Table Of ContentD
ow
nloaded from
https://onlinelibrary.w
iley.com
/doi/ by ibrahim
ragab - C
ochrane G
erm
any , W
iley O
nline Library on [19/12/2022]. See the Term
s and C
onditions (https://onlinelibrary.w
iley.com
/term
s-and-conditions) on W
iley O
nline Library for rules of use; O
A
articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
D
ow
nloaded from
https://onlinelibrary.w
iley.com
/doi/ by ibrahim
ragab - C
ochrane G
erm
LevulinicAcid any , W
iley O
nline Library on [19/12/2022]. See the Term
s and C
(cid:2) onditions (https://onlinelibrary.w (cid:2)
iley.com
/term
s-and-conditions) on W
iley O
nline Library for rules of use; O
A
articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
https://onlinelibrary.w
iley.com
/doi/ by ibrahim
ragab - C
ochrane G
Levulinic Acid ermany , W
iley O
ACAlnaSauudLstiúoaciiJna.Aad.beMleLoiPtmalaatform Chemical for Value-Added Products nline Library on [19/12/2022]. See the Terms and C
(cid:2) DBFIRBneriiasoadatzneidntirileucaetalJlealUanoPnef.iRivCPreo.hirneFsmitetoyrisnotrafynRidoedseJaneiro onditions (https://onlinelibrary.wiley.com (cid:2)
/term
s-and-conditions) on W
iley O
nline Library for rules of use; O
A
articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
T©h2is02e3diJtoiohnnfiWrsitlepyu&bliSsohnesdL2t0d23 nloaded from
Aipwnelwlramwrniygi.wthtfeotilsdremrybe.yscoeolrramvbwey/.dgAao.nd/Nypvoeimcrpemeaaorintsnssoih,foeotnlhwesi.csttorpouonbbiltcia,ciamntiepocenhrmamniaiscysaibol,enprtheoportreooucdsouepcymeidna,gtse,trroiearcelodfrridonminagtrhoeitrsroiteittvhlaeelriwssyaissvteea,mielax,bcolereptatrtaanhssttmp:i/t/ted, https://onlinelibrary.w
TherightofClaudioJ.A.Mota,AnaLúciadeLima,DaniellaR.Fernandes,andBiancaP.Pintotobeidentified iley.com
aRJosehgthinsetWearueildtehyOo&ffirscSoeofsnths,isInwco.,r1k1h1aRsibveeernStarseseetr,tHedobinokaecnco,rNdJa0n7c0e3w0i,tUhSlaAw. /doi/ by ibrahim
JohnWiley&SonsLtd,TheAtrium,SouthernGate,Chichester,WestSussex,PO198SQ,UK ragab - C
Fuosradtewtwaiwls.owfioleuyr.cgolomb.aleditorialoffices,customerservices,andmoreinformationaboutWileyproductsvisit ochrane G
erm
Wapipleeyaraslsinopstuabnldisahrdespirtisnbtovoekrssiionnasovafrtiheitsyboofoeklemctaryonnioctfboermavaatsilaabnldebinyoptrhinetr-ofonr-mdeamtsa.nd.Somecontentthat any , W
TaAwLIfltoonnfirolimaltderwvhdeoq/iiveteotuoahiwmorifnepefiwiyaortmnLsrfptfiakeraoaornsanffiorbn:ddmtdigWl,eluieoiarmtavcyeiittnliat/aaeeoDlggorsyunkeririaasnsenrvctnesteealt,eldanrhatoaiehtdtemrrihetconUdheehrgireenn,WmvtoefipoiotfqeicrelrWtnoueedmhptyifaeipSoeaolrmtrurotnra,itagsoyteeaeeonndnmostotayfipaofnrmtrnenehotdoxgtehvrpdiioioardeisttdfirerhhbieecdmeeomasrroipteniakcteonhroc.tntkihutanissenvl,goetrcpsrerh,aoiaeraacwgesnnkegnyaagniensgectrtesdshes,i.riamneneJnqodsagguehyoetrinrvstpnaemoiWodnrrteneimtibmlnnheetaseye,utrnari&ksnuntesascSddltotorirfdwuoneJencgisovtt,suhhiiIoclfonnaeonutcsrWsit,.oeotiwniashrlcsereni,hiyntoratd&ectenahinadcdSesapsotemthoernioiecriscmnis,caaIuoltoin,esnrfspdcgsi.ieoteadncne.t iley Online Library on [19/12/2022]. See the Term
(cid:2) upowsoioucnaofrrrsnaflggenatdeoraaphgtrsrennaaeeamrririinsneaczziattnponaaeaitnergttddiniieostoodthfsenhoonnienenfirnd,,rstgmwwesoatwaidetoeenethsdofibbrvamrecntssetkhhdiiostta,tiaeet,hwsytn,,mwhewanootearrpeorroyinbauttrpptiimnkbbnelrrioolengttaaiyhddssknsshuuauoeaadteccrilnntrestttadfihposimibstseepmrnlcarneerpeieyaepofiusfftcroptesecbaerrrearflusroioinlyeesatlvrogyihndliosauadetdntagorreopisterssaia.odicoipnnrWrtlntuiardirntosichaehmamutorciiuilesloroeoaatnmnwwhtrltdilh.ooompaewYernrrurseorkaiparannuerpluanrgndossbastadtsphinlaaeteioroitsts.ocroiehuesNifwmnetleesdasor,isetttsiihacihnwntioonoetcmanrsnndleirusnfaaarsaouadpylnfurolnisedtmtnrtetch/hmwygrtoaovitimkrwasritocsethpwiaie.ttohoyhahsoTnta.eroebhsvTknoupeaie.hsrettcciTueccwslarisihueelamaoerearsdldrvaitoivkfsitecautcaitdyhcicetrwseietcsooosiehtrratrnohhenoecblareadofxdeetntmfswseauyttnnprireittdalmffhheteetoepdtegrrhlntiibeseeeysdsins s and Conditions (https://onlinelibrary.wiley.com (cid:2)
adbiLnpeiisbcpalirirdpaaoeprbpnyelretaoiaarffloet,Cedrc.ooabFnnneugystrrweetlqhosesuseesCern,noarwtfteiaphaalldreo,onegofirirtnsthogsoi-thsrihnowaeu-nrPolyddrukaobbmtlweihcaaeaagsrwteicwoasonr.rmeiDtttmheanateatra:cwniaedlbwdsiahtmeesnalgiistetsies,dirneincaldut.hdNiisnewgitohbreukrtmtnhoaetyplihumabviltieesdhchetraonnsgpoeredcaiuoartl,horsshall /terms-and-conditions) on W
Names:Mota,ClaudioJ.A.,author.|Lima,AnaLúciade,author.| iley O
TDIdieteslFpBrnecereit:rfaorieiLfinndpreeucaetviranncosutcdnP:sleei.L:n/ssPHC,iCaicCDnonlabatNdaocuon.ii2kddnie0eido:ln2lea2a,Jx.0Ns.AR3uJ..8s,M:t1aaW1uio2nttihaal(epob,yrrAl,.ein2n|p0tPa)l2iaL|n3túLf.too|cCr,iImCaBnNcidacleuhn2Ldec0amei2ms2Pi0bcae3ai,rb8leDls1fiao,o1nrag3uirve(ataelhpllbauohoerRio.c-a.kadF)lde|reInSdaBnNdes, nline Library for rules of use; O
A
SCLLCuCColabv99Dsreje77seebDri88ccofiC11Dotosc11re:ka5d11sLt499riiaC7goe88v/ncn11Sa.o:44:0HirlW663Lad:696CbKi56–allCveeed((atycceQaoi2lptlnoDa3uhtib/hb3ctelt4))eanp1|cgsa.iI:K2td/S0/h2sBl2.tcNMt2cp1n79s1.:87l2/o8/32lc10c.1gc21no39v.(l8/op12cr40i.gn62o82t)v90/|3(2L8a01dC21oC22b0Qe3p8D1d31f4)31|.KIS2B(Nebook)| articles are governed by the applicable C
C©osvteorkIpmica/pgeixsa:b©aytc;hMaorale/AcudloabreStSrtuocctkurPehso:tCoosu;©rtePseygogfyD_Manaireclola/pRi.xFaberanya;n©dyebsernardi/pixabay; reative C
om
m
Setin9.5/12.5ptSTIXTwoTextbyStraive,Chennai,India ons License
(cid:2)
(cid:2)
D
ow
nloaded from
v https://onlinelibrary.w
iley.com
/doi/ by ibrahim
ragab - C
ochrane G
erm
Contents any , W
iley O
11.1 HALPUerbsievesofutsuao,ltcriSneytaihcafeenAxtdAicyiuPdtrh1–oopHresristiteoixsry,1Properties,GlobalMarket,Direct nline Library on [19/12/2022]. See the Term
1.2 GlobalMarket 8 s and C
(cid:2) 111...345 DTCRoeoirxfneeicccrlietutnUydcosienefssgLRe1ve15um0lianrikcsAc1id3andInorganicLevulinates 12 onditions (https://onlinelibrary.w (cid:2)
2 ProductionandTechnologicalRoutes 19 iley.com
2.1 ProductionandTechnologicalRoutesfromBiomass 19 /term
222...222..11.1 PMPhreeyctsrhiecaaantlmicPaerlnettroe2af4tLmigennotcel2lu3losicBiomass 23 s-and-conditions) on W
2.2.1.2 Microwave 25 iley O
22222.....22222.....21222....3123 CUAAIohcllnktierdiamaclsHiLioncyiueqadnluHrdPioydrldysesrt2roi5sel2ya7stmi2s5en2t6 25 nline Library for rules of use; O
222222......222222......333332.....31244 APSLSOtuhimreqpgyaumasemiinrdcocooErnHscixitohaoiplcetvlFamoWlisbiCia2ceotOa7rnelE2r(Px(ESrLpEexHatp)rnlWeosasi2)toi9monne2(nA9tF30E2X8) 30 A articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
vi 22Co..23n.t4ents BPriooldougcictiaolnPoreftLreeavtumliennictAc3i1dfromLignocellulosicBiomass 32 https://onlinelibrary.w
2.3.1 ProcessesforLAProduction:HomogeneousCatalysts 35 iley.com
2222....3333....3524 PDPTrrhoooewccBeenssisssoteerfissenaffeoomrrPPLLrorAAcoecPPserrssoosoddofuufLccLAttiiAooPnnRr::oeBHdciueoptcvheteariroosynigceSn4y4e2so1tuesmCsata4l0ysts 38 /doi/ by ibrahim ragab - C
22..45 CCoomncmluesricoinalP4la7ntsfortheProductionofLA 44 ochrane Germ
References 47 any , W
iley O
333333.....11111....1234 EDAAMLoefslliavccrtOeieoounrrchhlgiitfiPoonaPrcllanyyoratiossdectiiidussoaDucnoonectffdirtooiF5ifovIn-nuaLnHorRtefyfirvuovrgdoueuraramsltonielnx–isctyihcmM7LeAe66aeAv5citunhildclyPionlrhFao6otud5elurysfscuDitsrieoaorlnfivPRa8oot2liuyvtseecsshaanc6ad5riUdseess 71 nline Library on [19/12/2022]. See the Term
3.1.5 ProductionofLevulinateInorganicSalts 86 s and C
(cid:2) 33333.....33233...231 FUPFImolusaoeepsdsltoiAorcatfindazOddneircrCtsgeivoaaesnns9midc0eLMt8ie9cavrukl8ein8taotfetDheerLiveavtuilviensate8D8erivatives 87 onditions (https://onlinelibrary.w (cid:2)
3.3.4 Solvents 91 iley.com
3.4 UsesofInorganicLevulinateDerivatives 93 /term
3333444......444511....1231 ACMCLRLγ-eeeoonVivvfssntaeuucmiclrflelerleiielunernnltoeasiiiccilzccneoa,eAesAcnPocAtcohiuddina9ds9dre6HA5Hmit(ypiGydavpdcreVloeriLocuga)get9iten3cinoaa1antl0,tisoi7aonnnd9P4F1ro0oo7dducts93107 s-and-conditions) on Wiley Online Library for rules of use; O
444444......211131....1111....2134 2GP1LA-,eeVl4Mrkv-fLyuPoeleltrVihVnmneytairaalcls-ennutArecesatcedrtEiieaodotshfhltyGoa(d1n1Vγr,o14-oLVl3-fPuaaDlsre1aFOr1nou1)l(ea2lc-1AtMo1dn2TdeHitFiv1)e14111113 A articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
44..33..12 CGoVnLvteorsBiounteonfeGsVanLdinHtoyd1r,o4c-ParDbOonasnd121-7MTHF 115 Contents vii https://onlinelibrary.w
4.4 HomogeneousandHeterogeneousCatalystsfortheEfficient iley.com
444...444...122.1 CPNCroooepnncpvpioeerurres-csBiioMoanuseesotdafMlLCCeAatataattloalCylGysastVtstasLly1s1t2125211125 /doi/ by ibrahim ragab - C
44..44..22..32 ZNiircckoenl-iBumas-eBdaCseadtaClyasttaslys1ts27130 ochrane Germ
4.4.2.4 Iron-BasedCatalysts 130 any , W
4.5 HeterogeneousCatalystsfortheConversionofLAandGVLto iley O
4445...786 PC1RCT,aayeo4tprfn-ebePecnrosDletnuonOSysfceilHeoaaRsnnryecddahr1c21oot3-3igMf8o8eLnnTAsaHotHiFfnyLgdeA1rvo3ugg2leeinnntiacstAioc1ni3d5–13K7etalsandOther nline Library on [19/12/2022]. See the Term
DerivativesFormedUponReactionwiththeCarbonylGroup s and C
(cid:2) 555...112.1 LLSoUufeesvvecLcuuseivllniiunni1lcici4cnAA9iAcccciiAdiddcEidEs1.st5Ptee8rrroKKdeuetctaatlislosMnMaRaioinnuRtUeossu,etTseesch1n51o35l0ogies,andMain onditions (https://onlinelibrary.w (cid:2)
5.2.1 PetrochemicalandBiotechnologicalRoutes 158 iley.com
5.2.2 LevulinictoSuccinicAcid 163 /term
555...233..31 Sδδ--uAAcmmciniinnicoollAeevvciuudlliiMnniiacciAAnccUiiddse(MsDaAi1nL6AU4)seMsain16R9outes 167 s-and-conditions) on W
55555.....44655..11 5D5CDR--eoiiMMppfnehheecreettlehhunnnyysoocilllleo--iiNNsccn--LAAAe1c1llvi8kk8du5yy5lMlli--n22ai--ciPPnAyyRrrcrroioodulliitMddeoosanninee1MMU79saaeiisnnUR1os8eu1stes171771 iley Online Library for rules of use; O
A
66666....4231 PSLLBeureioovvgruduaelurlfiii-ncnBnticiaceosrAAneyccdoiiddfB1γiia9on-nV7rdteahfilLeenerCeovroluyanlcitnteo1axnt9tee8osifnfraoaBmSiuoagreSafiurngCeaarrnyCeaBn1i9eo7rBeifionreefiryner2y01200 articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
viii 66Co..65ntents CLAonicnluthsieoCnsont2e0x6tofaBiodieselPlant 204 https://onlinelibrary.w
References 207 iley.com
Index 209 /doi/ by ibrahim
ragab - C
ochrane G
erm
any , W
iley O
nline Library on [19/12/2022]. See the Term
s and C
(cid:2) onditions (https://onlinelibrary.w (cid:2)
iley.com
/term
s-and-conditions) on W
iley O
nline Library for rules of use; O
A
articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
ix https://onlinelibrary.w
About the Authors iley.com
/doi/ by ibrahim
CeRniloagiudndeeieoJraiJnn.geAir.ofMro(UmotFaRthhJ)oe,ldwFsheaderedereaghlreeUealnisniovecohrbsetimatyiniceoadfl ragab - Cochrane G
his PhD in chemistry. He is full professor of erm
chemistry and chemical engineering, as well any , W
as director of the Institute of Chemistry of the iley O
(cid:2) aSIMpbhinnncouatedivadbeeduirlrnncdaiesccoglstsa,erntatis,otveihlfoetssahenortrsh(eesheAi,eosiTfaBgntoeJamhI,cocbQeutuholassUirnnrtsenggohIdhaeMleaooltdoirg)nnont,ysoifgcetrbCPhlvaeioerepOosirfp,mz2aIltpelnihaUacinsfenattrsUstCSoToeitothtlSionfveWaitaFmoeBzacrrttCtnRaasnAiateQBe,ihnstlaJtoSit.yrha.sestoiynascinnHfemnPHozioids(e,rintePrABielhinsmiaJrzbSriaCtetoiilesoaorzisanuSy,scfzcoetautr)oaiiigCku,leon(elioifsRlhtvntralaraa.fyheoeSenanlbHsonamSmCnd(ooernBASed)farbid.BfaQcorsFpyCecactsHCfA,ahlipoahltlorameeohrPactStntoamwinfieE)oowascecl,dcyR.rtiileMapclieoisAHsoJoesiatafs.estwhnmtilteyxhastHeeasshiweasoec(cfnerenSroSfucaaiidoBntficnrritRomm1dsrahQACrteo6AneehãsmCn)O0yd.Coc,eatSCC2aeBsNlwredmMchhrecOdPSieiaeeasetbiaoqmmzmmehptnetcoiahtetlyraiiirurtiiegccinaihficarootaaaanhdyeecsfflll, nline Library on [19/12/2022]. See the Terms and Conditions (https://onlinelibrary.wiley.com/term (cid:2)
A(2n01a1)LiúncCiahedmeicLailmScaiernecceesivwedithhTerecBhAnodloeggirceael s-and-conditions) on W
Assignments in Chemical Sciences from the iley O
FSd(sUtheeugdeFdreRryereeJac()sl2e,fUi0rvBo1ner7mdia)vzheFairleet.srdiLteSMyMrhaSoelCcfUPhU(2n/abI0isMve1re3sAlr)tâsa/nairUtndtyeFdioadRdf(JRopUciooFotsnoUtdrdead)o,lJecBa(vt2noer0alero1zairp7itloe)-. nline Library for rules of use; O
A
paoforocuussmonatbeiroimalasswsittrhanvsafroiromusataipomfmAiUpnsoltnFroeiarcanRmyncaltJodyteaimtwnoaaticntndph,aUssdlesli,oFrhaCsreneRebuhvsceJciaheesnhlmeaautcasnraoipssdeftnrotishrootreayrefnaoCetrealsrOcrtesoihoos2nftegerhcseapoaeanriiotpcnlIeltthnyorhuteemsuherrtseseieeDt.acrruaeivatrtcpoeteaLaiarhlorAysotfy.smRfdtCAsHmrehotnwCeegttsimeOhtoolhes/--f articles are governed by the applicable Creative Com
m
ons License
(cid:2)
(cid:2)
D
ow
nloaded from
x AbouttheAuthors DsoarnaitetlhlaeRD.epFaerrtmnaenndteosf OisrgaanniacdCjuhnecmt ipsrtoryfeas-t https://onlinelibrary.w
theInstituteofChemistryoftheFederalUniver- iley.com
saauinntdydiveodegforrsecRiettioyori,nadateleclh(Jw2ae0nmit0eh9iisr)tsoripny(eUcc(hi2Fae0Rlmi0zJ1a)i),st,tiBromyrnaafzrisonitlem.prS’etshhter(eo2hsl0eao0uml4dm)es, /doi/ by ibrahim ragab - C
cChheemmiissttrryy. PShroefeisssaiopnearlmMaansetenrt’spProrofegsrsaomr iinntthhee ochrane Germ
National Network (PROFQUI) at the Institute any , W
of Chemistry, UFRJ. She has been working at iley O
utcvahaantietldloailLzrmyiaAzstaaiiRstoteiHnaor.rinCae,Olabsdi,ieonevfsuetplehoelespcimpearnleolvynditrucoofcontrirrmoeCnleaOnatten2,ddceatncophetrebugmiroye,imcaaaannlssdds, nline Library on [19/12/2022]. See the Term
(cid:2) Bf(dFBuHrUoenrioeaadcEimrvztneRoeirrclreraJ)taas).slhiletPeaSaUyd.nhrencSPdfegohitivrarnoecetfbeeotoraotssncaipUuttig(iyons2nrnesea0uitdodd1vdefe3uodohr)acnRsettiiteiortnotoydrhmaceiwldonhaefcosescatrmtahRektJyaareiisl’onmsyat(er2ttiiy(id0scr2tte1o0frht4ry0reoJ–(a9a(mU2n)2ns0sF0aea2ft0mRoin1hr6rJ)doee)-,. s and Conditions (https://onlinelibrary.wiley.com (cid:2)
moScahtharebteioroisnpnraocoladsfopultecuavtrsue,cl,aoinnfaoidncudCnaOcduie2dtricliiaonzpfattotuCiorvanearlabesnortnadorlAcatuoicrnptov.EneSnerhseiaerognniyds,. /terms-and-conditions) on W
currently a substitute professor at the Depart- iley O
mscieennttiofifcAanrtailcyletiscainl Cinhdeemxeidstrjoyuartntahlse,3UbFoRoJk. Schheapitsetrhs,eaanudth2opruobrlischoeadutbhooorkosf. 14 nline Library for rules of use; O
A
articles are governed by the applicable C
reative C
om
m
ons License
(cid:2)
