Physical Chemistry Research for Engineering and Applied Sciences, Volume One: Principles and Technological Implications

391 Pages·11.75 MB·english

by  Pearce E.M.

PHYSICAL CHEMISTRY
RESEARCH FOR ENGINEERING
AND APPLIED SCIENCES
VOLUME 1
Principles and Technological Implications
Edited by
Eli M. Pearce, PhD, Bob A. Howell, PhD,
Richard A. Pethrick, PhD, DSc, and
Gennady E. Zaikov, DSc
© 2015 by Apple Academic Press, Inc.

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ABOUT THE EDITOR
Eli M. Pearce, PhD
Dr. Eli M. Pearce was the President of the American Chemical Society. He
served as Dean of the Faculty of Science and Art at Brooklyn Polytechnic
University in New York, as well as a Professor of Chemistry and Chemi-
cal Engineering. He was the Director of the Polymer Research Institute, also
in Brooklyn. At present, he consults for the Polymer Research Institute. As
a prolific author and researcher, he edited the Journal of Polymer Science
(Chemistry Edition) for 25 years and was an active member of many profes-
sional organizations.
Bob A. Howell, PhD
Bob A. Howell, PhD, is a Professor in the Department of Chemistry at Cen-
tral Michigan University in Mount Pleasant, Michigan. He received his PhD
in physical organic chemistry from Ohio University in 1971. His research
interests include flame-retardants for polymeric materials, new polymeric fu-
el-cell membranes, polymerization techniques, thermal methods of analysis,
polymer-supported organoplatinum antitumor agents, barrier plastic packag-
ing, bioplastics, and polymers from renewable sources.
Richard A. Pethrick, PhD, DSc
Professor R. A. Pethrick, PhD, DSc, is currently a Research Professor and

Professor Emeritus in the Department of Pure and Applied Chemistry at the
University of Strathclyde, Glasglow, Scotland. He was Burmah Professor in
Physical Chemistry and has been a member of the staff there since 1969. He
has published over 400 papers and edited and written several books. Recently,
he has edited several publications concerned with the techniques for the char-
acterization of the molar mass of polymers and also the study of their mor-
phology. He currently holds a number of EPSRC grants and is involved with
Knowledge Transfer Programmes involving three local companies involved
in production of articles made out of polymeric materials. His current research
involves AWE and has acted as a consultant for BAE Systems in the area of
explosives and a company involved in the production of anticorrosive coat-
ings.
© 2015 by Apple Academic Press, Inc.
vi About the Editors
Dr. Pethrick is on the editorial boards of several polymer and adhesion
journals and was on the Royal Society of Chemistry Education Board. He is
a Fellow of the Royal Society of Edinburgh, the Royal Society of Chemistry,
and the Institute of Materials, Metal and Mining. Previously, he chaired the
‘Review of Science Provision 16-19’ in Scotland and the restructuring of the
HND provision in chemistry. He was also involved in the creation of the re-
vised regulations for accreditation by the Royal Society of Chemistry of the
MSc level qualifications in chemistry. For a many years, he was the Deputy
Chair of the EPSRC IGDS panel and involved in a number of reviews of the
courses developed and offered under this program. He has been a member of
the review panel for polymer science in Denmark and Sweden and the Na-
tional Science Foundation in the USA.
Gennady E. Zaikov, DSc
Gennady E. Zaikov, DSc, is the Head of the Polymer Division at the N. M.
Emanuel Institute of Biochemical Physics, Russian Academy of Sciences,
Moscow, Russia, and Professor at Moscow State Academy of Fine Chemical
Technology, Russia, as well as Professor at Kazan National Research Techno-
logical University, Kazan, Russia.
He is also a prolific author, researcher, and lecturer. He has received sev-
eral awards for his work, including the Russian Federation Scholarship for
Outstanding Scientists. He has been a member of many professional organiza-
tions and on the editorial boards of many international science journals.

© 2015 by Apple Academic Press, Inc.
Physical Chemistry Research for
Engineering and Applied Sciences
in 3 Volumes
Physical Chemistry Research for Engineering and Applied Sciences:
Volume 1: Principles and Technological Implications
Editors: Eli M. Pearce, PhD, Bob A. Howell, PhD,
Richard A. Pethrick, PhD, DSc, and Gennady E. Zaikov, DSc
Physical Chemistry Research for Engineering and Applied Sciences:
Volume 2: Polymeric Materials and Processing
Editors: Eli M. Pearce, PhD, Bob A. Howell, PhD,
Richard A. Pethrick, DSc, PhD, and Gennady E. Zaikov, DSc
Physical Chemistry Research for Engineering and Applied Sciences:
Volume 3: High Performance Materials and Methods
Editors: Eli M. Pearce, PhD, Bob A. Howell, PhD,
Richard A. Pethrick, DSc, PhD, and Gennady E. Zaikov, DSc

© 2015 by Apple Academic Press, Inc.

CONTENTS
List of Contributors ....................................................................................ix
List of Abbreviations ................................................................................xiii
List of Symbols ...........................................................................................xv
Preface ....................................................................................................xvii
Introduction—Professor Gennady Efremovich Zaikov: Sixty Years
in Science ...................................................................................................xix
Eli M. Pearce, Bob A. Howell, Richard A. Pethrick, and A. K. Haghi
1. Bacterial Poly(3-Hydroxybutyrate) as a Biodegradable Polymer
for Biomedicine ...........................................................................................1
A. L. Iordanskii, G. A. Bonartseva, T. A. Makhina, E. D. Sklyanchuk and G. E. Zaikov
2. The Effect of Antioxidant Drug Mexidol on Bioenergetics Processes
and Nitric Oxide Formation in the Animal Tissues ...............................45
Z. V. Kuropteva, O. L. Belaya, L. M. Baider, and T. N. Bogatyrenko
3. Calcium Soap Lubricants .........................................................................57
Alaz Izer, Tugce Nefise Kahyaoglu, and Devrim Balkose
4. Radical Scavenging Capacity of N-(2-mercapto-2-methylpropionyl)-l-
cysteine—Design and Synthesis of Its Derivative with Enhanced
Potential to Scavenge Hypochlorite .........................................................71
Maria Banasova, Lukas kerner, Ivo Juranek, Martin Putala, Katarina Valachova, and
Ladislav Soltes
5. Magnetic Properties of Organic Paramagnets .......................................93
M. D. Goldfein, E. G. Rozantsev, and N. V. Kozhevnikov
6. Photoelectrochemical Properties of the Films of Extra Coordinated
Tetrapyrrole Compounds and Their Relationship with the Quantum
Chemical Parameters of the Molecules .................................................125
V. A. IIatovsky, G. V. Sinko, G. A. Ptitsyn, and G. G. Komissarov
7. Bio-Structural Energy Criteria of Functional States in Normal and
Pathological Conditions ..........................................................................157
G. A. Korblev and G. E. Zaikov
© 2015 by Apple Academic Press, Inc.
x Contents
8. The Temporal Dependence of Adhesion Joining Strength:
The Diffusive Model ................................................................................175
Kh. Sh. Yakh’Yaeva, G. V. Kozlov, G. M. Magomedov, R. A.Pethrick, and G. E. Zaikov
9. Ways of Regulation of Release of Medicinal Substances from the
Chitosan Films .........................................................................................185
E. I. Kulish, A. S. Shurshina, and Eli M. Pearce
10. A Research Note on Enzymatic Hydrolysis of Chitosan in
Acetic Acid Solution in the Presence of Amikacin Sulfate ..................197
E. I. Kulish, I. F. Tuktarov, V. V. Chernova, M. I. Artsis, and R. A. Pethrick
11. The Structure of the Interfacial Layer and Ozone Protective Action
of Ethylene-Propylene-Diene Elastomers in Covulcanizates with
Butadiene-Nitrile Rubbers .....................................................................205
N. M. Livanova, A. A. Popov, V. A. Shershnev, M. I. Artsis, and G. E. Zaikov
12. A Research Note on Influence of Polysulfonamide Membranes
on the Productivity of Ultrafiltration Processes ...................................225
E. M. Kuvardina, F. F. Niyazi, B. A. Howell, G. E. Zaikov, and N. V. Kuvardin
13. A Research Note on Environmental Durability of Powder Poyester
Paint Coatings .........................................................................................233
T. N. Kukhta, N. R. Prokopchuk, and B. A. Howell
14. A Research Note on Elastomeric Compositions Based on Butadiene
Nitrile Rubber Containing Polytetrafluorethylene Pyrolysis
Products ...................................................................................................247
N. R. Prokopchuk, V. D. Polonik, Zh. S. Shashok, and E. M. Pearce
15. Spectral Fluorescent Study of the Complexation with Anionic
Polyelectroltes on Cis-Trans Equilibrium of Oxacarbocyanine .........257

P. G. Pronkin and A. S. Tatikolov
16. Ozone Decomposition .............................................................................273
T. Batakliev, V. Georgiev, M. Anachkov, S. Rakovsky, and G. E. Zaikov
17. A Technical Note Designing, Analysis and Industrial Use of the
Dynamic Spray Scrubber .......................................................................305
R. R. Usmanova, M. I. Artsis, and G. E. Zaikov
18. Engineered Nanoporous Materials: A Comprehensive Review ..........317
Arezoo Afzali and Shima Maghsoodlou
Index ..........................................................................................................357
© 2015 by Apple Academic Press, Inc.