Table Of ContentRECENT DEVELOPMENTS IN ION EXCHANGE
2
Proceedings of the International Conference, ION-EX '90, held at the
North East Wales Institute, Wrexham, Clwyd, UK, 9-11 July 1990.
Members of the Organising Committee
Mr E. R. Adlard Royal Society of Chemistry (NW Region)
Mr W. J. Beesley (Treasurer) North West Water Authority
Mr B. Crooks ICI Pharmaceuticals
Dr A. Davies Alfred H. Knight Ltd
Dr A. Dyer (Chairman) University of Salford
Dr H. Eccles SCI Solvent Extraction and Ion Exchange Group
Mr R. C. George Dionex (UK) Ltd
Dr J. Greene Nuclear Electric
Dr M. J. Hudson University of Reading
Mr H. Hughes (Secretariat) The North East Wales Institute
Mr B. W. King Phase Separations Ltd
Mr M. Parker Beckman Instruments (UK) Ltd
Mr M. Parker Waters Division of Millipore
Mr D. Ryder Ciba-Geigy pic
Mr P. Wall BDH Ltd
Dr P. A. Williams (Secretariat) The North East Wales Institute
Supported by the Royal Society of Chemistry North Wales Section and North West
Region (Analytical Division) and the Society of Chemical Industry.
RECENT DEVELOPMENTS
IN ION EXCHANGE
2
Edited by
P. A. WILLIAMS
Research Division, The North East Wales Institute,
Deeside, Clwyd, Wales, UK
and
M. J. HUDSON
Chemistry Department, University of Reading,
Whiteknights, Reading, UK
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© 1990 UNITED KINGDOM ATOMIC ENERGY AUTHORITY-pp. 213-218
Softcover reprint of the hardcover 1st edition 1990
British Library Cataloguing in Publication Data
Recent developments in ion exchange 2.
1. Ion exchange
I. Williams, Peter A. (Peter Anthony) II. Hudson, M. J.
(Michael James), 1940-
541.3723
ISBN-13:978-94-010-6836-9 e-ISBN-13:978-94-009-0777-5
DOl: 10.1007/978-94-009-0777-5
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v
PREFACE
These Conference Proceedings deal with the papers presented at the International
Conference on Ion Exchange Processes (ION-EX '90) which was held at The North
East Wales Institute of Higher Education, 9- 11 July 1990. The camera-ready paper
format was chosen so that delegates could receive their copy on arrival at the
Conference. The Proceedings include reviews of biological materials, inorganic ion
exchangers, the nuclear industry, theoretical aspects and new advances. In addition,
there are research papers dealing with industrial ion exchange procedures and new
materials. The Proceedings should therefore be of interest to those who need to be
brought up to date in the various aspects of processes which involve ion exchange
and ion chromatography which are now accepted as important in analysis,
separation processes and process control. In each of these areas there have been
important developments which are herein described.
As Editors we should like to express our thanks to the individual authors for
preparing their manuscripts in the required format and to Haydn Hughes and Linda
Sneddon for their invaluable assistance in compiling these Proceedings.
PETER A. WILLIAMS
MICHAEL J. HUDSON
V\1
CONTENTS
Preface v
Part 1: Biological Materials
The Importance of Ion Exchange Processes in Living Systems 3
R. J. P. Williams
The Use of Chemically Suppressed Ion Chromatography in Elemental
Analysis 17
J. P. Senior
Biological Separations Using Latex-Based Pellicular Resins 23
K. Cook
Simultaneous Determinatioui of Alkali and Alkaline Earth Metal Ions with
Isocratic Ion Chromatography Using the SUPER-SEP Cation Column
(According to Schomburg) 31
M. W. Liiubli
Part 2: Inorganic Ion Exchangers
Recent Advances in Inorganic Ion Exchangers 43
A. Dyer
Synthesis and Ion Exchange Properties of Lithium Ion Selective Inorganic
Ion Exchanger by Applying Ion Memory Effect 57
M. Abe, R. Chitrakar, M. Tsuji and Y. Kanzaki
Uptake of Several Tracer Cations and the Separation of Carrier Free !4°La
from 140Ba and also 115mIn from 115Cd Using a Zirconium(IV) Oxide
Column 67
D. K. Bhattacharyya and N. C. Dutta
Cation and Anion Exchange Properties of Pillared Clays 75
A. Dyer and T. Gallardo
Vlll
Ion Exchange Properties of a-Zirconium Phosphate Modified by a Process
of Intercalation/De-intercalation with Monoamines . 85
G. Alberti, O. Costantino, F. Marmottini, R. Vivani and C. Valentini
New Cross-Linked Layered Tin Phosphate Exchangers 95
P. Maireles-Torres, P. Olivera-Pastor, E. Rodriguez-Castellon,
A. Jimenez-Lopez and A. A. G. Tomlinson
Formation of Diamine-Complex Pillars in r-Ti (HP0 h 2H 0 . 103
4 2
C. Ferragina, A. La Ginestra, M. A. Massucci, P. Cafarelli, P. Patrono
and A. A. G. Tomlinson
Ion Exchange Behaviour of Some Amine Intercalates of a-Tin(IV) Hydrogen
Phosphate Monohydrate . 109
M. J. Hudson, E. Rodriguez-Castellon and P. Sylvester
Part 3: Nuclear Industry
Ion Exchange in the Nuclear Industry 121
J. P. Bibler
Activity Removal from Liquid Waste Streams by Seeded Ultrafiltration 135
E. W. Hooper and R. M. Sellers
Recovery of Fission Products by Fixation on Inorganic Adsorbents 151
S. Zouad, C. Loos-Neskovic, E. Garnier, J. Jeanjean and M. Fedoroff
Simultaneous Elimination of Heavy Metals and Chelating Agents from
Waste Waters 161
W. H. Hall
Separation of Ruthenium and Molybdenum by Cation Exchange Chroma-
tography on AG 50W-X4 in a Nitric Acid-Ethylenediamine Mixture 171
T. N. van der Walt, P. J. Fourie and P. P. Coetzee
Part 4: Theoretical Aspects and New Advances
Calculation of Retention Data in Ion Exchange Chromatography 187
J.lnczMy
Ligand Exchange Principles for Trace Enrichment and Selective Detection
of Ionic Compounds 195
U. A. Th. Brinkman and H. Irth
IX
Electrochemical Ion Exchange . 213
P. M. Allen, N. J. Bridger, C. P. Jones, M. D. Neville and A. D. Turner
Ion Exchange Separations in Conjunction with Electrochemical Detection 219
R. Cochrane
Reversible Extraction of Cobalt(IJ) from Aqueous Media Using Inorganic
Ion Exchangers in Electrochemical Ion Exchange 231
R. J. W. Adams and M. J. Hudson
Part 5: New Materials
A New Solvent Resistant Ion Exchange Material for Analytical Chroma-
tography 243
C. A. Pohl
Ion Exchange Adsorption of Metal Ions on Amine and Pyridine Types of
Chelating Resins 255
K. Inoue, K. Yoshizuka and Y. Baba
Specific Resins for Metal Ion Separation: The Cr(III), Fe(III), Al(JII)
System 265
D. Petruzzelli, L. Liberti, R. Passino and G. Tiravanti
Improvements in Macroreticular Particles for Ion-Exchange and Gel-
Permeation Chromatography 277
J. S. Watson
Some Properties of New Ion Exchangers with Organopolysiloxane Structure 287
F. Chen, G. Cote and D. Bauer
Extraction of the Perrhenate Anion Using Goethite Surface-Modified with
Hydrophobic Quaternary Amines 297
M. J. Hudson and D. J. Tyler
Solid Phase Extraction and Chromatography of Metal Ions Using Free and
Immobilised Biomimetic Chelating Agents 311
S. Srijarani, N. Ryan, N. Mitchell and J. D. Glennon
Part 6: Industrial Applications
Economic Process for Softening Produced Water Used in Secondary Oil
Recovery . 319
F. X. McGarvey and R. Gonzalez
x
On-Line Monitoring of Transition Metals in Wastewater 331
G. Humphrey
Some Problems in the Use ofChelating Resins for Environmental Protection
from Toxic Metals 337
J. R. Millar, D. Petruzzelli and G. Tiravanti
The Analysis of Industrial Water Treatment Products Using Ion
Chromatography Separation with Multiple Detection Systems 347
D. S. Ryder
Index of Contributors 357
Subject Index 359
Part 1
BIOLOGICAL MATERIALS
