Table Of ContentMEMBRANES AND
MEMBRANE PROCESSES
MEMBRANES AND
MEMBRANE PROCESSES
Edited by
E. Drioli
University of Calahria
Cosenza, Italy
and
M. Nakagaki
Kyoto University
Kyoto, Japan
SPRINGER SCIENCE+BUSlNESS MEDIA, LLC
Library of Congress Cataloging in Publication Data
Europe-Japan Congress on Membranes and Membrane Processes (1984: Stresa,
Italy)
Membranes and membrane processes.
"Proceedings of the Europe-Japan Congress on Membranes and Membrane Pro
cesses, held June 18-22, 1984, in Stresa, Italy" -T.p. verso.
Includes bibliographies and index.
1. Membranes-Congresses. I. Drioli, E. II. Nakagaki, Masayuki, 1923- . III.
Title.
TP159.M4E57 1984 660.2/842 86-5076
ISBN 978-1-4899-2021-8
ISBN 978-1-4899-2021-8 ISBN 978-1-4899-2019-5 (eBook)
DOI 10.1007/978-1-4899-2019-5
Proceedings of the Europe-Japan Congress on Membranes and
Membrane Processes, held June 18-22, 1984, in Stresa, Italy
© Springer Science+Business Media New York 1986
Originally published by Plenum Press, New York in 1986
Softcover reprint of the hardcover 1 st edition 1986
All rights reserved
No part of this book may be reproduced, stored in a retrieval system, or transmitted
in any form or by any means, electronic, mechanical, photocopying, microfilming,
recording, or otherwise, without written permission from the Publisher
PREFACE
During the past two decades Membrane Science and Technology has made
tremendous progress and has changed from a simple laboratory tool to large
scale processes with numerous applications in Medicine and Industry.
In this volume are collected papers presented at the First Europe
Japan Congress on Membrane and Membrane processes, held in Stresa in June
1984. Other contributions to the Conference will be published in a special
issue of the Journal of Membrane Science.
This Conference was organized by the European Society of Membrane
Science and Technology and the Membrane Society of Japan, to bring together
European Scientists and Engineers face to face with their colleagues from
Japan; in both countries membrane processes will play a strategic role in
many industrial areas in the 1990s, as predicted by the Japanese project
for Next Generation Industries and by the EEC Project on Basic Techno
logical Research (BRITE).
The large number of participants, of about four hundred from twenty
six countries including USA, Australia, China and Brazil, the quality of
the Plenary Lectures and Scientific Communications made the Conference a
significant international success.
We are deeply grateful to the following organizations that contributed
financial support for the Conference:
Ajinomoto Co., Japan Eisai Co. Ltd., Japan
Alitalia SpA, Italy ENEA, Italy
Asahi Chemical Industry Co. Ltd., ENKA AG, West Germany
Japan Farmitalia Spa, Italy
Asahi Glass Co. Ltd., Japan Fuji Standard Research Inc., Japan
Bellco Spa, Italy Gelman Sciences Japan, Ltd., Japan
Culligan Int., USA IRCHA, France
Daicel Chemical Industries Ltd., Istituto Bancario San Paolo di
Japan Torino, Italy
Daiichi Seiyaku Co. Ltd., Japan Japan Gore-Tex Inc., Japan
De Martini Spa, Italy Japan Organo Co. Ltd., Japan
O.de Nora Imp. Elettrochimici Spa, Kao Corporation, Japan
Italy Kuraray Co. Ltd., Japan
Diemme Filtri SpA, Italy Kurita Water Industries Ltd., Japan
v
Mitsubishi Rayon Co. Ltd., Japan Snow Brand Milk Products Co. Ltd.,
Montedison Spa, Italy Japan
Nomura Microscience Co. Ltd., Japan Solvay & Cie, Belgium
Nitto Electric Industrial Co. Ltd., Suntory Co., Japan
Japan Taisho Pharmaceutical Co. Ltd., Japan
Pierrel Spa, Italy Tokuyama Soda Co. Ltd., Japan
Shionogi & Co. Ltd., Japan Toray Industries Inc., Japan
Snia Fibre Spa, Italy Toyobo Co. Ltd., Japan
We acknowledge also in particular the Italian Oriented Program on Fine
Chemistry (CNR) and its Director Prof. L. Caglioti for the continuous
support to this event.
All the papers published in this volume have been reviewed by members
of the Scientific Committee or international experts in the field. We are
particularly grateful for their cooperation to: G. Alberti, P. Aptel,
T. Fane, C. Fell, A. Gliozzi, T. Hoshi, G. Jonsson, N. Kamo, S. Katoh,
O. Kedem, H. Kimizuka, S. Kimura, Y. Kobatake, T. Kondo, P. Meares,
T. Nakagawa, S. Nakao, J. Neel, A. Nidola, Y. Nozawa, H. Ohya, D. Paterson,
M. Pegoraro, R. Rautenbach, G. Sarti, G. Semenza, M. Sena, H. Strathmann.
Enrico Drioli
Presidente European Society of
Membrane Science and Technology
Masayuki Nakagaki
President Membrane Society
of Japan
CONTENTS
Transport Mechanisms of Organic Ions in Rat Renal
Brush Border and Basolateral Membrane Vesicles 1
R. Hori, K.-I. Inui, M. Takano and T. Okano
Reconstitution of Ionic Channels into Planar Lipid
Membranes by Fusion with Proteoliposomes 9
G. Menestrina and F. Pasquali
Photochemically Activated Electron Transport Across
Unilamellar Liposomes Using Coenzyme Q and
Vitamin Kl as Carriers 17
D. Coutts and R. Paterson
Disorder of Coupled Transport in Renal Brush Border
Membrane Vesicles from Rabbits with Experimental
Fanconi Syndrome Induced by Anhydro-4-Epitetracycline
as a Model of Membrane Disease 23
Y. Orita, Y. Fukuhara, T. Nakanishi, M. Horio and H. Abe
Advance and Perspective in Medical Application of Liposomes 31
Y. Nozawa
Measurement and Interpretation of Friction Coefficients of
Water and Ions in Membrane Polymers 39
M. A. Chaudry and P. Meares
Tentative Classification of Transport-reaction Systems by
SeCDAR-Analysis (Uphill, facilitated and active processes) 55
E. Selegny
The Response of Membrane Systems when Exposed to Oscillating
Concentration Waves 69
P. Doran and R. Paterson
Facilitated Transport of Ions in Asymmetric Membranes 77
M. Nakagaki and R. Takagi
Ion and Solvent Transports Through Amphoteric Ion Exchange
Membrane 85
H. Kimizuka, Y. Nagata and W. Yang
A Selective Parameter for Ionic Membrane Transport
Selectivity and Porosity of Several Passive Membranes 93
A. Hernandez, J. A. Ibanez and A. F. Tejerina
Ionic Permeability of the S18 Saft Carboxylic Membrane 101
A. Lindheimer, D. Cros, B. Brun and C. Gavach
Preparation of Microporous Membranes by Phase Inversion
Processes 115
H. Strathmann
Chitosan Hollow Fibers: Preparation and Properties 137
F. Pittalis and F. Bartoli
Research on the Preparation of a New Type of
Polyarylsulfone Membrane for Ultrafiltration 143
S.-J. Han, K.-F. Wu, G.-X. Wu and Y.-B. Wang
Outer Skinned Hollow-fibers-spinning and Properties 151
J. M. Espenan and P. Aptel
Factors Affecting the Structure and Properties of
Asymmetric Polymeric Membranes 163
A. Bottino, G. Capannelli and S. Munari
Separation Characteristics of Ultrafiltration Membranes 179
G. Jonsson and P. M. Christensen
Separation of Aminoacids by Charged Ultrafiltration
Membranes 191
S. Kimura and A. Tamano
Predicting Flux-time Behavior of Flocculating Colloids
in Unstirred Ultrafiltration 199
R. M. McDonogh, C. J. D. Fell and A. G. Fane
Separation Characterization of Ultrafiltration Membranes 209
G. Trag~rdh.and K. Olund
Influence of Surfactants on the Transport Behavior of
Electrolytes Through Synthetic Membranes 215
D. Laslop and E. Staude
Effects of Antifoams on Cross-flow Filtration of Microbial
Suspension 223
K. H. Kroner, W. Hummel, J. Volkel and M.-R. Kula
Yeast Cell Entrapment in Polymeric Hydrogels: a Kinetic
Study in Membrane Reactors 233
M. Cantarella, V. Scardi, A. Gallifuoco, M. G. Tafuri
and F. Afani
Performance of Whole Cells Possessing Cellobiase Activity
Immobilized into Hollow Fiber Membrane Reactors 241
A. Adami, C. Fabiani, M. Leonardi and M. Pizzichini
Recent Developments of Ultrafiltration in Dairy Industries 255
J. L. Maubois
Electrodialysis of Dilute Strontium Cations in Sodium
Nitrate Concentrated Solutions 263
C. Fabiani and M. De Francesco
Ion-selective Membranes for Redox-flow Battery 273
H. Ohya, K. Emori, T. Ohto and Y. Negishi
viii
Zero Gap Membrane Cell and Spe Cell Technologies vs.
Current Density Scale Up 281
A. Nidola
Electrodialysis in the Separation of Chemicals 299
W. A. McRae
Carrier Facilitated Transport and Extraction Through
Ion-exchange Membranes: Illustrated with Ammonia,
Acetic and Boric Acids 309
D. Langevin, M. Metayer, M. Labbe, M. Hankaoui
and B. Pollet
A Thin Porous Polyantimonic Acid Based Membrane as a
Separator in Alkaline Water Electrolysis 319
R. Leysen, W. Doyen, R. Proost and H. Vandenborre
Porous Membranes in Gas Separation Technology 327
U. Eickmann and U. Werner
Separation of Hydrocarbon Mixtures by Pervaporation
Through Rubbers 335
J.-P. Brun, C. Larchet and B. Auclair
An Energy-efficient Membrane Distillation Process 343
T. J. van Gassel and K. Schneider
Use of Hydrophobic Membranes in Thermal Separation of
Liquid Mixtures: Theory and Experiments 349
G. C. Sarti and C. Gostoli
The Water Structure in Membrane Models Studied by
Nuclear Magnetic Resonance and Infrared
Spectroscopies 361
C. A. Boicelli, M. Giomini and A. M. Giuliani
Preparation and in vitro Degradation Properties of
Polylactide Microcapsules 371
K. Makino, M. Arakawa and T. Kondo
Electromicroscopic Study of Ultrathin Solute Barrier
Layer of Composite Membranes and their Solute
Transport Phenomena by the Addition of Alkali
Metal Salts 379
T. Uemura and T. Inoue
Active Transport in Artificial Membrane Systems 387
Y. Kobatake, N. Kamo and T. Shinbo
+
Electrophysiological Aspects of Na -coupled Cotransport
of Organic Solutes and CI- in Epithelial Cell
Membranes 405
T. Hoshi
Disinfection of Escherichia coli by Using Water
Dissociation Effect on Ion-exchange Membrane 421
T. Tanaka, T. Sato and T. Suzuki
The Characterization of Polymer Membranes as Produced by
Phase Inversion 429
C. T. Badenhop and A. L. Bourgignon
Transport Equations and Coefficients of Reverse Osmosis
and Ultrafiltration Membranes 447
S. Kimura
Transfer of Solutes Through Composite Membranes
Containing Phospholipids 455
E. Sada, S. Katoh and M. Terashima
New Inorganic and Inorgan~c-organic Ion-Exchange Membranes 461
G. Alberti, M. Casciola, U. Costantino and D. Fabiani
The Influence of the Surfactants on the Permeation of
Hydrocarbons Through Liquid Membranes 475
P. Plucinski
Separation of Isomeric Xylenes by Membranes Containing
Clathrate-forming Metal Complexes 483
S. Yamada and T. Nakagawa
Mathematical Modeling of Colloidal Ultrafiltration:
a Method for Estimation Ultrafiltration Flux Using
Experimental Data and Computer Simulations 497
R. Lundqvist and R. von Schalien
Permeability and Structure of PMMA Stereocomplex Hollow
Fiber Membrane for Hemodialysis 507
T. Kobayashi, M. Todoki, M. Kimura, Y. Fujii,
T. Takeyama and H. Tanzawa
An Improved Model for Capillary Membrane Fixed Enzyme
Reactors 515
J. E. Prenosil and T. Hediger
Ethanol Production by Coupled Enzyme Fermentation and
Continuous Saccharification of Cellulose, Using
Membrane Cell-recycling Systems 533
H. Hoffmann, M. Grabosch and K. Schugerl
Enzymatic Determination of Cholic Acids in Human Bile
by Amperometric Oxygen Electrode as Detector 543
L. Campanella, F. Bartoli, R. Morabito and
M. Tomassetti
Synthesis of Polyurethane Membranes for the Pervaporation
of Ethanol-water Mixtures 549
L. T. G. Pessoa, R. Nobrega and A. C. Habert
Separation of Benzene-methanol and Benzene-cyclohexane
Mixtures by Pervaporation Process 563
E. Nagy, J. Stelmaszek and A. Ujhidy
Industrial Separation of Azeotropic Mixtures by
Pervaporation 573
E. Mokhtari-Nejad and W. Schneider
Economics of Industrial Pervaporation Processes 581
H. E. A. Bruschke and G. F. Tusel
Nonisothermal Mass Transport of Organic Aqueous Solution
in Hydrophobic Porous Membrane 587
Z. Honda, H. Komada, K. Okamoto and M. Kai
x
