Nanochemistry: From Theory to Application for In-Depth Understanding of Nanomaterials

628 Pages·2023·15.451 MB·english

by  Wang X., Bashir S., Liu J.L. (ed.)

XuanWang,SajidBashir,JingboLouiseLiu(Eds.)
Nanochemistry
Also of interest
MaterialsScience.
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Incooperationwith:ShanghaiJiaoTongUniversityPress
GengxiangHu,XunCaiandYonghuaRong,
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NanoscienceandNanotechnology.
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MarcelVandeVoorde(Ed.),
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Nanochemistry
From Theory to Application for In-Depth Understanding
of Nanomaterials
Edited by
Xuan Wang, Sajid Bashir, Jingbo Louise Liu
Editors
Prof.XuanWang
TexasA&MUniversityHigherEducationCenteratMcAllen
6200TresLagosBlvd.
McAllen,TX78504-9703
UnitedStatesofAmerica
[email protected]
Prof.SajidBashir
TexasA&MUniversity-Kingsville
MSC161,700UniversityBlvd.,Kingsville,TX78363-8202
UnitedStatesofAmerica
[email protected]
Prof.JingboLouiseLiu
TexasA&MUniversity-Kingsville
MSC161,700UniversityBlvd.,Kingsville,TX78363-8202
UnitedStatesofAmerica
and
TexasA&MEnergyInstitute
FrederickE.GieseckeEngineeringResearchBuilding
TAMU,TX77843-3372
UnitedStatesofAmerica
[email protected]
ISBN978-3-11-073985-5
e-ISBN(PDF)978-3-11-073987-9
e-ISBN(EPUB)978-3-11-073999-2
LibraryofCongressControlNumber:2022939582
BibliographicinformationpublishedbytheDeutscheNationalbibliothek
TheDeutscheNationalbibliothekliststhispublicationintheDeutscheNationalbibliografie;
detailedbibliographicdataareavailableontheinternetathttp://dnb.dnb.de.
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Contents
Commonabbreviations VII
Preface 1
Section1:Overview of nanoscienceandnanochemistry
SajidBashir,WilliamHouf,LuisVillanueva,JianhongRen,JingboLouiseLiu
Chapter1
Nanochemistry:developmentofnanomaterials 33
Section2:Focus onsynthesismethods
S.Bashir,C.Li,Y.Huang,S.Palakurthi,Z.Wang,Y.Olaseni,P.Villarreal,
W.Houf,M.Alexander,J.Ren,J.Liu
Chapter2A
Wet-chemistry-derivednanomaterialsandtheirmultidisciplinary
applications 133
XuanWang,JingboLouiseLiu
Chapter2B
Bottom-upsynthesisofnanomaterials 239
TelliAlia,DaremSabrine,SusheshSrivatsaPalakurthi,JingboLouiseLiu
Chapter2C
Greenpathwaystosynthesizenanomaterials 267
SaurabhVyas,VivekAnand,RoliMishra
Chapter2D
Synthesisandstabilizationofmetallicnanoparticles 307
Section3: Focusoncharacterization methods
HaoZhang,BingbaoMei,ZhengJiang
Chapter3A
Advancesinunderstandingelectrochemicalreactionmechanismsofhighly
dispersedmetalsitesusingX-rayabsorptionspectroscopy 329
VI Contents
DanKong
Chapter3B
Insituspectroscopicstudiesoftheelectrochemistry 357
SohaibMohammed,HassnainAsgar,GreeshmaGadikota
Chapter3C
IntegratedX-rayscatteringandmolecular-scalesimulationapproachesto
probethebehaviorofconfinedfluidsforasustainableenergyfuture 437
Section4:Focus onselect exampleapplicationsof
nanoscience inenergy,environment, andhealth
YeshuTan,IvanP.Parkin,GuanjieHe,
Chapter4A
Electrocatalytichydrogenproduction 463
WenLei,ShaoweiZhang,HaijunZhang
Chapter4B
Nanostructuredmaterialsforelectrocatalytichydrogenevolution
reaction 489
TanveerUlHaq,YousefHaik
Chapter4C
Recentprogressincobalt-basednanosheetsforelectrochemicalwater
oxidation 537
XuanWang,SajidLiu
Chapter4D
Nanoapplication:carboncaptureandconversions 565
RobertS.LuckettEd.D.,MSW
Postface:socialimpact,consequences,andresultsofnanotechnology 583
Biographyoftheeditors 593
Biographyoftheauthors 595
Authorlist 603
Index 607
Common abbreviations
δ Delta
α Elevationangle
λ Wavelength
Φ Polarizationpotential
θ Theta
AC Activatedcarbon
ACN Acetonitrile
AFC Alkalinefuelcell
AOR Alcoholoxidationreaction
ASU Airseparationunit
ATR Autothermalreformingofmethane
BFB Bubblingfluidizedbed
BP Blackphosphorus
CB Conductionband
CBM Conductionbandminimum
CCS Carboncaptureandstorage
CCS CO captureandstorage
2
CCT Cleancoaltechnology
CE Coulombicefficiency
CFS Capacitivefaradicstorage
C Helmholtzlayercapacitance
H
CHP Combinedheatandpower
CLG Chemicalloopinggasifier
CNF Carbonnanofibers
CNT Carbonnanotubes
CO Carbonmonoxide
CO Carbondioxide
2
COF Covalentorganicframeworks
COS Carbonylsulfide
CP Conductivepolymers
CQD Carbonquantumdots
CS Carbondisulfide
2
C Chargelayercapacitance
SC
CTMA Cetyltrimethylammoniumchloride
CV Cyclicvoltammetry
CVD Chemicalvapordeposition
des Desorption
DFT Densityfunctionaltheory
dI Decrementofthelightintensity
DL Doublelayer
DMF N,N-Dimethylacetamide
DMFC Directmethanolfuelcell
DOS Densityofstates
dx Filmthickness
E Occupiedbytheelectrons
https://doi.org/10.1515/9783110739879-203
VIII Commonabbreviations
Ec CBenergy
E Fermilevel
F
ESPW Electrochemicalstablepotentialwindow
ESR Equivalentseriesresistance
Ev VBenergy
FEC Fluoroethylenecarbonate
FOM Figureofmerit
GHG Greenhousegases
GO Grapheneoxides
GPL Gelpolymerelectrolyte
H O Water
2
H S Hydrogensulfide
2
HCN Hydrogencyanide
HER Hydrogenevolutionreaction
HF Heatingfluid
HHV Higherheatingvalue
HOMO Highestoccupiedmolecularorbital
HOR Hydrogenoxidationreaction
HRSG Heatrecoverysteamgenerator
HTMM High-temperaturemixingmethod
HyPr-RING Hydrogenproductionbyreaction-integratednovelgasification
hν Photonenergy
I Lightintensity
IEA InternationalEnergyAgency
IGCC Integratedcoalgasificationcombinedcycle
IGFC Integratedcoalgasificationfuelcell
IHP InnerHelmholtzplane
ISE Inorganicsolidelectrolytes
k Boltzmannconstant
LCI Lifecycleimpact
LDH Layereddoublehydroxides
LSV Linearsweepvoltammetry
LUMO Lowestunoccupiedmolecularorbital
MCFC Moltencarbonatefuelcell
MEA Membrane-electrodeassemblies
MeOH Methanol
MEXT MinistryofEducation,Culture,Sport,Science,andTechnologyofJapan
MH Metalhydride
MIEC Mixedionic/electronicconductors
MO Methylorange
MOF Metal-organicframeworks
Nc EffectivedensitiesofCB
NFCS Non-faradaiccapacitivestorage
NMP N-Methyl-2-pyrrolidone
Nv EffectivedensitiesofVB
OER Oxygenevolutionreaction
OHP OuterHelmholtzplane
OOH Adsorbed(per)hydroxidespecies
OOR Oxidationoforganicreactant
Commonabbreviations IX
ORR Oxygenreductionreaction
PAFC Phosphoricacidfuelcell
PAH Polycyclicaromatichydrocarbons
PANI Porousnanoflowerpolyanilineelectrode
PCE Powerconversionefficiency
PCM Phasechangematerial
PCP Porouscoordinationpolymers
PEMFC Protonexchangemembranefuelcell
PHES Pumpedhydroenergystorage
PM Particulatematter
PPy Polypyrrole
PVA Polyvinylalcohol
QFL Quasi-Fermilevel
RDE Rotatingdiskelectrode
RDS Rate-determiningstep
ROS Reactiveoxygenspecies
SDC Staticdielectricconstant
SEI Solidelectrolyteinterphase
SHE Standardhydrogenelectrode
SIB Sodium-ionbatteries
SNCR Selectivenoncatalyticreduction
SOFC Solidoxidefuelcell
SPE Solidpolymerelectrolyte
SRM Steamreformingofmethane
SSE Solid-stateelectrolyte
STEM Scanningtransmissionelectronmicroscopy
STP Standardtemperatureandpressure
TES Totalenergysupply
TFE Tetrafluoroethylenecopolymer
TGA Thermogravimetricanalysis
TiO Titaniumdioxide
2
TMB Transitionmetalbased
TMO Transitionmetaloxides
TOC Totalorganiccarbon
TXM TransmissionX-raymicroscopy
UPD Underpotentialdeposition
VB Valenceband
VBM Valencebandminimum
VOC Volatileorganiccompounds
WGS Water-gasshift
WtE Wastetoenergy
XAS X-rayabsorptionspectroscopy
XRD X-raydiffraction