N Nitrogen: Supplement Volume B2 Compounds with Noble Gases and Hydrogen

202 Pages·1993·4.535 MB·English

by  Reinhard Haubold, Claudia Heinrich-Sterzel, Peter Merlet, Ulrike Ohms-Bredeman, Carol Strametz, Astrid Wietelmann (auth.), Dieter Koschel, Peter Merlet, Astrid Wietelmann, Peter Merlet (eds.)

1
2 He 10 Ne 18 Ar 36 Kr 54 Xe 86 Rn H,
;
I
9 F 17 CI 35 Br 53 I 85 At
8 0 16 S 34 Se 52 Te 84 Po 71 Lu 03 Lr
1
7 N 15 P 33 As 51 Sb 83 Bi 70 Yb 102 No
6 C 14 Si 32 Ge 50 Sn 82 Pb 69 Tm 101 Md
5 B 13 AI 31 Ga 49 In 81 TI 68 Er 00 m
1F
30 Zn 48 Cd 80 Hg 67 Ho 99 Es
29 Cu 47 Ag 79 Au 66 Oy 98 Cf
28 Ni 46 Pd 78 Pt 65 Tb 97 Bk
with 27 Co 45 Rh 77 Ir 64 Gd 96 Cm
s
ement 26 Fe 44 Ru 76 Os 63 Eu 95 Am -~-
El
of the 25 Mn 43 Te 75 Re 62 Sm 94 Pu
e
Tabl 24 Cr 42 Mo 74 W 61 Pm 93 Np
c
di
erio 23 V 41 Nb 73 Ta 105 60 Nd 92 U
P
22 Ti 40 Zr 72 Hf 104 59 Pr 91 Pa
21 Se 39 Y 57** La 89*** Ae ----- 58 Ce 90 Th
-- es
4 Be 12 Mg 20 Ca 38 Sr 56 Ba 88 Ra -- idn des
I H 3 Li II Na 19 * K 37 Rb 55 Cs 87 Fr *Lantha **Actini
~ ~
,.. J ~ i C1 I oj' i 3 ... iii' i' !iii f i i= .. III ~ n I
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
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Volumes published on "Nitrogen" (Syst. No.4)
Main VoLume 1
History. Occurrence. The ELement - 1934
Main VoLume 2
Compounds of Nitrogen with Hydrogen - 1935
Main VoLume 3
Compounds of Nitrogen with Oxygen - 1936
Main VoLume 4
Compounds with Oxygen - 1936
Supplement Volume B 2
Compounds with NobLe Gases and Hydrogen - 1993 (present volume)
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
N
Nitrogen
Supplement Volume B 2
Compounds with NobLe Gases and Hydrogen
(continued)
With 2 illustrations
AUTHORS Reinhard HauboLd, CLaudia Heinrich-SterzeL, Peter MerLet,
ULrike Ohms-Bredeman, CaroL Strametz, Astrid WieteLmann
EDITORS Dieter KoscheL, Peter MerLet, Astrid WieteLmann
CHIEF EDITOR Peter MerLet
System Number 4
Springer-Verlag Berlin Heidelberg GmbH 1993
LITERATURE CLOSING DATE: MID 1992
IN SOME CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress Catalog Card Number: Agr 25-1383
ISBN 978-3-662-06338-5 ISBN 978-3-662-06336-1 (eBook)
DOI 10.1007/978-3-662-06336-1
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© by Springer-Verlag Berlin Heidelberg 1993
Originally published by Springer-Verlag, Berlin in 1993.
Solkover reprint of the hardcover 8th edition 1993
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Preface
"Nitrogen" SuppL. Vol. 82 continues the description of binary compounds composed
of nitrogen and hydrogen (nitrogen hydrides). While" Nitrogen" SuppL. Vol. 81 covers mono
nitrogen compounds, the present volume comprises compounds having two, three, four,
or more nitrogen atoms. Hydrazine, N2H4, and its ions N2Ht and N2H~+ were not included.
(Reference is made to a voluminous monograph: E.W. Schmidt, Hydrazine and its Deriva
tives: Preparation, Properties, Applications, Chichester 1984, 1088 pages.)
Among the dinitrogen compounds, the diazenyl cation, N2H+, has been extensively inves
tigated, especially in regards to spectroscopic and kinetic properties, because of its occur
rence in interstellar space. Chemically well-characterized are diazene, N2H2, the simplest
unsaturated nitrogen hydride which is used as a hydrogenation reagent, and the hydrazyl
radical, N2H3, which is frequently present as an intermediate during the formation and
decay of nitrogen-hydrogen compounds.
The major portion of this volume is taken up by hydrogen azide or hydrazoic acid,
HN3, the first member in the series of trinitrogen compounds. Known to be highly explosive
in pure form, it can be safely handled when diluted. Thus, a great deal of information
is available mainly on its properties as a chemical reagent and its decomposition processes.
Other compounds with three or more nitrogens which are stable at room temperature
include 2-tetrazene, N4H4, ammonium azide, NH4N3, and hydrazinium azide, N2HSN3. Cyclo
triazane, C-N3H3' and triazane, N3HS' were isolated as Ag+ complexes. The aminodiazonium
ion, N3Ht, and the triazanium ion, N3Ht, form isolable salts. Some other nitrogen hydrides
such as triazene, N3H3' 1,3-tetrazadiene, N4H2, and tetrazane, N4H6, were thought to form
only as intermediates. Occasionally they were identified by physical techniques. In several
cases, where the binary nitrogen hydrides cannot be isolated other than in the form of
organic derivatives, the data available for the organic derivatives were included when they
were thought to be characteristic for the particular unsubstituted N-H parent compound.
A series of other, hypothetical nitrogen hydrides have so far only been studied by quantum
chemical methods.
The volume closes with a few ternary compounds composed of nitrogen, hydrogen,
and noble gases.
Frankfurt am Main Peter Merlet
September 1993