prepared Gmelin-Institut fUr Anorganische Chemie
and issued by der Max-PLanck-Gesellschaft
zur Forderung der Wissenschaften
Director: Ekkehard FLuck
Founded by Leopold Gmelin
8th Edition 8th Edition begun under the auspices of the
Deutsche Chemische GeseUschaft by R. J. Meyer
Continued by E. H. E. Pietsch and A. Kotowski, and by
Margot Becke-Goehring
Springer-Verlag Berlin Heidelberg GmbH 1989
Gmelin-Institut fOr Anorganische Chemie
der Max-Planck-Gesellschaft zur Forderung der Wissenschaften
ADVISORY BOARD
Dr. G. Breil, Chairman (Ruhrchemie AG, Oberhausen-Holten), Prof. Dr. K. Dehnicke (Philipps
Universitat, Marburg), Prof. Dr. N. N. Greenwood (University of Leeds), Prof. Dr. H. Grunewald
(Bayer AG, Leverkusen), Prof. Dr. H. Harnisch (Hoechst AG, Frankfurt/Main-Hochst), Prof. Dr.
H. Noth (Universitat Munchen), Prof. Dr. H. Offermanns (Degussa AG, Frankfurt/Main), Prof.
Dr. G. zu Putlitz (Universitat Heidelberg), Prof. Dr. A. Rabenau (Max-Planck-Institut fOr Fest
korperforschung, Stuttgart), Prof. Dr. A. Simon (Max-Planck-Institut fur Festkorperforschung,
Stuttgart), Prof. Dr. Dr. A. H. Staab (Prasident der Max-Planck-Gesellschaft, Munchen), Prof.
Dr. Dr. h.c. mult. G. Wilke (Max-Planck-Institut fOr Kohlenforschung, MUlheim/Ruhr)
DIRECTOR DEPUTY DIRECTOR
Prof. Dr. Dr. h. c. Ekkehard Fluck Dr. W. Lippert
CHIEF EDITORS
Dr. K.-C. Buschbeck - Dr. H. Bergmann, J. Fussel, H. Hartwig, Dr. H. Katscher, Dr. R. Keim,
Dr. E. Koch, Dipl.-Phys. D. Koschel, Dr. U. Kruerke, Dr. P. Merlet, Dr. E. Schleitzer-Rust,
Dr. F. A. Schroder, Dr. A. Slawisch, Dr. W. Topper
CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. B. Baker, Dr. P. L. Bayless,
Dr. V. Haase, Dr. E. F. Hockings,
Dipl.-Ing. G. Kirschstein,
Dr. W. F. McNamara, Dr. K. Rumpf
EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E. h. Margot Becke
CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Hans Bock
Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.)
STAFF GMELIN HANDBOOK
Dr. G. Bar, Dr. R. Baier, D. Barthel, Dr. N. Baumann, Dr. B. Becker, Dr. W. Behrendt, D. Benzaid,
Dr. L. Berg, Dipl.-Chem. E. Best, Dr. R. Bohrer, K. D. Bonn, P. Born-Heck, Dipl.-Phys. R. Bost,
Dr. A. Brandl, Dr. R. Braun, Dipl.-Ing. V. A. Chavizon, E. Cloos, Dipl.-Phys. G. Czack, I. Deim,
Dipl.-Chem. H. Demmer, U. Dietz, Dipl.-Geol. R. Ditz, R. Dowideit, Dipl.-Chem. M. DroBmar,
U. Duggen, Dipl.-Chem. R. Durban, M. Engels, Dr. H.-J. Fachmann, Dr. J. Faust, B. Fischer,
G. Funk, Dipl.-Ing. N. Gagel, Dr. D. Germeshausen, Dr. U. W. Gerwarth, Dipl.-Phys. D. Gras,
Dipl.-Bibl. W. Grieser, Dr. I. Haas, Dr. R. Haubold, B. Heibel, Dipl.-Min. H. Hein, A. Heise
Schuster, H.-P. Hente, H. W. Herold, U. Hettwer, Dr. R. Heumuller, Dr. G. Hones, Dr. W. Hoff
mann, Dr. W. Huisl, B. Jaeger, R. Jonuschat, Dr. R. Jotter, Dr. J. von Jouanne, Dr. B. Kalbskopf,
Dipl.-Chem. W. Karl, H.-G. Karrenberg, Dipl.-Phys. H. Keller-Rudek, B. Kirchner, P. Klauck,
A. Klusch, Dipl.-Chem. C. Koeppel, Dipl.-Chem. H. Kottelwesch, R. Kolb, Dr. M. Kotowsky,
E. Kranz, Dipl.-Chem. I. Kreuzbichler, Dr. A. Kubny, Dr. M. Kunz, Dr. W. Kurtz, M. Langer, Dr.
U. Lanzendorfer, Dr. B. Leduc, Dr. A. Leonard, H. Mathis, E. Meinhard, C. Metz, K. Meyer, Dr.
M. Mirbach, Dipl.-Chem. B. Mohsin, Dr. U. Neu-Becker, K. Noring, Dipl.-Chem. R. Nohl, Dipl.
Min. U. Nohl, Dr. U. Ohms-Bredemann, Dr. W. Petz, I. Rangnow, Dr. B. Rempfer, Dipl.-Phys.
H.-J. Richter-Ditten, Dipl.-Chem. H. Rieger, E. Rieth, A. Rosenberger, E. Rudolph, G. Rudolph,
Dipl.-Chem. S. Ruprecht, Dr. B. Sarbas, Dr. H. Schafer, Dr. D. Schioberg, V. Schlicht, Dipl.
Chem. D. Schneider, Dipl.-Min. P. Schubert, Dr. K. Schucke, A. Schwarzel, Dr. B. Schwager,
Dipl.-Ing. H. M. Somer, G. Strauss, Dr. G. Swoboda, Dr. U. Taubald, M. Teichmann, Dr. D. Tille,
Dipl.-Ing. H. Vanecek, Dipl.-Chem. P. Velie, Dipl.-Ing. U. Vetter, H.-M. Wagner, Dipl.-Phys.
J. Wagner, R. Wagner, Dr. E. Warkentin, Dr. C. Weber, Dr. A. Wietelmann, Dr. M. Winter, Dr.
B. Wobke, K. Wolff
STAFF GMELIN ONLINE DATA SYSTEM
Dr. R. Deplanque, Dr. P. Kuhn, Dr. G. Olbrich
Gmelin Handbook Volumes on "Silicon" (Syst. No. 15)
Silicon Main Volume B
ELement and Compounds - 1959
Silicon Main Volume C
Organic Silicon Compounds - 1958
Silicon Suppl. Vol. B 1
Silicon and NobLe Gases. SiLicon and Hydrogen (incLuding SiHn-Oxygen Compounds) -1982
Silicon Suppl. Vol. B 2
Properties of Crystalline Silicon Carbide. Diodes. MoLecuLar Species in the Gas Phase.
Amorphous SiLicon-Carbon Alloys - 1984
Silicon Suppl. Vol. B 3
System Si~. SiC: NaturaL Occurrence. Preparation and Manufacturing Chemistry. SpeciaL
Forms. Manufacture. ELectrochemicaL Properties. ChemicaL Reactions. Applications. Ternary
and Higher Systems with Si and C - 1986
Silicon Suppl. Vol. B 4
System Si-N. Binary and Ternary Silicon Nitrides. SiLicon-Nitrogen-Hydrogen Compounds.
N-Substituted SiLicon-Nitrogen Compounds (present volume) - 1989
Gmelin Handbook
of Inorganic Chemistry
8th Edition
Si
Silicon
Supplement Volume B 4
System Si-N. Binary and Ternary Silicon Nitrides.
Silicon-Nitrogen-Hydrogen Compounds.
N-Substituted Silicon-Nitrogen Compounds
With 25 illustrations
AUTHORS Peter Eigen, Hannelore Keller-Rudek, Wolfgang Kurtz,
Peter Me rlet , Hans Schafer, Friedrich SchrOder
EDITORS Hartmut Katscher, Hannelore Keller-Rudek, Peter Merlet,
Hans Schafer, Friedrich Schroder
Hermann Jehn, Forschungsinstitut fUr Edelmetalle und
Metallchemie, SchwAbisch-GmOnd
CHIEF EDITOR Friedrich Schroder
System Number 15
Springer-Verlag Berlin Heidelberg GmbH 1989
LITERATURE CLOSING DATE: END OF 1987
IN SOME CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress Catalog Card Number: Agr 25-1383
ISBN 978-3~62-06999-8 ISBN 978-3-662-06997-4 (eBook)
DOll0.1007/978-3~62-06997-4
This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of
translation, reprinting, reuse of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in
data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to
"Verwertungsgesellschaft Wort", Munich.
© by Springer-Verlag Berlin Heidelberg 1988
Originally published by Springer-Verlag, Berlin· Heidelberg· New York· London· Paris· Tokyo in 1988
Softcover reprint of the hardcover 8th edition 1988
The use of registered names, trademarks, etc., in this publication does not imply, even in the absence of a specific statement, that
such names are exempt from the relevant protective laws and regulations and therefore free for general use.
Preface
This is the first supplementary volume on silicon-nitrogen compounds. It begins with the
system silicon-nitrogen and continues with the binary silicon nitrides, except for Si3N4 that will
be the subject of a separate Handbook volume. A chapter describes anionic formula units of
the type SixNr and includes a condensed description of a series of ternary silicon nitrides. A
treatment follows of the molecular and polymeric silicon-nitrogen-hydrogen compounds in
which hydrogen is bonded either to silicon, or to nitrogen, or to both. In other words, those
compounds have been selected for this chapter in which one or more nitrogen atoms are
bonded to silicon and also those compounds in which additional silicon and/or hydrogen have
been bonded to the initial silicon.
About 60% of this volume contains a description of predominantly molecular silicon
nitrogen compounds that are substituted at the nitrogen with groups containing other
elements. According to the Gmelin System the substituting groups may be bonded through
sulfur, boron, carbon, or both sulfur and carbon, or both boron and carbon. As may be
expected, the largest quantity of information exists for compounds that have organyl substi
tuents on the nitrogen, including the class of silicon coordination compounds that fulfill the
criteria. In particular in these chapters, sections and subsections have been formed grouping
compounds of the same class together. Compounds containing silicon--carbon bonds any
where in the molecule are not covered in this volume.
General remarks have been given to introduce chapters and to link chapters and sections.
In particular see p. 149ft.
Throughout this volume a question mark has been placed after the title formula or name of
a compound whose existence is very questionable according to the available information.
Titles with formulas in quotation marks indicate that the molecule has only been the subject of
calculations.
A list of abbreviations and some comments follow on the next three pages.
Frankfurt am Main
November 1988 Friedrich Schroder
Abbreviations, Comments and Units
Throughout this volume the Registry Number and Index Name from ChemicaL Abstracts
have been quoted for each compound. Formulas that are given in the CAS Registry fiLe with
"0 references" have not been covered in the voLume, if indeed no information has been
published.
For the description of the physical properties and the chemicaL reactions of many com
pounds, especially in tables, common abbreviations and units are used in this volume. In order
to avoid ambiguities, most of the abbreviations, not in each case specified in detail in the text,
are explained here.
Numerous abbreviations are used for the coverage of ab initio and semiempiricaL molecular
orbital calculations:
AM 1 Austin model 1
AO atomic orbital
a.u. atomic unit
CEPA coupLed electron pair approximation
CI configuration interaction
CNDO complete negLect of differentiaL overLap
DZ double-zeta
EA electron affinity
EH extended Hi.ickel
Er totaL energy
Ext. extended
GTO Gaussian-type orbital
HF Hartree-Fock
HOMO highest occupied molecular orbital
INDO intermediate negLect of differential overlap
LCAO Linear combination of atomic orbitals
LUMO Lowest unoccupied molecular orbitaL
MCSCF multiconfiguration seLf-consistent fieLd
MIM molecules in mOlecule
Min. minimal
MNDO modified neglect of differential overlap
MO moLecular orbitaL
MP M"ller-Plesset
MRD multi-reference and double-excitation
NDDO neglect of diatomic differentiaL overlap
NO natural orbitaL
PA proton affinity
PNO pair natural orbital
pop. population analysis
Gmelin Handbook
Si Suppl. Vol. B 4
