Molecular Nano Dynamics [2 Vols]

790 Pages·2009·15.561 MB·English

by  Fukumura, Irie, Iwasawa

Molecular Nano Dynamics
Edited by
Hiroshi Fukumura,
Masahiro Irie,
Yasuhiro Iwasawa,
Hiroshi Masuhara,
and Kohei Uosaki
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Molecular Nano Dynamics
Volume I: Spectroscopic Methods and Nanostructures
Edited by
Hiroshi Fukumura, Masahiro Irie, Yasuhiro Iwasawa,
Hiroshi Masuhara, and Kohei Uosaki
TheEditors AllbookspublishedbyWiley-VCHarecarefully
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Prof.Dr.HiroshiFukumura publisherdonotwarranttheinformationcontained
TohokuUniversity inthesebooks,includingthisbook,tobefreeof
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Sendai980-8578 otheritemsmayinadvertentlybeinaccurate.
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RikkyoUniversity BritishLibraryCataloguing-in-PublicationData
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V
Contents to Volume 1
Contents to Volume 2 XIII
Preface XVII
About the Editors XIX
List of Contributors for Both Volumes XXIII
PartOne SpectroscopicMethodsforNanoInterfaces 1
1 RamanandFluorescenceSpectroscopyCoupledwithScanning
TunnelingMicroscopy 3
NorikoNishizawaHorimotoandHiroshiFukumura
1.1 Introduction 3
1.2 OutlineofSTMCombinedwithOpticalSpectroscopy 4
1.2.1 RamanSpectroscopy 4
1.2.2 FluorescenceSpectroscopy 6
1.3 TheoreticalApproaches 6
1.4 ExperimentalApproaches 8
1.4.1 STMCombinedwithRamanSpectroscopy 8
1.4.2 STMCombinedWithFluorescenceSpectroscopy 12
1.5 FutureProspects 13
References 16
2 VibrationalNanospectroscopyforBiomoleculesandNanomaterials 19
YasushiInouye,AtsushiTaguchi,andTaroIchimura
2.1 Introduction 19
2.2 SurfacePlasmonPolaritons 20
2.3 Near-FieldOpticalMicroscopyUsingaMetallicNano-Tip 22
2.4 Tip-EnhancedNear-FieldRamanSpectroscopyandImaging 24
2.4.1 RamanSpectroscopy 25
2.4.2 Near-FieldNano-RamanMicroscopy 25
2.4.3 Tip-EnhancedNear-FieldRamanSpectroscopyandImaging 26
VI ContentstoVolume1
2.5 TipEffectonNear-FieldRamanScattering 30
2.6 Conclusion 36
References 36
3 Near-FieldOpticalImagingofLocalizedPlasmonResonances
inMetalNanoparticles 39
HiromiOkamotoandKoheiImura
3.1 Introduction 39
3.2 Near-FieldSpectroscopicMethod 40
3.3 FundamentalSpectroscopicCharacteristicsofGold
Nanoparticles 42
3.4 WavefunctionImagesofPlasmonModesofGoldNanorod–—
Near-FieldTransmissionMethod 42
3.5 UltrafastTime-ResolvedNear-FieldImagingofGoldNanorods 45
3.6 Near-FieldTwo-PhotonExcitationImagesofGoldNanorods 47
3.7 EnhancedOpticalFieldsinSphericalNanoparticleAssembliesand
SurfaceEnhancedRamanScattering 48
3.8 ConcludingRemarks 51
References 52
4 StructureandDynamicsofaConfinedPolymerChainStudiedbySpatially
andTemporallyResolvedFluorescenceTechniques 55
HiroyukiAoki
4.1 Introduction 55
4.2 ConformationofaConfinedPolymerChain 56
4.2.1 PolymerUltra-ThinFilm 56
4.2.2 Near-FieldOpticalMicroscopy 56
4.2.3 StructureofaSinglePolymerChain 58
4.3 DynamicsofaConfinedPolymerChain 61
4.3.1 PolymerBrush 61
4.3.2 FluorescenceDepolarizationMethod 61
4.3.3 DynamicsofaPolymerBrush 63
4.4 Summary 67
References 68
5 RealTimeMonitoringofMolecularStructureatSolid/LiquidInterfaces
byNon-LinearSpectroscopy 71
HidenoriNoguchi,KatsuyoshiIkeda,andKoheiUosaki
5.1 Introduction 71
5.2 SumFrequencyGenerationSpectroscopy 72
5.2.1 BriefDescriptionofSFG 72
5.2.2 OriginofSFGProcess 73
5.2.3 SFGSpectroscopy 74
5.2.4 ExperimentalArrangementforSFGMeasurements 77
ContentstoVolume1 VII
5.2.4.1 LaserandDetectionSystems 77
5.2.4.2 SpectroscopicCells 78
5.3 SFGStudyofthePotential-DependentStructureofWaterataPt
Electrode/ElectrolyteSolutionInterface 80
5.3.1 Introduction 80
5.3.2 ResultsandDiscussion 80
5.3.3 Conclusions 83
5.4 PhotoinducedSurfaceDynamicsofCOAdsorbedonaPlatinum
Electrode 84
5.4.1 Introduction 84
5.4.2 ResultsandDiscussion 85
5.4.3 Conclusions 88
5.5 InterfacialWaterStructureatPolyvinylAlcohol(PVA)Gel/Quartz
InterfacesInvestigatedbySFGSpectroscopy 89
5.5.1 Introduction 89
5.5.2 ResultsandDiscussions 90
5.5.3 Conclusions 92
5.6 Hyper-RamanSpectroscopy 94
5.6.1 SelectionRulesforHyper-RamanScattering 94
5.6.2 EnhancementofHyper-RamanScatteringIntensity 94
5.6.3 Conclusion 96
5.7 GeneralConclusion 96
References 97
6 Fourth-OrderCoherentRamanScatteringatBuriedInterfaces 103
HiroshiOnishi
6.1 WhyBuriedInterfaces? 103
6.2 OpticalTransitions 104
6.3 ExperimentalScheme 106
6.4 ApplicationtoaLiquidSurface 107
6.5 ApplicationtoaLiquid/LiquidInterface 108
6.6 ApplicationstoSolidSurfaces 109
6.7 FrequencyDomainDetection 112
6.8 ConcludingRemarks 113
References 113
7 DynamicAnalysisUsingPhotonForceMeasurement 117
HidekiFujiwaraandKeijiSasaki
7.1 Introduction 117
7.1.1 WeakForceMeasurements 117
7.1.2 PotentialAnalysisMethodUsingPhotonForceMeasurement 118
7.2 Measurement of the Hydrodynamic Interaction Force Acting between
TwoTrappedParticlesUsingthePotentialAnalysisMethod 121
7.2.1 Two-BeamPhotonForceMeasurementSystem 121
VIII ContentstoVolume1
7.2.2 PotentialAnalysisMethodforHydrodynamicForce
Measurement 122
7.2.3 TrappingPotentialAnalysis 124
7.3 KineticPotentialAnalysis 125
7.4 Summary 129
References 130
8 ConstructionofMicro-SpectroscopicSystemsandtheirApplicationto
theDetectionofMolecularDynamicsinaSmallDomain 133
SyojiIto,HirohisaMatsuda,TakashiSugiyama,NaokiToitani,
YutakaNagasawa,andHiroshiMiyasaka
8.1 Introduction 133
8.2 DevelopmentofaNear-Infrared35fsLaserMicroscopeandits
ApplicationtoHigherOrderMultiphotonExcitation 133
8.2.1 ConfocalMicroscopewithaChromium:ForsteriteUltrafastLaserasan
ExcitationSource 134
8.2.2 DetectionofHigherOrderMultiphotonFluorescencefromOrganic
Crystals 135
8.2.3 MultiphotonFluorescenceImagingwiththeNear-Infrared35fsLaser
Microscope 137
8.3 ApplicationofFluorescenceCorrelationSpectroscopytotheMeasurement
ofLocalTemperatureataSmallAreainSolution 139
8.3.1 ExperimentalSystemofFCS 139
8.3.2 ThePrincipleoftheMethodofMeasurementofLocalTemperature
UsingFCS 140
8.3.3 MeasurementofLocalTemperatureforSeveralOrganic
Solvents 141
8.3.4 Summary 146
8.4 RelaxationDynamicsofNon-EmissiveStateforWater-SolubleCdTe
QuantumDotsMeasuredbyUsingFCS 147
8.4.1 SamplesandAnalysisofExperimentalDataObtainedwithFCS 147
8.4.2 Non-EmissiveRelaxationDynamicsinCdTeQuantumdots 148
8.5 Summary 150
References 152
9 NonlinearOpticalPropertiesandSingleParticleSpectroscopyof
CdTeQuantumDots 155
LingyunPan,YoichiKobayashi,andNaotoTamai
9.1 Introduction 155
9.2 NonlinearOpticalPropertiesofCdTeQDs 156
9.3 OpticalTrappingofCdTeQDsProbedbyNonlinearOptical
Properties 158
9.4 SingleParticleSpectroscopyofCdTeQDs 162
9.5 Summary 166
References 167