Table Of ContentEnvironmental Science S Phosphate
e
Phosphate in Soils
l
i
m
Interaction with Micronutrients, Radionuclides and Heavy Metals
“Despite decades of research, there is still much to be learned about the reactions in Soils
and reaction products that occur from the addition of phosphorus to soils. The
ramifications are significant and include providing basic phosphorus needs to
P
plants, interactions with other plant essential elements, and interactions with and
possible immobilization of contaminants in soils. Phosphate in Soils: Interaction
h
with Micronutrients, Radionuclides and Heavy Metals, edited by H. Magdi
Selim, is an excellent summary of state-of-the-art science in this area, with the
o
major emphasis on the interactions between phosphorus and contaminants. Twenty-
nine eminent scholars from around the world author or co-author twelve chapters.
s
Readers will benefit from a thorough coverage of the topic, including basic
Interaction with
chemistry, mineralogy, and relevant case studies, as well as modeling approaches
p
to various processes. This edited volume will surely become a highly cited source
of information for many years.”
h
—Gary M. Pierzynski, Kansas State University, Manhattan, USA Micronutrients,
a
Edited by One of the Best Specialists in Soil Science
Radionuclides
Recent studies reveal that Phosphorus (P) in the form of phosphate, a macronutrient t
essential for plant growth, and crop yields can influence the bioavailability, e
retention, and mobility of trace elements, metal(loid)s, and radio nuclides in soils.
and Heavy Metals
When this occurs, phosphates can affect the dynamics of heavy metals and influence
soil characteristics, impacting soil mobility and toxicity.
i
n
Phosphate in Soils: Interaction with Micronutrients, Radionuclides and Heavy
Metals utilizes the latest research to emphasize the role that phosphate plays in
enhancing or reducing the mobility of heavy metals in soil, and the soil-water-plant
S
environment. It provides an in-depth understanding of each heavy metal species,
and expands on phosphate interactions in geological material.
o
The author includes analytical and numerical solutions along with hands-on
applications, and addresses other topics that include the transport and sorption i
l Edited by
modeling of heavy metals in the presence of phosphate at different scales in the
s
vadose zone.
H. Magdi Selim
K23137
6000 Broken Sound Parkway, NW
Suite 300, Boca Raton, FL 33487 ISBN: 978-1-4822-3679-8
711 Third Avenue 90000
New York, NY 10017
an informa business
2 Park Square, Milton Park
www.crcpress.com Abingdon, Oxon OX14 4RN, UK
9 781482 236798
w w w . c r c p r e s s . c o m
K23137 cvr mech.indd 1 2/4/15 10:20 AM
Phosphate
in Soils
Interaction with
Micronutrients, Radionuclides
and Heavy Metals
ADVANCES IN TRACE ELEMENTS IN THE ENVIRONMENT
Series Editor: H. Magdi Selim
Louisiana State University, Baton Rouge, USA
Permeable Reactive Barrier: Sustainable Groundwater Remediation
edited by Ravi Naidu and Volker Birke
Phosphate in Soils: Interaction with Micronutrients, Radionuclides and Heavy Metals
edited by H. Magdi Selim
Phosphate
in Soils
Interaction with
Micronutrients, Radionuclides
and Heavy Metals
Edited by
H. Magdi Selim
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
© 2015 by Taylor & Francis Group, LLC
CRC Press is an imprint of Taylor & Francis Group, an Informa business
No claim to original U.S. Government works
Version Date: 20150120
International Standard Book Number-13: 978-1-4822-3680-4 (eBook - PDF)
This book contains information obtained from authentic and highly regarded sources. Reasonable
efforts have been made to publish reliable data and information, but the author and publisher cannot
assume responsibility for the validity of all materials or the consequences of their use. The authors and
publishers have attempted to trace the copyright holders of all material reproduced in this publication
and apologize to copyright holders if permission to publish in this form has not been obtained. If any
copyright material has not been acknowledged please write and let us know so we may rectify in any
future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced,
transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or
hereafter invented, including photocopying, microfilming, and recording, or in any information stor-
age or retrieval system, without written permission from the publishers.
For permission to photocopy or use material electronically from this work, please access www.copy-
right.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222
Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that pro-
vides licenses and registration for a variety of users. For organizations that have been granted a photo-
copy license by the CCC, a separate system of payment has been arranged.
Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are
used only for identification and explanation without intent to infringe.
Visit the Taylor & Francis Web site at
http://www.taylorandfrancis.com
and the CRC Press Web site at
http://www.crcpress.com
To the memory of my brother
Sami
Contents
Preface ......................................................................................................................ix
Editor........................................................................................................................xi
Contributors .........................................................................................................xiii
1. Phosphorus-Induced (Im)mobilization of Heavy Metal(loid)s
in Soils ..............................................................................................................1
Anitha Kunhikrishnan, Jinhee Park, Shiv S. Bolan, Ravi Naidu,
and Nanthi S. Bolan
2. Influence of Phosphates on Copper and Zinc Retention
Processes in Acid Soils ................................................................................39
David Fernández-Calviño, Cristina Pérez-Novo, and Manuel Arias-Estévez
3. Phosphate–Uranium Interactions in Soils ..............................................59
John C. Seaman, Shea W. Buettner, and Hyun-shik Chang
4. Influence of Phosphates on Retention and Mobility of Zinc,
Cadmium, and Vanadium in Soils ............................................................97
H. Magdi Selim
5. Influence of Phosphate Fertilizer on Cadmium in Agricultural
Soils and Crops ...........................................................................................123
Cynthia A. Grant
6. Multicomponent Modeling of Phosphate and Arsenic Reactions
and Transport in Soils and Geological Media ......................................149
Hua Zhang
7. Influence of Phosphates on Fractionation, Mobility, and
Bioavailability of Soil Metal(loid)s ........................................................169
Sabry M. Shaheen and Christos D. Tsadilas
8. Effect of Phosphate Addition on Mobility and Phytoavailability
of Heavy Metals in Soils ...........................................................................203
Shiwei Zhou, Zhengguo Song, Minggang Xu, and Shibao Chen
9. Bioavailability of Trace Elements in Soils Amended with
High- Phosphate Materials ........................................................................237
Grzegorz Siebielec, Aleksandra Ukalska-Jaruga, and Petra Kidd
vii
viii Contents
10. Influence of Long-Term Soil Application of Sewage Sludge Rich
in Phosphorus on Heavy Metals Bioavailability to Plants ................269
Wanderley José de Melo, Gabriel Maurício Peruca de Melo,
and Valéria Peruca de Melo
11. Effectiveness of Lime and Glauconite-Phosphorite Containing
Organo-Mineral Ameliorants in Heavy-Metal-Contaminated
Soils ...............................................................................................................293
Maya Benkova and Irena Atanassova
12. Influence of Common Ions on Sorption and Mobility of
Soil Phosphorus ..........................................................................................321
Sabry M. Shaheen and Jörg Rinklebe
