Martti Toivakka: Paper as a Substrate for AIP

12 Pages·2017·3.01 MB·English

Active and Intelligent Packaging
www.actinpak.eu
Paper as a Substrate for
(Active and) Intelligent Packaging
Martti Toivakka
Laboratoryof PaperCoatingand Converting
Center for FunctionalMaterials
Åbo Akademi University
Martti Toivakka 2017
AIPIA - Active & Intelligent Packaging
Intelligent Packaging
Industry Association (www.aipia.info)
Active Solutions Intelligent Solutions
•Bio-Chemicalactivefilms •Sensors and Tags
•Antimicrobialpackaging •NFC Technology in packaging
•Oxygen, CO2, Gas-scavenging •Printed Electronics
•Moisturecontrol •RFID Technology
•Anti-Oxidation •Track, Trace and Control Systems
•TemperatureControlledPackaging •Telecommunications
•Active labels •IT solutions, software
•Nano-technologyenabledpackaging •Time-and temperature indicators
•Hardware (logistical)
•Supply chain order,-control-and information
systems
•Anti-theft devices
•Tamper proofing and Anti Counterfeit
Systems
•Mobile Commerce
•Transport & Logistics
Martti Toivakka 2017 Modifiedfrom www.attophotonics.com Martti Toivakka 2017
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Fortune-magazine:
”McDonalds Unveils ’McBike’
Bicycle-Friendly Bic Mac Packaging”
Fulton Innovation
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Hype and Unreasonable Expectations… Communicative Packaging –
Bar- and QR(Quick Response)-codes
hhttttpp::////wwwwww..aabboo..ffii//llppcccc
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FFoorrddoomm ooddllaaddee mmaann vviinnddrruuvvssrraannkkaa FFoorrddoomm ooddllaaddee mmaann vviinnddrruuvvssrraannkkaa
aaCvv vvoaamrrss ffmrruuukkttn mmiaacnna ggtjjioovrreddee P ääaddeecllktt vvaiinng..ing – aaCvv vvoaamrrss ffmrruuukkttn mmiaacnna ggtjjioovrreddee P ääaddeecllktt vvaiinng..ing –
NNuu mmaann pprreessssaarr ssaafftteenn uurr eenn ppllaannkkaa,, NNuu mmaann pprreessssaarr ssaafftteenn uurr eenn ppllaannkkaa,,
Bar- and QR(Quick Response)-codes Bar- and QR(Quick Response)-codes
ddooffttaannddee aavv ääkkttaa tteerrppeennttiinn.. ddooffttaannddee aavv ääkkttaa tteerrppeennttiinn..
HHööjj nnuu bbääggaarreenn oo bbrrooddeerr,, ssyysstteerr.. HHööjj nnuu bbääggaarreenn oo bbrrooddeerr,, ssyysstteerr..
LLåått ddeenn hhffiinnttsskkttaapp sskk::oo//gg//eennww rriinnwwnnaa wwkkaall..ll..aabboo..ffii//llppcccc LLåått ddeenn hhffiinnttsskkttaapp sskk::oo//gg//eennww rriinnwwnnaa wwkkaall..ll..aabboo..ffii//llppcccc
NNeerr ii ssttrruuppeenn NNeerr ii ssttrruuppeenn
oocchh oomm dduu äärr ddyysstteerr,, oocchh oomm dduu äärr ddyysstteerr,,
llåått oossss ddrriicckkaa uupppp eenn lliitteenn ttaallll.. llåått oossss ddrriicckkaa uupppp eenn lliitteenn ttaallll..
Martti Toivakka 2017 Martti Toivakka 2017
www.huhtamaki.com/adtone www.huhtamaki.com/adtone
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Electronically Readable Communicative
Communicative Packaging for Medicine
Packaging
RFID (Radio Frequency Identification)
NFC(near field
communication)
StoraEnso PharmaDDSiWireless
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Paper Electronics = Disposable Printed
Communicative Packaging for Medicine
Electronics on/in Paper with Commercial Potential
Incontinence detection, Sensible Solutions Sweden AB
Electro-magneticblocking, Patient adherence tracking
De Barroset al. Pharma DDSi, StoraEnso
Self-cooking soup packaging
StoraEnso PharmaDDSiWireless Fulton Innovation
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Hybrid Products
Product Concepts Based on Electrochemistry
Confidex
•Combine, e.g. silicon-based
Li-ion paper-batteries,
“Zero-Cost Diagnostics” Jabbouret al. RFID-chips with printed antenna:
G.M. Whitesides
›Contactless smartcards and tickets
›Product tracing and copy protection
Walki®Pantenna
Powercoat®Alive
Ultra thin chips
NDSU Printable LEDs
Gas sensor on paper,
Printed bio-sensing platform, Acreo Peltonenet al., FunMat/FlexSens Laser-enabled advanced packaging (LEAP)
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Functional Printing on Paper
InkjettedParticulate Silver Ink
Embedding Intelligence R. Bollströmet al., 2013.
InkjettedPEDOT:PSS-SWCNT Ink
in Paper-based Products
Martti Toivakka
220000 µµmm
Laboratoryof PaperCoatingand Converting
Center for FunctionalMaterials
•Poor performance due to:
Åbo Akademi University
›high surface roughness
›uncontrolled spreading
›uncontrolled absorption
P. Angelo et al.NPPRJ 27(2):486, 2012
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Challenges of Using Paper as Substrate
for Printed Electronics
•Highsurfaceroughnessand porosity, largeporesize
•Hygroscopicityand poordimensionalstability
•Poorlong timeheat resistance
•Complexsurfacechemistry
•Poorbarrierproperties
•Dusty material not allowedin cleanroom
environmentusedby printedelectronics
manufacturers
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Example Substrate Concept
Printed Electronics Requires Surface
for Paper Electronics
Smoothness
•A combination of:
›sufficient smoothness(~50nm RMS),
Calanderedtopcoating
›solvent barrier/sealingproperties (Kaolin) Omya
(DCB, acids, bases etc.), RMS 55 nm
›adjustable printabilityfor given Barrierlayer
functional ink through control of (Latex)
surface energy and surface porosity, RMS 260 nm
›thermal performanceallowing for IR Smoothinglayer
sintering (Kaolin)B asepaper: 80 g/m2 woodfree M y l a r ®25 A0 µm
•Roll-to-roll processable, recyclable RMS 300 nm RMS 30 nm
Precoating
and compostable
(GCC)
RMS 580 nm
Bollström, R., A. Määttänen, D. Tobjörk, P. Ihalainen, N. Kaihovirta, R. Österbacka, J. Peltonen, and M.Toivakka.
"A multilayer coated fiber-based substrate suitable for printed functionality." Organic Electronics10:1020–1023. J. Järnström, P. Ihalainen, K. Backfolk, J. Peltonen: Applied Surface Science 2542 (2008) 5741
Bollströmet al. "Method for creating a substrate for printed or coated functionality, substrate, functional device and its use“, R. Bollström, A. Määttänen, P. Ihalainen, M. Toivakka, J. Peltonen: Chinese patent (ZL 201080006446.5), European patent (2392197)
EPO Patent EP2392197, Chinese Patent ZL 201080006446.5 Martti Toivakka 2017 R. Bollstrom,D. Tobjörk, A. Määttänen, P. Ihalainen, R. Österbacka, J. Peltonen, M. Toivakka,: Org. Electronics, 10, 1020 (2009) Martti Toivakka 2017
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Roughness vs. Conductivity Printing of Functional Materials by Inkjet
Ag comb structure: Silver
-Line width 185 µm Barrier layer Topcoat
-Gap 595 µm
Precoat Smoothinglayer
Basepaper
Silver ink for inkjet:
Silver content 20 wt%
Viscosity 10-13 cps @ 25 °C
Surface tension 27-31 dynes/cm
Määttänen, et al., Colloid Surfaces A 367 (2010) 76-84 Martti Toivakka 2017 Martti Toivakka 2017
Improved Inkjet Printability Through
Flexography as a Fabrication Process
Control of Wettability
Ink: 0.5 wt.% P3HT in o-dichlorobenzene(o-DCB), V = 10 pl
P3HT
PET
Määttänen, A., Ihalainen, P., Bollström, R., Toivakka, M., & Peltonen, J. (2010). Colloidsand SurfacesA: Physicochemical
and Engineering Aspects, 367(1-3), 76–84. Martti Toivakka 2017 Martti Toivakka 2017
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Surface Porosity Minimizes
Commercial Papers for Printed
Characteristic “Squeeze”
Electronics
in Flexography
Arjowiggins Felix Schoeller
Ilford PrintedElectronics Ltd
Low surface porosity High surface porosity
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Intelligent Packaging: from Components
to Devices and Products Low-voltage Printed Transistor on Paper
Sensorcomponent –e.g.,
chemiresistor, piezoelectrics, HIFET (Hygroscopic Insulator FET):
accelerometer, touch sensor
Input/Output–e.g., •Source and drain
electrochromic inks,
colorindicators, Power Supply –e.g., ›AgNP-ink: Inkjet printed
external interface printedbattery, and IR-sintered (10 s)
Device supecreclal,p fauceitlocre, lslolar •Organic semiconductor
Smart label, Package,
Sensor, Diagnostic ›P3HT: Inkjet printed
system… •Dielectric(hygroscopic insulator) FUJIFILM Dimatix, Inc
Memory -e.g., ›PVP: Reverse gravure coated
WORM, combinations
Logiccomponent–
of transistors •Gate contact
transistor, e.g., Ion
modulatingFET ›PEDOT:PSS: Inkjet printed or drop cast
Connectors, Resistors
Mini‐Labo, YasuiSeiki Co.
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“FunPrinter” - Custom-built Hybrid R2R-printed Transistors
Printer for Functional Materials on Paper
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Towards Logic Circuits on Paper
Electronically Readable, Printed
pH Sensor on Paper
CSorbtransistor
characteristics
Inverter Ring-
oscillator
NOR-gate SR-latch
Pettersson, F., Paper-and Membrane-BasedIon-Modulated
Electronics, 2015, PhD thesis, Åbo Akademi Martti Toivakka 2017 Martti Toivakka 2017
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Electrochromic Pixels
Simple Hydrogen Sulfide Sensor
10 ppm HS at 40% RH
2
-1.5 V 0 V +1.5 V
•Flexography/Inkjet-printed
interdigitatedelectrodes P. Andersson, D. Nilsson, P. O. Svensson, M. X. Chen, A. Malmstrom, T.
•Spray-/reversegravurecoated, or Roregmaonnice nel,e Tc.t rKoucghleemr,i cMa.l Bsemrgargtr epnix, e“lAsc ptirvine tmeda tornix p daipsperla”,y sA dbvaasnecde odn M aallt-erials
inkjet-printed 2002, 14, 1460
› Copperchloride
› Copperacetate J. Sarfraz, A. Määttänen, P. Ihalainen, M. Keppeler, M. Lindén, J. Peltonen.Printed copper acetate Pe.le Acntrdoecrhsrsoomn,i cRa. cFtoivrech-hmeaimtriexr ,d Pis. pTleahysra, nAid, vM. .F Buenrcgt.g Mreant,e Pr.r i1n7ta (b2l0e 0a7ll)- 3o0rg7a4n–ic
based H2S sensor on paper substrate, Sensors and Actuators B173:868-873. 3082.
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Printable Demonstrator Circuit for Gas Adjustable Packaging Line for the Future
Sensors on Paper
•Sensors and indicators for modified atmospherepackaging
›E.g. for oxygen and hydrogen sulfide
FunMat/Flexsens/Peltonenet al.
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