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<span>SYLLABUS- B.SC. CHEMISTRY VI, INORGANIC CHEMISTRY-VI</span><br><span>B.Sc. VI Semester; I Paper</span><br><span>1. Hard and Soft Acid-Base Theory: Classification of acids and bases as hard and soft. Pearson's hard and soft</span><br><span>acid base concept, acid base strength and hardness and softness. Symbiosis, theoretical basis of hardness and</span><br><span>softness, electronegativity and hardness and softness.</span><br><span>2 general methods of preparation of organometallic</span><br><span>compounds and a brief account of metal-ethylenic complexes. Applications of organometallic compounds-</span><br><span>Ziegler-Natta catalyst, Wilkinson catalyst (No mechanism).</span><br><span>3. Bioinorganic Chemistry: Role of metal ions in biology, essential and trace elements in biological systems,</span><br><span>toxic elements, elementary idea of structure and oxygen binding mechanism in metallo-porphyrins with special</span><br><span>reference to haemoglobin and myoglobin. Alkali and alkaline earth metal ions in biological system-mechanism</span><br><span>of transport across cell membrane, biochemistry of magnesium and calcium</span><br><span>4 Inorganic Polymers of Silicon and Phosphorus : Silicones; siloxanes, silicone rubber, polymethyl</span><br><span>hydrosiloxanes, applications. Phosphazenes, nature of bonding in triphosphazenes. Zeolites.</span><br><span>Some Industrially Important Inorganic Materials: Cement-Manufacture, composition and setting.</span><br><span>Glass- Manufacture, annealing, types and uses.</span><br><span>Ceramics-Definition, traditional and new ceramics, structure of ceramics. Inorganic fertilizers-essential nutrients</span><br><span>for plants- nitrogenous, phosphatic and potash fertilizers.</span><br><span>ORGANIC CHEMISTRY-VI</span><br><span>B.Sc. VI Semester; II Paper Nomenclature of peptides and proteins. Classification of proteins. Peptide structure determination, end</span><br><span>group analysis, selective hydrolysis of peptides. Classical peptide synthesis, solid-phase peptide synthesis.</span><br><span>Levels of protein structure. Protein denaturation/renaturation. Nucleic acids: introduction, constituents of</span><br><span>nucleic acids. Ribonucleosides and ribonucleotides. The double helical structure of DNA.</span><br><span>2. Fats, Oils and Detergents : Natural fats and common fatty acids, glycerides, hydrogenation of unsaturated</span><br><span>oils. Saponification value, iodine value and acid value. Soaps, synthetic detergents, alkyl and aryl sulp-</span><br><span>honates.</span><br><span>processes. Laws of photochemistry; Grothuss-Drapper law, Lambert's law, Lambert-Beer's law, St</span><br><span>3. Solutions and Colligative Properties: Ideal and non-ideal solutions, methods of expressing concentrations</span><br><span>of solutions, activity and activity coefficient. Dilute solutions, colligative properties, Raoult's law, relative</span><br><span>lowering of vapour pressure, molecular mass determination. Osmosis, law of osmotic pressure and its</span><br><span>measurement, determination of molecular mass from osmotic pressure. Elevation of boiling point and</span><br><span>depression in freezing point. Experimental methods for determining various colligative properties. Abnormal</span><br><span>molar mass, degree of dissociation and association of solutes.</span><br><span>4. Thermodynamics III : Statement and concept of residual entropy, third law of thermodynamics,</span><br><span>unattainability of absolute zero, Nernst heat theorem. Evaluation of absolute entropy from heat capacity data.</span></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br></br>
Detailed Information
| Author: | , |
|---|---|
| Publication Year: | 2021 |
| Pages: | 362 |
| Language: | other |
| File Size: | 6.3959 |
| Format: | |
| Price: | FREE |
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