Minerals as Advanced Materials I

251 Pages·2010·4.03 MB·English

by  Sergey V. Krivovichev

Minerals as Advanced Materials I
Sergey V. Krivovichev (Ed.)
Minerals as Advanced
Materials I
Editor
Prof.Dr.SergeyV.Krivovichev
Department ofCrystallography,FacultyofGeology
St.PetersburgStateUniversity
UniversityEmb.7/9
St.Petersburg
Russia199034
[email protected]
ISBN:978-3-540-77122-7 e-ISBN:978-3-540-77123-4
LibraryofCongressControlNumber:2007942593
(cid:1)c 2008Springer-VerlagBerlinHeidelberg
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Coverillustration:Yakovenchukite-(Y),anewyttriumsilicatewithuniquemicroporousstructurediscov-
eredinKhibinymassif,Kolapeninsula,Russia(KrivovichevS.V.,PakhomovskyYa.A.,IvanyukG.Yu.,
MikhailovaJ.A.,Men’shikovYu.P.,ArmbrusterT.,SelivanovaE.A.,MeisserN.(2007):Yakovenchukite-
(Y)K3NaCaY2[Si12O30](H2O)4,anewmineralfromtheKhibinymassif,KolaPeninsula,Russia:A
noveltypeofoctahedral-tetrahedralopen-frameworkstructure.AmerMineral92:1525-1530)
Coverdesign:deblik,Berlin
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Foreword
This book contains chapters presented at the International workshop ‘Minerals as
Advanced Materials I’ that was held in the hotel of the Russian Academy of Sci-
encesontheImandralake,Kolapeninsula,oneofthemostbeautifulplacesofthe
Russian North, during 8–12 July, 2007. The idea of the workshop originated from
thenecessityofinteractionsbetweenmineralogyandmaterialscience,includingall
aspects of both these disciplines. Many important materials that dominate modern
technologicaldevelopmentwereknowntomineralogistsforhundredsyears,though
theirpropertieswerenotfullyrecognized.Mineralogy,ontheotherhand,needsnew
impactsforthefurtherdevelopment inthelineofmodernscientificachievements,
includingnovelinsightsprovidedbydevelopmentofbio-andnanotechnologiesas
wellasbytheunderstandingofadeeprolethatinformationplaysintheformation
ofnaturalstructuresanddefinitionofnaturalprocesses.
Thematically,thebookcanbeseparatedintoseveralpartsdedicatedtosomespe-
cificideas:zeolitesandmicroporousmaterials(contributionsbyArmbruster,Pekov
etal.,Petersetal.,Yakovenchuketal.,Merlinoetal.,ZubkovaandPushcharovsky,
Spiridonova et al., Khomyakov, Zolotarev et al., Grigorieva et al., Olysych et al.,
Organova et al.), crystal chemistry of minerals with important properties (chap-
tersbyYakubovich,FilatovandBubnova,Krzhizhanovskayaetal.,Britvin,Siidra
and Krivovichev, Selivanova et al., Karimova and Burns), mineral nanostructures
(chaptersbyFerraris,Kovalevski,Voytekhovsky,Krivovichev),mineralsasactinide
host matrices (chapters by Livshits and Yudintsev, Burakov et al., Tananaev), and
biomineralsandbiomineralogy(chaptersbyChukanovetal.,IzatulinaandElnikov,
Frank-Kamenetskaya). Thus, the chapters in this book touch almost all important
pointswheremineralogyintersectswithmaterialscienceandrelateddisciplines.
Wehopethattheworkshopseries‘MineralsasAdvancedMaterials’willinitiate
interestingandfruitfuldiscussionsthatwillhelpustoachievedeeperunderstanding
ofinorganicnaturalmatter.
ThanksareduetotheSwissNationalScienceFoundationforthesupportofthe
firstworkshopoftheseries.
v
Contents
Natural Zeolites: Cation Exchange, Cation Arrangement
andDehydrationBehavior........................................ 1
ThomasArmbruster
Natural Ion Exchange in Microporous Minerals: Different Aspects
andImplications ................................................ 7
Igor V. Pekov, Arina A. Grigorieva, Anna G. Turchkova
andEkaterinaV.Lovskaya
WhyDoSuper-Aluminous SodalitesandMelilitesExist,butNotso
Feldspars? ..................................................... 17
LarsPeters,Nouri-SaidRahmoun,KarstenKnorrandWulfDepmeier
First Natural Pharmacosiderite-Related Titanosilicates and Their
Ion-ExchangeProperties ......................................... 27
ViktorN.Yakovenchuk,EkaterinaA.Selivanova,GregoryYu.Ivanyuk,
YakovA.Pakhomovsky,Dar’yaV.SpiridonovaandSergeyV.Krivovichev
Tobermorite 11A˚ and Its Synthetic Counterparts: Structural
RelationshipsandThermalBehaviour .............................. 37
Stefano Merlino, Elena Bonaccorsi, Marco Merlini, Fabio Marchetti
andWalterGarra
Mixed-FrameworkMicroporousNaturalZirconosilicates.............. 45
NataliaV.ZubkovaandDmitriiYu.Pushcharovsky
Chivruaiite,aNewMineralwithIon-ExchangeProperties ............. 57
Viktor N. Yakovenchuk, Sergey V. Krivovichev, Yurii P. Men’shikov,
Yakov A. Pakhomovsky, Gregory Yu. Ivanyuk, Thomas Armbruster
andEkaterinaA.Selivanova
vii
viii Contents
Tl-ExchangeinZoriteandETS-4 .................................. 65
Dar’ya V. Spiridonova, Sergey N. Britvin, Sergey V. Krivovichev,
ViktorN.YakovenchukandThomasArmbruster
TheLargestSourceofMineralswithUniqueStructureandProperties... 71
AlexanderP.Khomyakov
TrigonalMembersoftheLovozeriteGroup:ARe-investigation......... 79
Andrey A. Zolotarev, Sergey V. Krivovichev, Viktor N. Yakovenchuk,
ThomasArmbrusterandYakovA.Pakhomovsky
Ion-ExchangePropertiesofNaturalSodiumZirconosilicateTerskite .... 87
ArinaA.Grigorieva,IgorV.PekovandIgorA.Bryzgalov
ChemistryofCancrinite-GroupMineralsfromtheKhibiny–Lovozero
AlkalineComplex,KolaPeninsula,Russia........................... 91
LyudmilaV.Olysych,IgorV.PekovandAtaliA.Agakhanov
On the Inhomogeneities in the Structures of Labuntsovite-Group
Minerals....................................................... 95
Natalia I. Organova, Sergey V. Krivovichev, Andrey A. Zolotarev
andZoyaV. Shlyukova
PhosphateswithAmphotericOxocomplexes:CrystalChemicalFeatures
andExpectedPhysicalProperties .................................. 101
OlgaV.Yakubovich
Structural Mineralogy of Borates as Perspective Materials
forTechnologicalApplications..................................... 111
StanislavK.FilatovandRimmaS.Bubnova
Zeolite-Like Borosilicates from the Si-Rich Part
oftheR O–B O –SiO (R=K,Rb,Cs)Systems ..................... 117
2 2 3 2
MariaG.Krzhizhanovskaya,RimmaS.BubnovaandStanislavK.Filatov
StructuralDiversityofLayeredDoubleHydroxides................... 123
SergeyN.Britvin
CrystalChemistryofOxocenteredChainLeadOxyhalidesandtheir
ImportanceasPerspectiveMaterials ............................... 129
OlegI.SiidraandSergeyV.Krivovichev
FeaturesofLow-TemperatureAlterationofTi-andNb-Phyllosilicates
UnderLaboratoryConditions..................................... 143
EkaterinaA.Selivanova,ViktorN.Yakovenchuk,YakovA.Pakhomovsky
andGregoryYu.Ivanyuk
SilicateTubesintheCrystalStructureofManaksite .................. 153
OxanaKarimovaandPeterC.Burns
Contents ix
Heterophyllosilicates, a Potential Source of Nanolayers
forMaterialsScience ............................................ 157
GiovanniFerraris
Fullerene-Like Carbon in Nature and Perspectives of its use
inScience-BasedTechnologies..................................... 165
VladimirV.Kovalevski
Fullerenes as Possible Collectors of Noble, Rare, and Disseminated
Elements....................................................... 169
YuriiL.Voytekhovsky
NanotubesinMineralsandMineral-RelatedSystems ................. 179
SergeyV.Krivovichev
NaturalandSyntheticMinerals–Matrices(Forms)forActinideWaste
Immobilization ................................................. 193
TatianaLivshitsandSergeyYudintsev
Behavior of Actinide Host-Phases Under Self-irradiation: Zircon,
Pyrochlore,Monazite,andCubicZirconiaDopedwithPu-238.......... 209
Boris E. Burakov, Maria A. Yagovkina, Maria V. Zamoryanskaya,
Marina A. Petrova, Yana V. Domracheva, Ekaterina V. Kolesnikova,
Larisa D. Nikolaeva, Vladimir M. Garbuzov, Alexander A. Kitsay
andVladimirA.Zirlin
StabilizationofRadioactiveSalt-ContainingLiquidandSludgeWaste
ontheCeramicMatrices ......................................... 219
IvanG.Tananaev
TheRoleofOrganicMatterinPeralkalinePegmatites:Comparison
ofMinerogeneticandTechnologicalProcesses ....................... 221
NikitaV.Chukanov,IgorV.PekovandVeraN.Ermolaeva
Structure, Chemistry and Crystallization Conditions of Calcium
Oxalates–TheMainComponentsofKidneyStones .................. 231
AlinaR.IzatulinaandVladislavYu.Yelnikov
Structure,ChemistryandSynthesisofCarbonateApatites–TheMain
ComponentsofDentalandBoneTissues ............................ 241
OlgaV.Frank-Kamenetskaya
Index .............................................................253
List of Contributors
AtaliA.Agakhanov
FersmanMineralogicalMuseum,Moscow,Russia
ThomasArmbruster
InstituteofGeologicalSciences,ResearchGroup:MineralogicalCrystallography,
University of Bern, Freiestr. 3, CH-3012 Bern, Switzerland, e-mail:
[email protected]
ElenaBonaccorsi
DipartimentodiScienzedellaTerra,Universita` diPisa,ViaS.Maria53,56126
Pisa,Italy
SergeyN.Britvin
DepartmentofCrystallography,FacultyofGeology,St.PetersburgStateUniversity,
UniversityEmb.7/9,St.Petersburg,Russia,e-mail:[email protected]
IgorA.Bryzgalov
FacultyofGeology,MoscowStateUniversity,119991Moscow,Russia
RimmaS.Bubnova
InstituteofSilicateChemistryofRussianAcademyofSciences,St.Petersburg,
Russia,e-mail:Rimma [email protected]
BorisE.Burakov
LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium
Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg,
Russia,e-mail:[email protected]
PeterC.Burns
DepartmentofCivilEngineering andGeologicalSciences,UniversityofNotre
Dame,156FitzpatrickHall,NotreDame,IN46556-0767,USA
xi
xii ListofContributors
NikitaV.Chukanov
Institute of Problems of Chemical Physics Russian Academy of Sciences,
Chernogolovka,Moscowregion,Russia,e-mail:[email protected]
WulfDepmeier
Universita¨tKiel,InstitutfuerGeowissenschaften,Olshausenstrasse40,D-24098
Kiel,Germany
YanaV.Domracheva
LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium
Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg,
Russia
VeraN.Ermolaeva
InstituteofGeochemistryandAnalyticalChemistry,119991Moscow,Russia
GiovanniFerraris
Dipartimento di Scienze Mineralogiche e Petrologiche, Universita` di Torino –
Istituto di Geoscienze e Georisorse, CNR – Via Valperga Caluso 35, I-10125
Torino,Italy,e-mail:[email protected]
StanislavK.Filatov
Department of Crystallography, St. Petersburg State University, St. Petersburg,
Russia,e-mail:fi[email protected]
WalterGarra
Dipartimento di Chimica e Chimica Industriale, Universita` di Pisa, Via
Risorgimento35,56126Pisa,Italy
VladimirM.Garbuzov
LaboratoryofAppliedMineralogyandRadiogeochemistry,V.G.KhlopinRadium
Institute, 2-nd Site, KIRSI-branch, 1, Roentgen Street, 197101 St. Petersburg,
Russia
ArinaA.Grigorieva
FacultyofGeology,MoscowStateUniversity,119991Moscow,Russia,e-mail:
[email protected]
GregoryYu.Ivanyuk
GeologicalInstitute,KolaScienceCentreoftheRussianAcademyofSciences,
Apatity,Russia,e-mail:[email protected]
AlinaR.Izatulina
DepartmentofCrystallography,FacultyofGeology,St.PetersburgStateUniversity,
UniversityEmb.7/9,St.Petersburg,Russia,e-mail:[email protected]
OxanaKarimova
DepartmentofMineralogy,InstituteofGeologyofOreDepositsRussianAcademy
ofSciences,35Staromonetny,119017Moscow,Russia,e-mail:[email protected]