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About Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations
The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.
Detailed Information
| Author: | B. Meunier |
|---|---|
| Publication Year: | 2000 |
| ISBN: | 9783540669432 |
| Pages: | 327 |
| Language: | English |
| File Size: | 5.11 |
| Format: | |
| Price: | FREE |
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