Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells

309 Pages·2012·15.4 MB·English

by  Kirt A. Page

Polymers for Energy Storage and
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
1096
ACS SYMPOSIUM SERIES
Polymers for Energy Storage and
Delivery: Polyelectrolytes for
Batteries and Fuel Cells
1
0 Kirt A. Page, Editor
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pu01 Christopher L. Soles, Editor
2 | http://021/bk-2 NationalInstituteofStandardsandTechnology
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wnloaation ACS DiviSsipoonnosforPeodlybmyetrhCehemistry
Doublic ACSDivisionofPolymericMaterials: ScienceandEngineering
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AmericanChemicalSociety,Washington,DC
DistributedinprintbyOxfordUniversityPress,Inc.
In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
LibraryofCongressCataloging-in-PublicationData
Polymersforenergystorageanddelivery:polyelectrolytesforbatteriesandfuelcells/Kirt
A.Page,editor;ChristopherL.Soles,editor;JamesRunt,editor.
p.cm.-- (ACSsymposiumseries;1096)
"SponsoredbytheACSDivisionofPolymerChemistryandACSDivisionofPolymeric
1
g w00 Materials:ScienceandEngineering."
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pu01 Electronicpolymers--Congresses.4. Polymers--Electricproperties--Congresses. I.Page,
p://k-2 KirtA.II.Soles,ChristopherL.III.Runt,JamesP.(JamesPatrick),1953-
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
Foreword
The ACS Symposium Series was first published in 1974 to provide a
mechanism for publishing symposia quickly in book form. The purpose of
the series is to publish timely, comprehensive books developed from the ACS
sponsoredsymposiabasedoncurrentscientificresearch. Occasionally,booksare
developed from symposia sponsored by other organizations when the topic is of
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g w00 keeninteresttothechemistryaudience.
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
Preface
Polymericmaterialshavebeenandcontinuetobeafocusofresearchinthe
developmentofmaterialsforenergyconversion,storageanddeliveryapplications
(fuelcells,batteries,photovoltaics,capacitors,etc.). AWebofScienceSMsearch
for polymer research as applied to various energy applications over the past 47
years yields a significant number of results as can be seen in the Figure below.
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For polymers, particularly polyelectrolytes, being used in fuel cell and
battery applications, the importance of chain microstructure, chain dynamics,
and nanoscale morphology on the overall performance characteristics of these
materials cannot be overstated. As further advancements are made in polymer
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
chemistry, control of nanostructure and characterization, there is a necessity for
organized forums that foster cross-fertilization of knowledge and ideas between
experts in polymer chemistry, chemical engineering, and polymer physics. This
volumeistheresultofsuchaforum. Mostofthechaptersinthisbookarebased
on a cross-section of the oral presentations in a symposium on Polymers for
Energy Storage and Delivery held in March of 2011 as part of the 241st ACS
National Meeting & Exposition (Anaheim, CA). The symposium was organized
by ACS Division of Polymer Chemistry (POLY) and co-sponsored by the ACS
DivisionofPolymericMaterials: Science&Engineering(PMSE).
Thebookcontains17chaptersandispresentedintwoparts. Partonefocuses
on polymers for battery applications and will cover theory and modeling, novel
materials,andmaterialscharacterization. ProfessorJannaMaranashasprovided
an excellent review of the current state of understanding in polyelectrolytes as
1 ion conductors in batteries. Part two will focus on polymers for fuel cells and
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n J01 We would like to thank the authors for their efforts and the high quality of
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u Itisourhopethatscientistsandengineerswhoareengagedinresearchand
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developmentinthestructure,dynamics,andtransportofionsinpolyelectrolytes
foruseinenergyapplicationsfindthisbooktobeavaluablereference.
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
The cover art design and concept were created by Kirt A. Page (NIST)
and Kevin G. Yager (Brookhaven National Laboratory Center for Functional
Nanomaterials), the graphics and artwork were created by Kevin G. Yager.
The molecule shown is the result of a molecular dynamics simulation of a
polyethyleneoxide-based,single-ionconductor(seebelow)andwasprovidedby
ProfessorJannaMaranasandherstudentKan-JuLin(Ph. D.candidate)fromthe
DepartmentofChemicalEngineeringatThePennsylvaniaStateUniversity.
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Gaithersburg,MD20899-8542,USA
James Runt
DepartmentofMaterialsScienceandEngineering
ThePennsylvaniaStateUniversity
325CSteidleBuilding
UniversityPark,PA16802,USA
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In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.
Editors’ Biographies
Kirt Page
KirtPageisastaffscientistinthePolymersDivisionatNISTworkingonthe
EnergyStorageandDeliveryProjectwithintheEnergyandElectronicsMaterials
Research Group. He completed his Ph.D. in Polymer Science and Engineering
(2005) at The University of Southern Mississippi and then came to NIST as a
pubs.acs.org 2-1096.ot001 FmHNuiaosltlbieorrcineugsalhelatarArFdccehyalnldoiaenwmmteiayrcnesodsfitnsaSpcpaiorreaelnycctmiientesio,rtnhNseeyarsttaoieorfmenVaaslipfoRoafresssseaetnrnauerarccgtMhuyrCeaedop/piuptranloitccipoiaelntrPi.toyonsstr.-edlKaoticirtotonirssahlaiFpfeoslrlmaonwedr.
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ne 14, oi: 10. Christopher Soles leads the Energy and Electronics Materials Research
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NI7, as a NRC Postdoctoral Research Fellow. His research interests include thin
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NEb): porousmaterials,organicsemiconductingmaterials,andioncontainingpolymers
ORWe for energy storage and delivery. He has over 110 peer-reviewed publications
ed by Cn Date ( SancdienrecceeaivneddEsnegvienreaelrainwga(r2d0s,06in)calundditnhgetUheniPterdesSidtaetnetsiaDleEpaarrltymCenatreoefrCAowmamrderfcoer
oadatio Bronze (2006, 2008) and Silver (2006) Medals, and the Arthur S. Flemming
wnlblic Award from the George Washington University (2010). From 2007 to 2010 he
DoPu wasaTechnicalProgramChairforthePMSEDivisionoftheAmericanChemical

SocietyandisaFellowoftheAmericanPhysicalSociety.
James Runt
James Runt is currently Professor of Polymer Science in the Materials
ScienceandEngineeringDepartmentatPennStateUniversity. Jimistheauthor
ofmorethan180peer-reviewedpublicationsandbookchapters,andisaFellow
of the American Physical Society and the American Institute of Medical and
Biological Engineers. He is an editor of the ACS Professional Reference Series
book: Dielectric Spectroscopy of Polymeric Materials: Fundamentals and
Applications, and is a member of the Board of Directors of the International
DielectricsSociety.
©2012AmericanChemicalSociety
In Polymers for Energy Storage and Delivery: Polyelectrolytes for Batteries and Fuel Cells; Page, K., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2012.