Lithium-Ion Batteries Fundamentals and Applications

582 Pages·2015·12.792 MB·English

by  Yuping Wu (ed.)

LITHIUM-ION
BATTERIES
Fundamentals and Applications
ELECTROCHEMICAL ENERGY STORAGE AND CONVERSION
Series Editor: Jiujun Zhang
National Research Council Institute for Fuel Cell Innovation
Vancouver, British Columbia, Canada
Published Titles
Electrochemical Supercapacitors for Energy Storage and Delivery: Fundamentals and Applications
Aiping Yu, Victor Chabot, and Jiujun Zhang
Proton Exchange Membrane Fuel Cells
Zhigang Qi
Graphene: Energy Storage and Conversion Applications
Zhaoping Liu and Xufeng Zhou
Electrochemical Polymer Electrolyte Membranes
Yan-Jie Wang, David P. Wilkinson, and Jiujun Zhang
Lithium-Ion Batteries: Fundamentals and Applications
Yuping Wu
Forthcoming Titles
Lead-Acid Battery Technologies: Fundamentals, Materials, and Applications
Joey Jung, Lei Zhang, and Jiujun Zhang
Electrochemical Energy: Advanced Materials and Technologies
Pei Kang Shen, Chao-Yang Wang, San Ping Jiang, Xueliang Sun, and Jiujun Zhang
ELECTROCHEMICAL ENERGY STORAGE AND CONVERSION
LITHIUM-ION
BATTERIES
Fundamentals and Applications
Edited by
Yuping Wu
CRC Press
Taylor & Francis Group
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Boca Raton, FL 33487-2742
© 2015 by Taylor & Francis Group, LLC
CRC Press is an imprint of Taylor & Francis Group, an Informa business
No claim to original U.S. Government works
Version Date: 20150324
International Standard Book Number-13: 978-1-4665-5734-5 (eBook - PDF)
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Contents
Series Preface ........................................................................................................vii
Preface ......................................................................................................................ix
Editor........................................................................................................................xi
Contributors .........................................................................................................xiii
1. Introduction .....................................................................................................1
Yuping Wu, Xiangyun Yuan, Shiyong Zhao, and Teunis van Ree
2. LiCoO -Based Positive Electrode Material ..............................................19
2
Chenglin Hu, Xiangyun Yuan, Yuping Wu, and Teunis van Ree
3. LiNiO -Based Positive Electrode Materials ............................................35
2
Chenglin Hu, Xiangyun Yuan, Yuping Wu, and Teunis van Ree
4. Spinel LiMn O -Based Positive Electrode Materials ............................59
2 4
Yuyang Hou, Shiyong Zhao, Yuping Wu, and Teunis van Ree
5. LiFePO -Based Positive Electrode Materials ..........................................95
4
Yuyang Hou, Faxing Wang, Shiyong Zhao, Yuping Wu, and
Teunis van Ree
6. Other Positive Electrode Materials .........................................................125
Faxing Wang, Yuping Wu, and Teunis van Ree
7. Negative Electrode Materials Based on Carbon...................................161
Lijun Fu, Yuping Wu, and Teunis van Ree

8. Noncarbon Negative Electrode Materials .............................................225
Lijun Fu, Yuping Wu, and Teunis van Ree
9. Liquid Electrolytes .....................................................................................273
Bin Wang, Xiangyun Yuan, Shiyong Zhao, Yuping Wu, and
Teunis van Ree
10. Solid Electrolytes ........................................................................................341
Yusong Zhu, Shiying Xiao, Yuping Wu, and Teunis van Ree
11. Gelled Polymer Electrolytes .....................................................................399
Yusong Zhu, Shiying Xiao, Yuping Wu, and Teunis van Ree
v
vi Contents
12. Separators .....................................................................................................443
Yuping Wu, Shiyong Zhao, and Teunis van Ree
13. Other Materials for Lithium-Ion Batteries ............................................461
Yuping Wu, Shiyong Zhao, and Teunis van Ree
14. Assembly Processes for Lithium-Ion Batteries ....................................479
Changhe Cao, Xiangyun Yuan, Shiyong Zhao, Yuping Wu, and
Teunis van Ree
15. Electrochemical Performance of Lithium-Ion Batteries .....................507
Changhe Cao, Xiangyun Yuan, Yuping Wu, and Teunis van Ree
16. Applications of Lithium-Ion Batteries ...................................................525
Changhe Cao, Yuping Wu, and Teunis van Ree
Index .....................................................................................................................557
Series Preface
The goal of the Electrochemical Energy Storage and Conversion book series
is to provide comprehensive coverage of the ield, with titles focusing on fun-
damentals, technologies, applications, and the latest developments, including
secondary (or rechargeable) batteries, fuel cells, supercapacitors, CO electro-
2
reduction to produce low-carbon fuels, electrolysis for hydrogen generation/
storage, and photoelectrochemistry for water splitting to produce hydrogen,
among others. Each book in this series is self-contained, written by scien-
tists and engineers with strong academic and industrial expertise who are
at the top of their ields and on the cutting-edge of technology. With a broad
view of various electrochemical energy conversion and storage devices, this
unique book series provides essential reading for university students, scien-
tists, and engineers and allows them to easily locate the latest information on
electrochemical technology, fundamentals, and applications.
Jiujun Zhang
National Research Council of Canada
Richmond, British Columbia

vii

Preface
The history of lithium batteries dates back to the 1970s. Over the past 40
years, a great number of scientists have contributed to the current great suc-
cess of lithium-ion batteries. It would be impossible to do justice to the con-
tributions of all of them in the present work. Therefore, we would like to use
this opportunity to salute all past and current researchers and engineers in
the ield of lithium-ion batteries, especially those who pioneered this ield.
Without their work, we would not have the present knowledge and under-
standing of lithium-ion batteries. Without their work, research and develop-
ment in this ield would not have developed the way that it did. Without their
work, we would not have been able to inish this wide-ranging monograph.
Another salute is to the editor’s late father, Dingfu Wu, on his centennial
birthday. It was his diligence and kindness that kept his poor family going,
even during very tough times, so that Yuping Wu and his brothers and sister
had a chance to study, to graduate from universities, and to grow up.
Finally, the generous inancial support of the China national funds for dis-
tinguished youth scientists (51425301), Nature Science Foundation of China
(NSFC) (21374021), Minister of Science and Technology of China (MOST)
(2010DFA61770), and Science and Technology Commission of Shanghai
Municipality (STCSM) (12JC1401200 and 14520721800), is also acknowledged.
This provided the editor’s laboratory great opportunities to carry out long-
term research work on lithium-ion batteries, providing a solid foundation for
the completion of this book.

ix