Nanoclay Reinforced Polymer Composites: Nanocomposites and Bionanocomposites

395 Pages·2016·11.21 MB·English

by  Mohammad Jawaid

Engineering Materials
Mohammad Jawaid
Abou el Kacem Qaiss
Rachid Bouhfid Editors
Nanoclay
Reinforced
Polymer
Composites
Nanocomposites and
Bionanocomposites
Engineering Materials
The “Engineering Materials” series provides topical information on innovative,
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More information about this series at http://www.springer.com/series/4288
Mohammad Jawaid Abou el Kacem Qaiss
(cid:129)
fi
Rachid Bouh d
Editors
Nanoclay Reinforced
Polymer Composites
Nanocomposites and Bionanocomposites
123
Editors
Mohammad Jawaid RachidBouhfid
Laboratory of Biocomposite Technology, Laboratory of Polymer Processing
INTROP MAScIRFoundation
Universiti PutraMalaysia Rabat
Serdang Morocco
Malaysia
Abou elKacem Qaiss
Laboratory of Polymer Processing
MAScIRFoundation
Rabat
Morocco
ISSN 1612-1317 ISSN 1868-1212 (electronic)
Engineering Materials
ISBN978-981-10-1952-4 ISBN978-981-10-1953-1 (eBook)
DOI 10.1007/978-981-10-1953-1
LibraryofCongressControlNumber:2016936990
©SpringerScience+BusinessMediaSingapore2016
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To Our Parents
Parents of Dr. Mohammad Jawaid
Ziaur Rahman (Father)
Late Razia Rahman (Mother)
Parents of Dr. Abou el Kacem Qaiss
Mohammed Qaiss (Father)
Khadija Ghazouli (Mother)
Parents of Dr. Rachid Bouhfid
Lahcen Bouhfid (Father)
Khadija Lograi (Mother)
Preface
Nowadaysnanoclay-basedpolymericmaterialsdisplaybetterutilizationindifferent
applications. The nanoclay as inorganic fillers results from the exfoliation or the
dispersion at nanoscale into polymeric matrices, which allows the improvement of
nanocomposites properties by adding small quantities of clay due to the high
specific area and the possibility to reach an affinity between the nanoclay and the
polymericmatrix.Recentstudiesreportedaboutfabricationandcharacterizationof
nanoclay-based nanocomposites and bionanocomposites, which illustrated better
mechanical and thermal properties as compared to nanoclay-reinforced polymer
composites.Theproposedbookisfocusedonnanoclay-basednanocompositesand
bionanocomposites fabrication, characterization, and applications. It will also
includetheclassificationoftheclaywhichcanbenano-sized,chemicallymodified,
processing techniques of the nanocomposites based on nanoclay. The readers will
find complete information about nanoclay modification and functionalization,
modification of nanoclay systems, characteristic properties of nanoclay and
nanoparticulate-based nanocomposites, modification of nanoclay systems, geolog-
ical and mineralogical research on clays suitability, role of various polymers and
shape of nanoclays on bionanocomposites, effect of nanoclays on gas barrier
propertiesofpolymersandco-polymersnanocompositesanddifferentpropertiesof
tropical wood polymer nanocomposites, bionanocomposites based on modi-
fied montmorillonite and nanocrystaline cellulose, synthesis of natural rubber/
palygorskite nanocomposites, hybrid polymer layered silicate nanocomposites,
mechanical and thermal properties of halloysite nanotube based nanocomposites,
nanoclay-based hybrid composites for advanced functional materials, 3D Smart
Materials, biodegradable nanocomposites for soil erosion mitigation and nanoclay
reinforced three-phase sandwich composite laminates.
We are highly thankful to all authors who contributed book chapters and pro-
videdtheirvaluableideasandknowledgetothiseditedbook.Weattempttogather
all the scattered information of authors from diverse fields in nanoclay-based
vii
viii Preface
nanocomposites and bionanocomposites and finally produce this venture that will
hopefully become a success. We greatly appreciate contributors’ commitment to
support us in formulating ours idea in reality.
We thank Springer Science+Business Media Singapore Pte Ltd. team for their
generous cooperation at every stage of the book production.
Serdang, Malaysia Mohammad Jawaid
Rabat, Morocco Abou el Kacem Qaiss
Rabat, Morocco Rachid Boufid
Contents
Nanoclay Modification and Functionalization for Nanocomposites
Development: Effect on the Structural, Morphological, Mechanical
and Rheological Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Marya Raji, Mohamed El Mehdi Mekhzoum, Abou el Kacem Qaiss
and Rachid Bouhfid
Characteristic Properties of Nanoclays and Characterization
of Nanoparticulates and Nanocomposites. . . . . . . . . . . . . . . . . . . . . . . 35
Muhammad Shahid Nazir, Mohamad Haafiz Mohamad Kassim,
Lagnamayee Mohapatra, Mazhar Amjad Gilani, Muhammad Rafi Raza
and Khaliq Majeed
Modification of Nanoclay Systems: An Approach to Explore
Various Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
Mohd Amil Usmani, Imran Khan, Naheed Ahmad, A.H. Bhat,
Dhananjay K. Sharma, Jahangir Ahmad Rather and Syed Imran Hassan
Geology and Mineralogy of Clays for Nanocomposites: State
of Knowledge and Methodology. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
I. El Amrani El Hassani and C. Sadik
Bioplastics and Bionanocomposites Based on Nanoclays
and Other Nanofillers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
A.H. Bhat, Imran Khan, Mohd Amil Usmani and Jahangir Ahmad Rather
Oxygen Permeability of Layer Silicate Reinforced Polymer
Nanocomposites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
Sarat K. Swain, Niladri Sarkar, Gyanaranjan Sahoo and Deepak Sahu
Bionanocomposite Materials Based on Chitosan Reinforced with
Nanocrystalline Cellulose and Organo-Modified Montmorillonite . . . . . 167
Meriem Fardioui, Mohamed El Mehdi Mekhzoum, Abou el Kacem Qaiss
and Rachid Bouhfid
ix
x Contents
Hybrid Polymer Layered Silicate Nanocomposites . . . . . . . . . . . . . . . . 195
Hazizan Md Akil, Nur Suraya Anis Ahmad Bakhtiar
and Nor Hafizah Che Ismail
Rubber/Nanoclay Composites: Towards Advanced
Functional Materials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Mohammad Khalid, Rashmi Walvekar, Mohammad Reza Ketabchi,
Humaira Siddiqui and M. Enamul Hoque
Clay, Natural Fibers and Thermoset Resin Based Hybrid
Composites: Preparation, Characterization and Mechanical
Properties. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225
Hind Abdellaoui, Rachid Bouhfid and Abou el Kacem Qaiss
Wear Properties of Nanoclay Filled Epoxy Polymers
and Fiber Reinforced Hybrid Composites . . . . . . . . . . . . . . . . . . . . . . 247
A. Jumahat, A.A.A. Talib and A. Abdullah
Synthesis of Natural Rubber/Palygorskite Nanocomposites
via Silylation and Cation Exchange. . . . . . . . . . . . . . . . . . . . . . . . . . . 261
N.A. Mohd Nor, S.N.A. Muttalib and N. Othman
Impact of Nanoclay on the Properties of Wood Polymer
Nanocomposites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
Md. Saiful Islam, Irmawati Binti Ramli, Sinin Hamdan,
Rezaur Rahman, Ahmad Adib Aiman, Abdul Rasyid
and Amyrah Auni
Mechanical and Thermal Properties of Hybrid Graphene/Halloysite
Nanotubes Reinforced Polyethylene Terepthalate Nanocomposites. . . . . 309
Ibrahim Mohammed Inuwa, Tan Boon Keat and Azman Hassan
Nanoclay Reinforced on Biodegradable Polymer Composites:
Potential as a Soil Stabilizer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329
M.I. Syakir, N.A. Nurin, N. Zafirah, Mohd Asyraf Kassim
and H.P.S. Abdul Khalil
Development and Characterization of Nano Clay Reinforced
Three-Phase Sandwich Composite Laminates. . . . . . . . . . . . . . . . . . . . 357
N.R.R. Anbu Sagar and K. Palanikumar