Table Of ContentUral Scientific Research Institute
for Metrology
Reference Materials
in Measurement
and Technology
Proceedings of the Third International
Scientific Conference
Reference Materials in Measurement
and Technology
Sergei V. Medvedevskikh Olga N. Kremleva
(cid:129) (cid:129)
’
Irina E. Vasil eva Egor P. Sobina
(cid:129)
Editors
Reference Materials
in Measurement
and Technology
Proceedings of the Third International
fi
Scienti c Conference
123
Editors
SergeiV.Medvedevskikh OlgaN.Kremleva
UralScientificResearch UralScientificResearch
Institute for Metrology Institute for Metrology
Ekaterinburg, Russia Ekaterinburg, Russia
Irina E. Vasil’eva EgorP. Sobina
A.P. Vinogradov Institute of Geochemistry UralScientificResearch
Siberian Branch,Russian Academy Institute for Metrology
of Sciences Ekaterinburg, Russia
Irkutsk,Russia
ISBN978-3-030-32533-6 ISBN978-3-030-32534-3 (eBook)
https://doi.org/10.1007/978-3-030-32534-3
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Preface
This Springer collection features selected fundamental and appliedresearch papers
devoted to various issues involved with the development and application of refer-
encematerialsandmethods.ThesepaperswerepresentedattheThirdInternational
ScientificConferenceReferenceMaterialsinMeasurementandTechnology,which
was held on 11–14 September 2018 in Ekaterinburg (Russia) under the auspices
of the Federal Agency for Technical Regulation and Metrology (Rosstandart) and
the Ural Scientific Research Institute for Metrology (UNIIM), a scientific method-
ological centre of the State service of reference materials for the composition and
properties ofsubstances andmaterials.
The conference was aimed at facilitating the exchange of scientific information
between its participants about fundamental and applied research in the field of
reference materials, as well as at attracting attention to reference materials as an
importanttechnicalandregulatorybasisforensuringtheuniformityandaccuracyof
measurements. In the context of knowledge economy, when digitisation comes to
embrace not only industrial and social sectors, but also the entire quality control
infrastructure, the maintenance of international uniformity of measurements
becomes essential. In turn, the system aimed at providing uniformity of measure-
ments also undergoes massive transformations concerned with increased informa-
tisation and digitisation.
Under these circumstances, metrological activity is acquiring an infrastructural
character by bolstering the national economy in all areas of activity, including
health care, labour safety, pharmaceutical production, environmental protection,
development and maintenance of diagnostic equipment. There is a clear trend
towards theuseofmeasuringinstrumentswithdistributed andvirtual components,
as well as cloud computing services and databases.
Intelligentsystemsareintendedtosimplifyandoptimiseproductionandsupport
the development of new technologies and substances. Already, new technologies
permit more accurate data on measurementobjectsto be obtained, while advanced
dataprocessingmethodsofferimprovedapproachestoanalysingsuchmeasurement
data. Experimental work devoted to the development of new reference materials is
also becoming more accurate and efficient. As a result, the problem of both
v
vi Preface
expanding the range and increasing the quality of modern reference materials is
movingtotheforefront.Anotherurgenttaskistheoptimisationofmechanismsfor
forecasting the needs of states and society in terms of metrological measurement
support, which can be achieved by increasing the competitiveness of domestic
reference materials in international markets. Therefore, in the context of global
digitalisation, key objectives of metrological support include not only monitoring
but also a prompt response to the growing demands of national economies.
Leading experts in the field of measurements and reference materials from dif-
ferent countries are working on solving the aforementioned issues. The Third
International Scientific Conference Reference Materials in Measurement and
Technology brought together scientists, lecturers, postgraduate researchers and
practitionersfromvariousuniversities,researchinstitutesandindustrialcompanies.
The conference was also attended by the representatives of ISO/REMCO, CITAC,
COOMET, COMAR Central Secretariat and experts in the area of reference
materials from Belarus, Germany, Israel, Kazakhstan, the Netherlands, Poland,
Russia, South Africa, Switzerland and the USA.
Theconferencehostedmeetingsof11themedsections.Duringplenary,themed
and poster conference sections, participants made over 80 presentations.
This collection contains 21 conference papers, which were selected during a
rigorousdouble-blindpeer-reviewprocessorganisedbytheeditorsofthisevent.The
papers presented in this collection were published in Russian in the peer-reviewed
scientific and technical journal Reference Materials.
Ekaterinburg, Russia Sergei V. Medvedevskikh
Ekaterinburg, Russia Olga N. Kremleva
Irkutsk, Russia Irina E. Vasil’eva
Ekaterinburg, Russia Egor P. Sobina
Acknowledgements OnbehalfoftheOrganisingCommitteeoftheThirdInternationalScientific
Conference Reference Materials in Measurement and Technology,we express our sincere grati-
tude to all invited speakers, section chairpersons and conference participants for their valuable
contribution to this event. We are also thankful to Anna Kveglis and Dr. Natalia Popova, Head
oftheForeignLanguagesDepartmentoftheInstituteofPhilosophyandLaw,UralBranchofthe
RussianAcademyofSciences(Ekaterinburg)fortheirassistanceintranslatingandpreparingthis
bookforpublication.
We especially appreciate the work done by the members of the Conference Organising
CommitteeI.E.Vasil’eva,A.I.Krylov,M.V.Okrepilov,N.P.Muravskaya,E.V.Kulyabina,
whogreatlyhelpedinreviewingandeditingtheseconferenceproceedings.
Contents
Development and Creation of Reference Materials
Development of Interlaboratory Comparison Test Samples
and Reference Materials for the Quality Assurance of Air
Composition Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Anna M. Bogacheva, Olga B. Ponomareva and Yuliya V. Kanaeva
Metrological Assurance of Dioxin Measurements. A Certified
Reference Material for Measuring the Dioxin Mass Fraction
in Animal Fat. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Alexandra G. Budko, Alena Y. Mikheeva and Anatoliy I. Krylov
Development of Certified Reference Materials for Physicochemical
Analysis. Certified Reference Solutions for the Composition of
Aqueous Aluminium, Indium, Magnesium, Nickel and Titanium. . . . . . 27
Ianina I. Ermakova, Alexander V. Ivanov, Irina N. Zyablikova
and Anna N. Shobina
Multiparametric Reference Materials for Metrological Support
in the Area of Coating Parameter Control. . . . . . . . . . . . . . . . . . . . . . . 39
Vyacheslav V. Kazantsev and Alexander S. Vasilyev
Reference Materials Used for Specific Safety Evaluation of Human
Immunoglobulin and Human Albumin Products: Features
of Development, Certification and Application. . . . . . . . . . . . . . . . . . . . 47
Olga G. Kornilova, Maxim A. Krivykh, Rauza A. Volkova
and Igor V. Borisevich
Reference Materials for Ensuring the Metrological Traceability
of Enzyme Catalytic Activity Measurement (KATAL) . . . . . . . . . . . . . . 57
Elena V. Kulyabina, Olga N. Melkova, Ekaterina A. Guskova
and Tatiana V. Grebennikova
vii
viii Contents
Manufacturing and Certification of Reference Materials
for the Mass Fraction of Boron in Silumin. . . . . . . . . . . . . . . . . . . . . . . 67
Dmitry G. Lisienko, Margarita A. Dombrovskaya
and Eugeniya D. Kubrina
PreparationandCertificationofaReferenceMaterialforthePhysical
Properties of Clay Soils (Loam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Ilona N. Matveeva and Vladimir V. Tolmachev
Development of Reference Materials for Thermodynamic Properties:
Metrological Support of Measurements in the Field of Thermal
Analysis and Calorimetry in Russia . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
Andrey M. Nepomiluev, Vyacheslav V. Kazantsev
and Artyom P. Shipitsyn
Development of Alumina-Based Porosity Reference Materials
for the Mercury Porosimetry Method . . . . . . . . . . . . . . . . . . . . . . . . . . 91
Egor P. Sobina
Development of a Reference Material for the Composition
of 0.1M Potassium Dichromate Solution. Certified Reference
Material GSO 10992-2017 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
Alexander Yu. Shimolin and Alena V. Sobina
Development and Testing of a Certified Reference Material
of the Lead Mass Fraction in Solutions for Measurements
Using Inductively Coupled Plasma Methods. . . . . . . . . . . . . . . . . . . . . . 123
Alexey A. Stakheev and Tatiana P. Stolboushkina
Radiation-Sensitive Film Compositions for Measuring Absorbed
Doses Within the 100–1000 Gy Range . . . . . . . . . . . . . . . . . . . . . . . . . . 131
Vladimir P. Tenishev and Ivan A. Emelyanenko
Developing a Reference Material Set for the Magnetic Properties
of NdFeB Alloy-Based Hard Magnetic Materials . . . . . . . . . . . . . . . . . . 141
Ekaterina A. Volegova, Tatiana I. Maslova, Vladimir O. Vaskovskiy
and Aleksey S. Volegov
Mathematical and Statistical Support of Reference Material
Characterisation
Estimation of Consensus Value of Interlaboratory Measurement
Results Accompanied by a Minimum Increase in Associated
Uncertainty. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
Peter M. Aronov
Contents ix
Quality Assessment of the Preparation of Reference Materials
of Moist Solid Substances. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
Sergej V. Medvedevskikh, Maria Yu. Medvedevskikh
and Maria P. Krasheninina
A Method for Estimating the Certified Value Uncertainty
of a Multicomponent Reference Material . . . . . . . . . . . . . . . . . . . . . . . . 175
Pavel V. Migal, Sergei V. Medvedevskikh and Valery A. Firsanov
Use of Reference Materials
Bismuth-Containing Glassy Reference Materials for Establishing
the Content of Transition Elements Using Luminescent-Based
Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
Valentina V. Borisova, Valentin A. Kutvitsky, Elena V. Mironova,
Inna A. Romanova and Olga I. Ostanina
Participation of the All-Russian Research Institute
of Physical-Technical and Radio-Technical Measurements
(VNIIFTRI) in International Comparisons in the Field
of Physicochemical Measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201
Vladimir I. Dobrovolskiy, Narine G. Oganyan, Sergey V. Prokunin
and Alexey A. Stakheev
Quality Improvement of Commercially Available Certified
Reference Gas Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Leonid A. Konopelko, Anna V. Kolobova and Olga V. Fatina
Application of Raman Spectroscopy in the Quality Control
of Injectable Medicines. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
Maria P. Krasheninina, Maria Yu. Medvedevskikh, Ekaterina V. Galeeva
and Roman R. Galeev
Reference Materials for Isotopic Composition Used in Implementing
Isotope Dilution Mass Spectrometry. . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
Olga N. Kremleva and Tatiana N. Tabatchikova
Combined Measurement Uncertainty for pH-Values Using Certified
Reference Materials in Potentiometric Measurements with Glass
Electrodes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251
Samuel Wunderli
Development and Creation of Reference
Materials
