Progress in Inorganic Chemistry, Volume 57

620 Pages·2012·6.26 MB·English

Progress in
Inorganic Chemistry
Volume 57
Advisory Board
JACQUELINEK.BARTON
CALIFORNIAINSTITUTEOFTECHNOLOGY,PASADENA,CALIFORNIA
JAMESP.COLLMAN
STANFORDUNIVERSITY,STANFORD,CALIFORNIA
ALANH.COWLEY
UNIVERSITYOFTEXAS,AUSTIN,TEXAS
RICHARDH.HOLM
HARVARDUNIVERSITY,CAMBRIDGE,MASSACHUSETTS
EIICHIKIMURA
SHIZUOKAUNIVERSITY,SHIZUOKA,JAPAN
NATHANS.LEWIS
CALIFORNIAINSTITUTEOFTECHNOLOGY,PASADENA,CALIFORNIA
STEPHENJ.LIPPARD
MASSACHUSETTSINSTITUTEOFTECHNOLOGY,CAMBRIDGE,
MASSACHUSETTS
TOBINJ.MARKS
NORTHWESTERNUNIVERSITY,EVANSTON,ILLINOIS
KARLWIEGHARDT
MAX-PLANCK-INSTITUT,MU¨LHEIM,GERMANY
PROGRESS IN
INORGANIC CHEMISTRY
Edited by
KENNETH D. KARLIN
DEPARTMENTOFCHEMISTRY
JOHNS HOPKINS UNIVERSITY
BALTIMORE, MARYLAND
VOLUME 57
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ISBN 978-1-118-01063-1
PrintedintheUnitedStatesofAmerica
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10 9 8 7 6 5 4 3 2 1
Contents
Chapter 1 Mechanisms ofWaterOxidation Catalyzed
byRuthenium Coordination Complexes .................... 1
AURORA E. CLARKand JAMESK. HURST
xþ
Chapter 2 Biomimetic andNonbiological Dinuclear M
Complex-Catalyzed AlcoholysisReactions of
PhosphorylTransfer Reactions ........................... 55
R. STAN BROWN
Chapter 3 Photoactivated DNACleavage and Anticancer
Activityof 3d Metal Complexes ......................... 119
AKHIL R. CHAKRAVARTYand MITHUN ROY
Chapter 4 Design and EvolutionofArtificialMetalloenzymes:
Biomimetic Aspects.................................... 203
MARC CREUS and THOMAS R. WARD
Chapter 5 Functionalizationof Fluorinated Aromatics by
Nickel-Mediated C–Hand C–F BondOxidative
Addition: Prospects for the Synthesis of
Fluorine-ContainingPharmaceuticals..................... 255
SAMUEL A.JOHNSON, JILLIANA. HATNEAN, and
MEGHANE. DOSTER
Chapter 6 DNA Based Metal Catalysis............................. 353
JENS OELERICH andGERARD ROELFES
Chapter 7 Metallo-b-lactamases and Their Synthetic Mimics:
Structure, Function, and Catalytic Mechanism ............. 395
MUTHAIAH UMAYAL,A. TAMILSELVI, and
GOVINDASAMY MUGESH
v
vi CONTENTS
Chapter8 ANewClass ofNanostructuredInorganic–Organic
Hybrid Semiconductors Based on II–VI
BinaryCompounds .................................... 445
JING LI andRUIBO ZHANG
Chapter9 OxygenEvolutionReaction Chemistry
of Oxide-Based Electrodes .............................. 505
YOGESH SURENDRANATH andDANIEL G. NOCERA
Subject Index .................................................... 561
CumulativeIndex................................................. 593
Chapter1,Figure3. TheDFTpredictedmechanismforwateroxidationcatalyzedby[Ru(OH)(3,6-
2 2
BuQ)(btpyan)]2þ ion [3,6-BuQ¼3,6-di-tert-butyl-1,2-benzoquinone and btpyan¼ 1,8-bis
2 2
(2,20:60,200-terpyrid-40-yl)anthracene].(Seetextforfullcaption.)
Dark
m)0.10
(b) 0 n0.09
4
7
(a)0.6 nce (0.08
a
orb0.07
bs
A0.06 Light
100 200 300 400
0.4
Time (s)
e
nc (c)
a
b
Absor 0.2 {4,5} NIR component nsity
RuIII nte
al i
RuII {3,4} gn
0.0 PR si
E
300 450 600 750 900
330340350360 0 20 40 60 80
Wavelength (nm) Magnetic field (mT) Time (s)
Chapter1, Figure 9. Photocatalyzed water oxidation by the SO2(cid:2)/[Ru(bpy)]2þ/“blue dimer”
2 8 3
system.(Seetextforfullcaption.)
Chapter2,Figure4. Molecularstructureof20:CuII:(HO(cid:2))(PhCHO)PO(cid:2))(CFSO(cid:2)) shownas
2 2 2 2 3 3 2
anORTEPdrawingatthe50%probabilitylevel.(Hydrogensandcounterionsareomittedforclarity.)
Chapter4,Figure12. Enantioselectivityofartificial-transferhydrogenasesforacetophenonereduc-
tion.Intheachiral(planartrigonal)intermediateduringcatalyticturnover,incorporationofahydride
fromoneofthetwopossibleprochiralfaceswillleadtoenantiomersofthethree-leggedd6pianostool
complex.(Seetextforfullcaption.)
T6
N
N
Cu2+
HN O
X
ON7 ON8
N
Cu2+
N
HN O
X
O
N
1a O N
3a
2
Chapter6,Scheme17. CovalentapproachtoasymmetricDNAbasedcatalysis.
Chapter7,Figure4. Mono-andbinuclearstructuresofmblsfromBacilluscereus(BcII)ofsubclassB1.
(a)Panelarepresentstheoverallproteinstructuresofmbls,A,BandCfromBcIIwith2.5-,1.85-,and1.9-
A˚resolution,respectively.(b)panelb(D–F)representstheactivesitesofcorrespondingproteinstructures.
Watermoleculeandhydroxideionsareshownasredspheres,whereasZn(II)ionsareshownasgray
spheres.[PDBcodesforstructuresA,BandCare1BMC,1BVT,and1BC2,respectively(60–62).
Chapter7,Figure5. StructuresofVIM-2mblsofsubclassB1inbothreducedGandIandoxidized
HandJforms.Panelarepresentstheoverallproteinstructures,whereaspanelbrepresentstheactive
sitesoftheseproteins.[PDBcodesforstructuresGandHare1KO3and1KO2,respectively.Here
Ocs221representsthecysteinesulfonicacid(66).]
Chapter8, Figure 32. (a) A reference UV LED (360nm) illuminating blue light (commercially
available).(b)ImageofthesameLEDcoatedwithathinlayerof2D-[CdS(ba)]beforeillumination.
2 2
(c)TheilluminatingimageofthecoatedLED.(d)TheilluminatingimageofthecoatedLEDafterMn2þ
doping(0.1mol%).