Table Of ContentMetal-Organic Frameworks for
Chemical Reactions
From Organic Transformations to Energy Applications
Metal-Organic
Frameworks for
Chemical Reactions
From Organic Transformations to Energy
Applications
Edited by
Anish Khan
CenterofExcellence for Advanced Materials Research,
King Abdulaziz University, Jeddah, SaudiArabia
Francis Verpoort
State Key Laboratory ofAdvanced Technologyfor Materials Synthesis
and Processing, Wuhan University ofTechnology, Wuhan,China;
Ghent University– GlobalCampus, Ywonsu-Gu, Incheon,
Republic ofKorea
Abdullah M. Asiri
Chemistry Department, Faculty ofScience, KingAbdulaziz University,
Jeddah,Saudi Arabia; Center of Excellence for Advanced Materials
Research, KingAbdulaziz University, Jeddah,Saudi Arabia
Md Enamul Hoque
Department ofBiomedical Engineering atthe Military Instituteof
Science and Technology (MIST), Dhaka, Bangladesh
Anwar L. Bilgrami
Department ofEntomology, RutgersUniversity, New Jersey, United
States; DeanshipofScientific Research,King Abdulaziz University,
Jeddah,Saudi Arabia
Mohammad Azam
Associate Professor ofChemistry, King Saud University, Riyadh, Saudi
Arabia
K. Chandra Babu Naidu
GITAMSchoolofScience(GSS),GITAMDeemed-to-BeUniversity,
Bangalore,India
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Contents
Listofcontributors xi
1. Metal-organic frameworks and their composites 1
M.RameshandC.Deepa
1.1 Introduction 1
1.2 Metal-organicframeworkcomposites 1
1.3 Characterizationofmetal-organicframeworkcomposites 9
1.4 Conclusion 14
References 14
2. Metal-organic framework for batteries and
supercapacitors 19
M.Ramesh,N.KuppuswamyandS.Praveen
2.1 Introduction 19
2.2 Metal-organicframeworks 20
2.3 Metal-organicframeworksforbatteries 21
2.4 Metal-organicframeworksforsupercapacitors 25
2.5 Conclusion 30
References 31
3. Titanium-based metal-organic frameworks for
photocatalytic applications 37
A.Ratnamala,G.DeepthiReddy,M.Noorjahaan,H.Manjunatha,
S.Janardan,N.SureshKumar,K.ChandraBabuNaidu,AnishKhan
andAbdullahM.Asiri
3.1 Introduction 37
3.2 Preparationoftitanium-basedmetal-organicframeworks
andtheselectionofprecursors 38
3.3 Thestructureoftitanium-basedmetal-organicframeworks 47
3.4 Photocatalyticoxidationreaction 50
3.5 Conclusion 56
References 57
v
vi Contents
4. Electrochemical aspects of metal-organic frameworks 65
H.Manjunatha,S.Janardan,A.Ratnamala,K.VenkataRatnam,
L.VaikuntaRao,S.Ramesh,K.ChandraBabuNaidu,
N.SureshKumar,AnishKhanandAbdullahM.Asiri
4.1 Introduction 65
4.2 Electrochemicalsynthesisofmetal-organicframeworks 67
4.3 Electrochemicalapplicationsofmetal-organic
frameworks 75
4.4 Conclusion 96
Acknowledgment 97
References 97
5. Permeable metal-organic frameworks for fuel (gas)
storage applications 111
S.Janardan,PC.V.V.EswaraRao,H.Manjunatha,K.VenkataRatnam,
A.Ratnamala,K.ChandraBabuNaidu,A.Sivarmakrishna,
AnishKhanandAbdullahM.Asiri
5.1 Introduction 111
5.2 Conceptofporosityinfuelstorage 112
5.3 Permeablemetal-organicframeworksforH storage
2
application 113
5.4 Permeablemetal-organicframeworksforCH storage
4
applications 114
5.5 Permeablemetal-organicframeworksforC H storage
2 2
applications 118
5.6 Permeablemetal-organicframeworksforCO storage
2
applications 120
5.7 Conclusion 120
Acknowledgment 122
References 122
6. Excessively paramagnetic metal organic framework
nanocomposites 127
B.VenkataShivaReddy,N.SureshKumar,K.ChandraBabuNaidu,
K.Srinivas,H.Manjunatha,A.Ratnamala,AnishKhanand
AbdullahM.Asiri
6.1 Introduction 127
6.2 Discussionandapplications 130
6.3 Conclusion 136
References 137
Contents vii
7. Expanding energy prospects of metal-organic
frameworks 139
K.RamaKrishnaReddy,D.PrakashBabu,N.SureshKumar,
G.RanjithKumar,K.ChandraBabuNaiduandAnishKhan
7.1 Introduction 139
7.2 Metal-organicframeworksinLi-ionbatteries 140
7.3 Applicationsofmetal-organicframeworksaselectrode
materialforlithium-ionbatteries 142
7.4 Applicationsofhighconductivemetal-organicframeworks 143
7.5 Utilizationofmetal-organicframeworksaselectric
double-layercapacitors(supercapacitors) 144
7.6 Utilizationoflithium(cid:1)oxygenasseparators 145
7.7 Utilizationofsolid-stateelectrolytes 145
7.8 Applicationsofelectrode(cid:1)electrolytealliances 146
7.9 Fuelcellapplications 146
7.10 Electrocatalyticapplications 147
7.11 Conclusion 148
References 148
8. Metal-organic framework(cid:1)based materials and
renewable energy 153
PrasunBanerjee,AdolfoFrancoJr,K.ChandraBabuNaidu,
AnishKhan,AbdullahM.AsiriandSrinivasanNatarajan
8.1 Introduction 153
8.2 0D-metal-organicframework(cid:1)basedmaterials-nanoparticles 154
8.3 1D-metal-organicframework(cid:1)basedmaterials-nanoparticles 155
8.4 2D-metal-organicframework(cid:1)basedmaterials-nanoparticles 158
8.5 3D-metal-organicframework(cid:1)basedmaterials-nanoparticles 160
8.6 Conclusion 163
Acknowledgments 164
References 164
9. Applications of metal-organic frameworks in
analytical chemistry 167
RuthRodr´ıguez-Ramos,A´lvaroSantana-Mayor,
Ba´rbaraSocasRodr´ıguez,AntonioV.Herrera-Herrera
andMiguelA´ngelRodr´ıguezDelgado
9.1 Introduction 167
9.2 DesirablecharacteristicsofMOFsforanalyticalchemistry
applications 171
9.3 Recentapplications 174
9.4 Conclusionandfutureremarks 223
Acknowledgement 224
References 224
viii Contents
10. Modified metal-organic frameworks as photocatalysts 231
WeiNiandAnishKhan
10.1 Introduction 231
10.2 Structure,merits,andstrategies 232
10.3 Metal-organicframeworkmodification 233
10.4 Applications 236
10.5 Conclusionandoutlook 255
Acknowledgments 256
Abbreviations 256
References 257
11. The sensing applications of metal-organic frameworks
and their basic features affecting the fate of detection 271
TolgaZorlu,LucaGuerriniandRamonA.Alvarez-Puebla
11.1 Introduction 271
11.2 Typeofmetal-organicframeworks 272
11.3 Porediameter 280
11.4 Poremorphology 280
11.5 Combinationwithdifferentnanoparticles 281
11.6 Thesensingapplicationscarriedoutwithmetal-organic
frameworks 283
11.7 Conclusion 287
References 287
12. Thermomechanical and anticorrosion characteristics
of metal-organic frameworks 295
MohammadRamezanzadehandBahramRamezanzadeh
12.1 Introduction 295
12.2 Designofmetal-organicframeworks 296
12.3 Stabilityofmetal-organicframeworks 306
12.4 Application 311
12.5 Conclusion 320
References 321
13. Metal-organic frameworks: preparation and
application in electrocatalytic CO2 reduction reaction 331
RajasekaranElakkiyaandGovindhanMaduraiveeran
13.1 Introduction 331
13.2 Synthesisandpropertiesofmetal-organicframeworks 334
13.3 ElectrocatalyticCO reductionreaction 339
2
13.4 Conclusion 341
Acknowledgment 343
References 343
Contents ix
14. Metal-organic frameworks as diverse chemical
applications 349
ShahidPervezAnsari,AhmadHusain,MohdUroojShariq
andAnishKhan
14.1 Introduction 349
14.2 Electrochemicalapplications 350
14.3 Metal-organicframeworksinsupercapacitorapplications 351
14.4 Wastewatertreatment 355
14.5 Drugdelivery 357
14.6 Conclusion 358
References 358
15. Metal-organic frameworks as chemical reaction flask 365
RakeshKumarAmetaandParthMalik
15.1 Introductiontometal-organicframeworks 365
15.2 Versatilityofmetal-organicframeworks 367
15.3 Metal-organicframeworksaschemicalreactionflask 367
15.4 Utilityofmetal-organicframeworkaschemical
reactionflask 368
15.5 Conclusion 378
Acknowledgment 381
References 381
16. Unique attributes of metal-organic frameworks
in drug delivery 389
ParthMalik,RachnaGuptaandRakeshKumarAmeta
16.1 Introduction 389
16.2 Synthesisofmetal-organicframeworks 391
16.3 Aspiringfeaturesformetal-organicframeworks’application
indrugdelivery:toxicologicalcompatibility,stability,and
biodegradation 394
16.4 Surfacemodificationofmetal-organicframeworks 396
16.5 Synthesisofnanoscalemetal-organicframeworks 397
16.6 Therapeuticefficacyofmetal-organicframeworks 399
16.7 Howmetal-organicframeworkscanadvancethepresent
successofdrugdelivery? 400
16.8 Drugreleasemechanismsofmetal-organicframeworks 402
16.9 Conclusionandfuturedirections 410
References 410
x Contents
17. Metal-organic frameworks and permeable natural
polymers for reasonable carbon dioxide fixation 417
M.Ramesh,M.MuthukrishnanandAnishKhan
17.1 Introduction 417
17.2 Carboncapturetechnologiesandstorage 418
17.3 Postcombustioncapture 418
17.4 Metal-organicframeworks 422
17.5 StrategiesofCO fixation 426
2
17.6 EvaluationofCO adsorbentmaterials 431
2
17.7 Conclusion 434
References 437
18. Nanomaterials derived from metal-organic frameworks
for energy storage supercapacitor application 441
LakshmananGurusamy,SambandamAnandanandJerryJ.Wu
18.1 Introduction 441
18.2 Metal-organicframework(cid:1)derivedmetaloxideand
composites 445
18.3 Metal-organicframework-derivedbimetaloxide
nanostructures 453
18.4 Metal-organicframework(cid:1)derivedmetalsulfide
nanostructures 455
18.5 Metal-organicframework(cid:1)derivedcarbonnanostructures 461
18.6 NiCo-MOF@PNTs 464
18.7 Conclusionandfutureperspective 466
Acknowledgment 467
References 467
Index 471
