Table Of ContentPYROLYSIS-GC/MS DATA
BOOK OF SYNTHETIC
POLYMERS
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PYROLYSIS-GC/MS DATA
BOOK OF SYNTHETIC
POLYMERS
Pyrograms, Thermograms and
MS of Pyrolyzates
TSUGE Shin,
OHTANI Hajime,
WATANABE Chuichi
Amsterdam(cid:129)Boston(cid:129)Heidelberg(cid:129)London (cid:129)NewYork (cid:129)Oxford
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11 12 13 10 9 87 6 5 4 3 2 1
CONTENTS
Preface xiii
Part1 Introduction 1
1.1 Historyandscopeofanalyticalpyrolysis 1
1.2 ExpandedapplicabilityofGC/MSbycombiningwithpyrolysis 3
1.3 Py-GC/MSmeasuringprocessforpolymercharacterization 4
Part2 Pyrograms andthermogramsof163 high polymers,and MS data of the
major pyrolyzates 7
2.1 Experimentalconditionsformeasuringpyrogramsandthermograms
ofhighpolymers,andMSdataforthemajorpyrolyzatesbymeans
ofpyrolysis-GC/MSandevolvedgasanalysis(EGA)-MStechniques 7
2.1.1 Polymersamples 7
2.1.2 Measuringconditionsforthepyrogramsofthepolymersand
theMSdataofthemajorpeaksoneachpyrogram,andthe
thermogramsofthepolymers 7
2.1.3 DatadescriptionsforthepyrogramsandtheMSdataofthe
majorpeaksonthepyrograms,andthethermogramsfor
163polymersamples 10
2.2 Datacompilationofpyrograms,thermogramsandMSdataofmajor
pyrolyzatesfor163typicalpolymersamples 12
2.2.1 Polyolefins(homopolymers) 12
001Polyethylene(highdensity);PE(HDPE) 12
002Polypropylene(isotactic);iso-PP 14
003Polypropylene(atactic);at-PP 16
004Polypropylene(syndiotactic);syn-PP 18
005Polybutene-1(isotactic) 20
006Poly(4-methyl-1-pentene);PMP 22
007Isobutylene-isoprenerubber;IIR 24
2.2.2 Vinylpolymerswithethyleneunits(copolymers) 26
008Ethylene-propylenecopolymer;P(E-P) 26
009Ethylene-propylene-dienerubber;EPDM 28
010Ethylene-methylmethacrylatecopolymer;P(E-MMA) 30
011Ethylene-acrylicacidcopolymer;P(E-AA) 32
j
v
vi Contents
012Ethylene-vinylacetatecopolymer;EVA 34
013Ethylene-ethylacrylatecopolymer;P(E-EA) 36
014Ethylene-vinylalcoholcopolymer;P(E-VA) 38
015Polyethyleneionomer;IO 40
2.2.3 Vinylpolymerswithstyreneunits 42
016Polystyrene;PS 42
017Styrene-methylacrylatecopolymer;P(S-MA) 44
018Styrene-methylacrylatealternatingcopolymer 46
019Styrene-methylmethacrylatecopolymer;P(S-MMA) 48
020Styrene-methylmethacrylatealternatingcopolymer 50
021Methylmethacrylate-butadiene-styrenecopolymer;MBS 52
022Acrylonitrile-styrenecopolymer;AS 54
023Acrylonitrile-styrenealternatingcopolymer 56
024Acrylonitrile-butadiene-styrenecopolymer;ABS 58
025Acrylonitrile-acrylate-styrenecopolymer;AAS 60
026Acrylonitrile-EPDM-styrenecopolymer;AES 62
027Styrene-maleicanhydridecopolymer;P(S-Mah) 64
028Styrene-divinylbenzenecopolymer;P(S-DVB) 66
2.2.4 Vinylpolymerswithstyreneunits’derivatives 68
029Poly(a-methylstyrene);P-a-MS 68
030Polydivinylbenzene;PDVB 70
031Poly(p-chlorostyrene) 72
032Poly(p-methylstyrene);PMS 74
033Poly(2-vinylpyridine) 76
034Acrylonitrile-p-chlorostyrenecopolymer 78
035Chloromethylatedstyrene-divinylbenzenecopolymer 80
2.2.5 Acrylate-typepolymers 82
036Poly(methylmethacrylate);PMMA 82
037Poly(n-butylmethacrylate);PBMA 84
038Poly(2-hydroxyethylmethacrylate);PHEMA 86
039Poly(methylacrylate);PMA 88
040Poly(ethylacrylate);PEA 90
041Poly(butylacrylate);PBA 92
042Poly(acrylicacid;isotactic);PAA 94
043Methylmethacrylate-methylacrylatecopolymer;
P(MMA-MA) 96
044Highermethacrylatecopolymer 98
045Acrylicrubber;ACM 100
046Polyacrylonitrile;PAN 102
Contents vii
047Acrylonitrile-methylacrylatecopolymer 104
048Polyacrylamide;PAAm 106
049Poly(maleicanhydride);PMAH 108
2.2.6 Chlorine-containingvinylpolymers 110
050Poly(vinylchloride);PVC 110
051Vinylchloride-vinylidenechloridecopolymer;
P(VC-VdC) 112
052Chlorinatedpoly(vinylchloride);CPVC 114
053Chlorinatedpolyethylene;CM 116
054Vinylchloride-vinylacetatecopolymer;P(VC-VAc) 118
055Chlorosulfonatedpolyethylene;CSM 120
056Acrylonitrile-vinylchloridecopolymer;P(AN-VC) 122
057Acrylonitrile-vinylchloridealternatingcopolymer 124
058Methylacrylate-vinylchloridecopolymer;P(MA-VC) 126
059Methylacrylate-vinylchloridealternatingcopolymer 128
2.2.7 Fluorine-containingvinylpolymers 130
060Polytetrafluoroethylene;PTFE 130
061Tetrafluoroethylene-hexafluoropropylenecopolymer;FEP 131
062Polychlorotrifluoroethylene;PCTFE 132
063Poly(vinylfluoride);PVF 134
064Poly(vinylidenefluoride);PVDF 136
065Vinylidenefluoride-hexafluoropropylenerubber 138
066Propylene-tetrafluoroethylenerubber 140
2.2.8 Theothervinylpolymers 142
067Poly(vinylalcohol);PVA 142
068Poly(vinylbutyral);PVB 144
069Poly(vinylacetate);PVAc 146
070Poly(vinylpyrrolidone);PVP 148
2.2.9 Diene-typeelastomers 150
071Highcis-butadienerubber;BR 150
072Poly(1,2-butadiene) 152
073Naturalrubber;NR 154
074Chloroprenerubber;CR 156
075Hydrogenatednaturalrubber 158
076Acrylonitrile-butadienerubber;NBR 160
077Hydrogenatedacrylonitrile-butadienerubber 162
078Polynorbornene 164
079Styrene-butadienerubber;SBR 166
080Styrene-butadiene-styreneblockcopolymer;SBS(TPS) 168
viii Contents
081Styrene-ethylene-butadiene-styreneblockcopolymer;
hydrogenatedSBS(SEBS) 170
2.2.10 Polyamides 172
082Polycaproamide;Nylon-6 172
083Polyundecanoamide;Nylon-11 174
084Polylauroamide;Nylon-12 176
085Poly(tetramethyleneadipamide);Nylon-4,6 178
086Poly(hexamethyleneadipamide);Nylon-6,6 180
087Poly(hexamethylenesebacamide);Nylon-6,10 182
088Poly(dodecamethyleneadipamide);Nylon-12,6 184
089Caproamide-hexamethyleneadipamidecopolymer;
Nylon-6/66 186
090Poly(m-xyleneadipamide);Nylon-MXD6 188
2.2.11 Polyacetalsandpolyethers 190
091Polyoxymethylene;POM 190
092Polyoxymethylene(copolymer) 192
093Poly(ethyleneoxide) 194
094Epichlorohydrinrubber;CHR 196
095Epichlorohydrin-ethyleneoxiderubber;CHC 198
2.2.12 Thermosettingpolymers 200
096Phenolformaldehyderesin(novolak);PF 200
097Phenolformaldehyderesin(resol);PF 202
098Cresolformaldehyderesin(novolak) 204
099Diallylphthalateresin;DAP 206
100Poly(ethyleneglycolbisallylcarbonate);CR-39 208
101Ureaformaldehyderesin;UF 210
102Melamineformaldehyderesin;MF 212
103Xyleneresin 214
104Unsaturatedpolyester;UP 216
105Epoxyresin;EP 218
106Brominatedepoxyresin 220
2.2.13 Polyimideandpolyamide-typeengineeringplastics 222
107Bismaleimidetriazineresin;BTresin 222
108Polyetherimide;PEI 224
109Polypyromellitimide;PI 226
110Polyaminobismaleimide;PABM 228
111Polyamideimide;PAI 230
112Poly(p-phenyleneterephthalamide);Kevlar 232
113Poly(m-phenyleneisophthalamide);Nomex 234
Contents ix
114Poly(p-phenylene/3,4-diphenyleneetherterephthalamide) 236
2.2.14 Polyesters 238
115Poly(ethyleneterephthalate);PET 238
116Poly(butyleneterephthalate);PBT 240
117Poly(ethylenenaphthalate);PEN 242
118Poly(p-hydroxybenzoicacid);typeA 244
119Poly(p-hydroxybenzoicacid);typeB 246
120Polyarylate;PAR 248
121Poly(1,4-cyclohexanedimethyleneterephthalate) 250
122Poly(lacticacid);PLA 252
123Poly(3-caprolactone);PCL 254
124Poly(butylenesuccinate/adipate);PBSA 256
125Poly(3-hydroxybutylicacid);PHB 258
126Poly(butylenesuccinate/carbonate);PEC 260
2.2.15 Theotherengineeringplasticswithphenyleneskeletons 262
127Polycarbonate(meltmethod);MM-PC 262
128Polycarbonate(solventmethod);SM-PC 264
129BisphenolZpolycarbonate 266
130Polycarbonate(thermallystabilized) 268
131Brominatedpolycarbonate;Br-PC 270
132Polysulfone;PSF 272
133Poly(phenyleneoxide);PPO 274
134Modifiedpoly(phenyleneoxide);ModifiedPPO 276
135Polyethersulfone;PESF 278
136Poly(etheretherketone);PEEK 280
137Poly(phenylenesulfide);PPS 282
138Poly(arylethernitrile);PEN 284
2.2.16 Siliconepolymers 286
139Polydimethylsiloxane;PDMS 286
140Polymethylphenylsiloxane;PMPS 288
141Dimethylsiloxane-methylphenylsiloxanecopolymer 290
142Polymethylsilsesquioxane;PMSQ 292
143Poly(methyl-phenyl)silsesquioxane;PMPSQ 294
2.2.17 Polyurethanes 296
144TDI-polyesterpolyurethane;PU 296
145TDI-polyetherpolyurethane;PU 298
146MDI-polylactonepolyurethane;PU 300
147Urethanerubber;U 302
2.2.18 Cellulose-typepolymers 304
