Photochemistry. Volume 42

288 Pages·2014·28.267 MB·English

by  Angelo Albini, E Fasani, Royal Society of Chemistry (Great Britain)

Photochemistry
Volume 42
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A Specialist Periodical Report
Photochemistry
Volume 42
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54 Editors
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62 Angelo Albini, University of Pavia, Pavia, Italy
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78 Elisa Fasani, University of Pavia, Pavia, Italy
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1 Montserrat Agut, Ramon Llull University, Spain
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g | d Roger Bresol´ı-Obach, Ramon Llull University, Spain
or Marco Caricato, Gaussian, Inc., USA
sc. Cristina Flors, Madrid Institute for Advanced Studies in Nanoscience,
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b Spain
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p:// Jean-Pierre Fouassier, Institute of Materials Science of Mulhouse,
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on Ignacio Fdez. Galva´n, Uppsala University, Sweden
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01 M. Consuelo Jime´nez, Polytechnic University of Valencia, Spain
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3:06. August JRaoclaqnudesLiLnadlehv,e´Uep,pInsastlaituUteniovefrMsitayt,eSriwalesdSecnience of Mulhouse, France
11:4n 19 YMai-gJuuenl AL.iuM,iBraenijidnag,NPoolrymteaclhUnniciveUrnsiivtye,rsCithyinoaf Valencia, Spain
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ed Kazuhiko Mizuno, NAIST, Japan
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blis Santi Nonell, Ramon Llull University, Spain
Pu Oriol Planas, Ramon Llull University, Spain
Daniel Roca-Sanjua´n, University of Valencia, Spain
Beatriz Rodr´ıguez-Amigo, Ramon Llull University, Spain
Rube´n Ruiz-Gonza´lez, Ramon Llull University, Spain
Joaquim Torra, Ramon Llull University, Spain
Takashi Tsuno, Nihon University, Japan
Cristiano Viappiani, University of Parma Italy
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c.or ISBN: 978-1-84973-956-6
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p:// DOI: 10.1039/9781782624547
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permitted under the Copyright, Designs and Patents Act, 1988 and the
Copyright and Related Rights Regulations 2003, this publication may
not be reproduced, stored or transmitted, in any form or by any means,
without the prior permission in writing of The Royal Society of Chemistry,
or in the case of reproduction in accordance with the terms of the licences
issued by the Copyright Licensing Agency in the UK, or in accordance with
the terms of the licences issued by the appropriate Reproduction Rights
Organization outside the UK. Enquiries concerning reproduction outside
the terms stated here should be sent to The Royal Society of Chemistry
at the address printed on this page.
Published by The Royal Society of Chemistry,
Thomas Graham House, Science Park, Milton Road,
Cambridge CB4 0WF, UK
Registered Charity Number 207890
For further information see our web site at www.rsc.org
Preface
DOI: 10.1039/9781782624547-FP005
Volume 42 follow the pattern of previous issues from Vol. 39 on, which
combines review on the latest advancements in photochemistry (every
other year on a part of this discipline) and highlights on some topics.
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00 We thank the reviewers, who maintained their thorough work once
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7-F again, as well as the contributors of highlights. It has been, as usual,
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5 quiteatoughjobtocompleteallofthecontributions(almost)withinthe
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6 planneddeadlines.Wemustadmitthat,hard workasitmayhavebeen,
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7 having the opportunity of seeing such a large wealth of photochemical
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7 research has been a really nice experience.
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9/ We thank the staff of Specialist Periodical Reports at RSC and our
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Photochemistry,2015,42,v–v | v
(cid:2)c TheRoyalSocietyofChemistry2015
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CONTENTS
Cover
Aquote(backcover)fromacentury
agothatunderlineshowdifficultit
wastounderstandthekineticsof
7 photochemicalreactionsuntilthe
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7- statebecamefullyintegratedinthe
54 generalphotochemicalapproach.
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2 Herethereferenceistoanion.Often
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82 atthattimeelectronicexcitationand
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1 ionizationwereconfused,also
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97 becausethelowsensitivityofthe
39/ detectiontechniquesusedfavoured
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1 thechoiceofastrongsource,and
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doi: Z.Phys.Chem.1914,87,93–103.)
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4 Periodical reports: organic and computational aspects
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3:08. August IAnntgreoldouAcltbiionni and review of the year 2013 3
11:4n 19 1 Introduction 3
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Recent method developments and applications in computational 11
photochemistry, chemiluminescene and bioluminescence
Daniel Roca-Sanjua´n, Ignacio Fdez. Galva´n, Roland Lindh and
Ya-Jun Liu
1 Introduction 11
2 Development of methodology (2012–2013) 12
3 Applications (2012–2013) 22
4 Conclusion and outlook 36
Acknowledgments 38
References 38
Alkenes, alkynes, dienes, polyenes 43
Takashi Tsuno
1 Introduction 43
2 Photochemistry of alkenes 43
Photochemistry,2015,42,vii–ix | vii
(cid:2)c TheRoyalSocietyofChemistry2015
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3 Photochemistry of alkynes 69
4 Photochemistry of dienes and polyenes 72
5 Photochemistry of haloalkenes 74
6 Photooxygenation and photooxidation 74
References 76
07 Photochemistry of aromatic compounds 89
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Functions containing a heteroatom different from oxygen 166
Angelo Albini and Elisa Fasani
1 Nitrogen containing functions 166
2 Functions containing different heteroatoms 185
References 188
Highlights in photochemistry
Towards the accurate simulation of UV/Vis spectra in solution: 199
combining the EOM-CCSD method with polarizable solvation
models within state-specific and linear-response formalisms
Marco Caricato
1 Introduction 199
2 Theory 202
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3 Numerical results 207
4 Conclusions 211
References 212
Recentadvancesinphotoinducedpolymerizationreactionsunder 215
400–700 nm light
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5 2 The input of the silyl radical chemistry: a way to a 218
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n Cristiano Viappiani, Montserrat Agut, Rub´en Ruiz-Gonza´lez
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4 and Santi Nonell
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Acknowledgements 267
References 268
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