Phase Diagrams and Physical Properties of Nonequilibrium Alloys: 5 Component Amorphous Alloys: A Supplement to Landolt-Börnstein III/37 Series

505 Pages·2023·20.721 MB·English

by  Yoshiyuki Kawazoe, Ursula Carow-Watamura

Yoshiyuki Kawazoe
Ursula Carow-Watamura
Phase Diagrams and
Physical Properties
of Nonequilibrium
Alloys: 5 Component
Amorphous Alloys
A Supplement to Landolt-Börnstein III/37
Series
MATERIALS.SPRINGER.COM
Phase Diagrams and Physical Properties of
Nonequilibrium Alloys: 5 Component
Amorphous Alloys
(cid:129)
Yoshiyuki Kawazoe
Ursula Carow-Watamura
Phase Diagrams and
Physical Properties of
Nonequilibrium Alloys:
5 Component Amorphous
Alloys
o¨
A Supplement to Landolt-B rnstein
III/37 Series
With432Figuresand305Tables
YoshiyukiKawazoe UrsulaCarow-Watamura
NewIndustryCreationHatcheryCenter DepartmentofPhysics,Grad.SchoolofScience
TohokuUniversity TohokuUniversity
Aoba-ku,Sendai,Japan Aoba-ku,Sendai,Japan
ISBN978-3-662-64977-0 ISBN978-3-662-64978-7(eBook)
https://doi.org/10.1007/978-3-662-64978-7
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Preface
Naturalglassesareformedinvariousmaterials,forexample,oxidesandpolymers,
while commercial metallic alloys have a crystalline structure either after slow or
rapid cooling on casting. Metallic glassy alloys were first produced by using
sputtering and rapid solidification techniques at very high cooling rates. Many
amorphousalloysproduceduntilthelastdecadeofthelastcentury,beingmarginal
glass-formers, have been obtained in the shape of melt-spun ribbons or thin films.
Laterrod-shapedsamplesover1cmindiameter(calledbulkmetallicglasses,BMG)
wereproducedbycastingofthealloys,havinghighglass-formingabilityinavariety
ofalloysystemsincludingRare-Earth(RE)metals-,Mg-,Zr-,Ti-,Fe-,Co-,Pd-,Pt-,
Au-, Ag-, Cu-, Ni-, and Ca-based system alloys. These amorphous/glassy alloys
demonstratehighstrength,goodelasticity,highwear,andcorrosionresistance.
Theexistingdataontheglass-formingability(includingchemicalcompositions,
criticalsizeoffullyglassy/amorphoussample,theircharacteristictemperatures,etc.)
as well as physical and chemical properties of metallic amorphous materials have
been collected since the database project AMOR was started in 1993 and are
presentedinthedatabase.
Thefirstvolumeofthisseries,LBIII/37A,presenting6,450compositionsfrom
351 ternary amorphous alloy systems of fully amorphous, mixtures of amorphous
and crystalline as well as crystalline and quasi-crystalline phases in the form of
compositiontrianglesandtables,waspublishedin1996.
Thesecondvolume,LBIII/37B,asuccessorvolumetoLBIII/37A,accumulating
the data on the structural, thermal, mechanical, magnetic, electrical, and optical
properties as well as the corrosion behavior of the ternary alloys listed in
volumeA,waspublishedin2011.Inaddition,another32ternaryamorphousalloy
systems found in the period from 1995 to 2008 were added to volume B updating
importantinformationonternaryamorphousalloys.
Thethirdvolume,LBIII/37C,focusesonquaternarymetallicamorphousalloys,
whichareofgreatinterestforindustrialapplications.Thevolumecoversthegeneral
physical structure, as well as thermal, mechanical, magnetic, electrical, and optical
properties.
The current fourth volume presents the data of five-component metallic amor-
phous alloys, including a large number of specimen obtained by adding a fifth
component to a quaternary alloy; some were obtained by starting from lower
v
vi Preface
component base alloys, and there are a few examples of so-called high-entropy
alloys.
Structural data include diffraction profiles, radial distribution functions, coordi-
nation numbers, interatomic distances, etc. The methods include X-ray diffraction,
small-angle x-ray scattering, small-angle neutron scattering, atom probe field ion
microscopy, electron probe micro analysis, EDX, EXAFS, and XANES Spectra as
wellasX-rayphotoelectronspectroscopy.
Thermal properties include specific heat capacity, Debye temperature, atomic
diffusivity, thermal expansion coefficient, glass transition temperature, reduced
glasstransitiontemperature,crystallizationtemperature,enthalpyofcrystallization,
structural relaxation, supercooled liquid range, melting enthalpy, critical quantities
forformationofamorphousphase,andconfigurationentropy.
Mechanical properties include stress-strain curves, yield strength and strain
values, elastic moduli, hardness, fatigue strength, fracture and critical fracture
temperature,aswellaswearresistance,internalfriction,viscosityandmagnetome-
chanicalcouplingdata.
Magnetic properties include Curie temperature, magnetization curves, coercive
force, remanence, permeability, core loss, saturation magnetic moment, magnetic
anisotropy, susceptibility, magnetostriction, Mössbauer spectroscopy data, quadru-
polesplittingandisomershift,magnetichyperfinefieldandlinesplitting,aswellas
magneticresonancespectra,ferromagneticresonance,etc.
Electrical properties include electrical resistivity and conductivity, temperature
dependenceofresistivity,Halleffectdata,etc.
Corrosion data include potentiostatic and potentiodynamic polarization curves
andcorrosionrate.
We hope that the present volume composed of a collection of five-component
metallic amorphous alloy systems contribute both to fundamental researches and
industrialapplications.
Sendai,Japan Y.Kawazoe
December2022
Contents
PartI
Introduction .............................................. 1
PartII Data
Ag-Al-Co-Cu-La ........................................... 17
Ag-Al-Cu-La-Ni ........................................... 23
Ag-Cu-Hf-Ta-Ti ........................................... 29
Al-B-Cu-Ni-Zr ............................................ 35
Al-B-Fe-Nb-Si ............................................. 41
Al-B-Fe-P-Si .............................................. 43
Al-Ce-Fe-Nd-Si ............................................ 47
Al-Co-Cu-Ga-Zr ........................................... 49
Al-Co-Cu-La-Ni ........................................... 52
Al-Co-Cu-Mm-Ni .......................................... 60
Al-Co-Cu-Nd-Ni ........................................... 62
Al-Co-Cu-Ni-Y ............................................ 66
Al-Co-Cu-Ni-Zr ........................................... 74
Al-Co-La-Ni-Y ............................................ 84
Al-Cu-Ir-Ni-Zr ............................................ 86
Al-Cu-La-Ni-Zr ............................................ 88
Al-Cu-Nb-Ni-Zr ........................................... 91
vii
viii Contents
Al-Cu-Ni-Pd-Zr ............................................ 97
Al-Cu-Ni-Si-Zr ............................................ 99
Al-Cu-Ni-Sn-Zr ............................................ 103
Al-Cu-Ni-Ta-Zr ............................................ 110
Al-Cu-Ni-Ti-Zr ............................................ 114
Al-Cu-Ni-Y-Zr ............................................. 117
Al-Nb-Ni-Ta-Zr ............................................ 119
Al-Nb-Ni-Ti-Zr ............................................ 127
B-C-Co-Cr-Fe ............................................. 132
B-C-Co-Cr-Mo ............................................ 140
B-C-Co-Fe-Pr ............................................. 142
B-C-Cr-Fe-Mo ............................................. 145
B-C-Cr-Fe-Si .............................................. 161
B-C-Dy-Fe-Mo ............................................ 163
B-C-Er-Fe-Mo ............................................. 166
B-C-Fe-Ga-P .............................................. 169
B-C-Fe-Mo-P ............................................. 174
B-C-Fe-P-Si ............................................... 182
B-Co-Cr-Fe-Si ............................................. 193
B-Co-Cu-Fe-Mo ........................................... 197
B-Co-Cu-Fe-Nb ............................................ 208
B-Co-Cu-Nb-Si ............................................ 211
B-Co-Cu-Ni-Zr ............................................ 218
B-Co-Dy-Fe-Nd ............................................ 220
B-Co-Fe-Ge-Ni ............................................ 231
B-Co-Fe-Hf-Nb ............................................ 234
B-Co-Fe-Hf-Ni ............................................ 237
B-Co-Fe-Mn-Nb ........................................... 246
B-Co-Fe-Mn-Si ............................................ 253
B-Co-Fe-Mo-Si ............................................ 256
Contents ix
B-Co-Fe-Mo-Ta ............................................ 259
B-Co-Fe-Nb-Ni ............................................ 262
B-Co-Fe-Nb-P ............................................. 268
B-Co-Fe-Nb-Si ............................................ 272
B-Co-Fe-Nb-Y ............................................. 278
B-Co-Fe-Nb-Zr ............................................ 284
B-Co-Fe-Ni-Si ............................................. 306
B-Co-Fe-Ni-Zr ............................................ 309
B-Co-Fe-Pr-Zr ............................................ 328
B-Co-Fe-Si-Zr ............................................. 332
B-Co-Fe-Ta-Zr ............................................ 334
B-Co-Fe-W-Zr ............................................ 340
B-Cu-Fe-Nb-Si ............................................ 347
B-Cu-Ni-Si-Ti ............................................. 374
B-Cu-Ni-Ti-Zr ............................................. 376
Be-Cu-Fe-Nb-Zr ........................................... 379
Be-Cu-Nb-Ni-Zr ........................................... 381
Be-Cu-Ni-Sn-Ti ............................................ 383
Be-Cu-Ni-Ti-Zr ............................................ 388
B-Fe-Ga-Ni-P ............................................. 396
B-Fe-Nb-Si-Y ............................................. 398
B-Fe-Nb-Y-Zr ............................................. 400
B-Fe-Ni-Si-Ta ............................................. 405
C-Cr-Er-Fe-Mo ............................................ 410
C-Cr-Fe-Mo-P ............................................. 413
Co-Cu-Ga-Ni-Zr ........................................... 415
Co-Cu-Hf-Ni-Ti ............................................ 417
Co-Cu-Ni-Ti-Zr ............................................ 419
Co-Cu-Sn-Ti-Zr ........................................... 422
Co-Nb-Ni-Sn-Zr ........................................... 424
x Contents
Co-Nb-Ni-Ti-Zr ............................................ 430
Cu-Fe-Ni-Ti-Zr ............................................ 435
Cu-Hf-Nb-Ni-Ti ........................................... 440
Cu-Hf-Ni-Ti-Zr ............................................ 447
Cu-Nb-Ni-Si-Ti ............................................ 449
Cu-Ni-P-Ti-Zr ............................................. 452
Cu-Ni-Si-Ti-Zr ............................................ 455
Cu-Pd-Si-Ti-Zr ............................................ 468
Cu-Pd-Sn-Ti-Zr ........................................... 475
Cu-Pd-Ta-Ti-Zr ........................................... 488
Nb-Ni-Ta-Ti-Zr ............................................ 492