Table Of ContentJournal of Chemical Tecimolo}’}' am! Biotechnology J Chcm Techno! Biotechnol 74:1207-1218 (1999)
JOURNAL OF CHEMICAL TECHNOLOGY
AND BIOTECHNOLOGY
Contents of volume 74
ISSUE 1
Acknowledgement. 1
Comment
‘Clean-Process Biotechnology’ aimed at retaining bioactive components in foods
A Wiseman, T Ridgway and H Wiseman (UK). 3
Papers
Effect of dissolved oxygen tension and pH on the production of extracellular protease from a
new isolate of Bacillus subtilis K2, for use in leather processing
A Hameed (Pakistan), T Keshavarz and CS Evans (UK). 5
Biofiltration control of pulping odours - hydrogen sulfide: performance, macrokinetics, and
coexistence effects of organo-sulfur species
AH Wani, AK Lau and RMR Branion (Canada). 9
Measurement of native dextran synthesis and sedimentation properties by analytical
ultracentrifugation
SJ Setford (UK). 17
Thermostability of modified enzymes: a detailed study
MA Longo and D Combes (France). 25
Differentiation of pH and free lactic acid effects on the various growth and production phases
of Lactobacillus helveticus
A Amrane and Y Prigent (France). 33
Studies of viscosity build-up properties of sodium alcohol ether sulphates
W Hreczuch, K Rolnik, J Szymanowski and W Apostoluk (Poland). 41
Removal of linuron from water by natural and activated bentonite
E Gonzalez-Pradas, M Villafranca-Sachez, A Gallego-Campo, D Urena-Amate and
M Fernandez-Perez (Spain). 49
A pseudo first order rate model for the adsorption of an organic adsorbate in aqueous
solution
PHY Li, RL Bruce and MD Hobday (Australia). 55
The gas phase hydrodechlorination of chlorobenzene over nickel/silica
G Tavoularis and MA Keane (UK). 60
Continuous fixed bed biosorption of Cu""^ ions: application of a simple two parameter
mathematical model
J M Brady, J M Tobin (Ireland) and J-C Roux (France). 71
Mathematical analyis of proportional-integral control for fixed bed bioreactors
J Alvarez-Ramirez, M Meraz and O Monroy (Mexico). 78
© 1999 Society of Chemical Industry. J. Chew Technol Biotechnol 0268-2575/99/S17.50 1207
Contents of volume 74
Calendar of meetings. 85
Instructions to authors of papers 1999 . 87
Papers published in volumes 71-73. 91
ISSUE 2
Review
New reagents or new ways with old reagents
D S Flett (UK). 99
Papers
Screening and selection of microfungi for microbial biomass protein production and water
reclamation from starch processing wastewater
B Jin, J van Leeuwen, Q Yu and B Patel (Australia). 106
Mechanisms of Cr(VI) removal from water by various types of activated carbons
C Selomulya, V Meeyoo and R Amal (Australia). Ill
Liquid-phase adsorption of phenol by activated carbons prepared from bituminous coals
with different oxygen contents
H Teng and C-T Hsieh (Taiwan). 123
Production of lactic acid from beet molasses by calcium alginate immobilized Lactobacillus
delbrueckii IFO 3202
Y Goksungur and U Giiventj (Turkey). 131
Influence of growth medium composition on the lipolytic enzyme activity of Ophiostoma
piliferum (Cartapip^^')
E George, C Tamerler (UK), A Martinez, MJ Martinez (Spain) and T Keshavarz (UK) . . 137
Preliminary study on products distribution in alcohol pulping of Eucalyptus globulus
JI Botello, MA Gilarranz, F Rodriguez and M Oliet (Spain). 141
Inactivation of microorganisms in a flow-through photoreactor with an immobilized Ti02
layer
L Belhacova, J Krysa, J Geryk and J Jirkovsky (Czech Republic). 149
Etherification rates of 2-methyl-2-butene and 2-methyl-1-butene with ethanol for
environmentally clean gasoline production
N Oktar, K Miirtezaoglu, G Dogu, I Gonderten and T Do^ (Turkey). 155
A kinetic study of the oxidation of phenol, o-chlorophenol and catechol by hydrogen
peroxide between 298 K; and 333 K: the effect of pH, temperature and ratio of oxidant to
substrate
A K De, B Chaudhuri and S Bhattacharjee (India). 162
Fluidized tube heat exchanger
FF Ar and BZ Uysal (Turkey). 169
Dynamic modelling, simulation and optimization of an extractive continuous alcoholic
fermentation process
FL Honorato da Silva, MI Rodrigues and F Maugeri (Brazil). 176
Kinetic study on the esterification of geraniol and acetic acid in organic solvents using
surfactant-coated lipase
S-Y Huang and H-L Chang (Taiwan). 183
Calendar of meetings. 188
120S
Contents of volume 74
ISSUE 3
Introduction
D L Pyle. 191
Papers presented at the 4th International Conference on Separations for
Biotechnology, University of Reading, UK, 29-31 March 1999
Investigation of single protein adsorption on ion exchangers using confocal laser scanning
microscopy
M Ahmed and DL Pyle (UK). 193
Adsorption isotherms of the Aspergillus niger glucoamylases I and II on the anionic exchanger
DEAE-Toyopearl 650
R Soriano, LF Bautista, M Martinez and J Aracil (Spain). 199
A scale-down study into the chromatography of a peptide using the cation-exchange
cellulose, Express-Ion C
P R Levison, M Streater and J W Dennis (UK). 204
Direct process integeration of cell disruption and fluidised bed adsorption for the recovery of
intracellular proteins
H Bierau, Z Zhang and A Lyddiatt (UK). 208
Azeotropic phenomena during separation of dilute mixtures of proteins by simulated moving
bed chromatography
J Houwing, HAH Billiet, HA Wesselingh and LAM van der Wielen (Netherlands) .... 213
The adsorption kinetics of cephalosporin-c on non-ionic polymeric macropore Amberlite
XAD-16 resin
SA Yang and DL Pyle (UK). 216
Protein extraction using sugar ester reverse micelles
K Naoe, M Nishino, T Ohsa, M Kawagoe and M Imai (Japan). 221
Enhanced recovery and catalytic activity of Rhizopus delemar lipase in an AOT
microemulsion system with guanidine hydrochloride
K Nagayama, R Nishimura, T Doi and M Imai (Japan). 227
Colloidal gas aphrons generated from the anionic surfactant AOT for the separation of
proteins from aqueous solution
M J Noble and J Varley (UK). 231
Purification of recombinant proteins using thermoseparating aqueous two-phase system and
polymer recycling
J Persson, L Nystrom, H Ageland and F Tjeraeld (Sweden). 238
Flooding characteristics of aqueous two-phase systems in a countercurrent sieve-plate
column
A Hamidi, M van Berio, KChAM Luyben and LAM van der Wielen (Netherlands) .... 244
Processing of nanoparticulate bioproducts: application and optimisation of aqueous two-
phase systems
S G Walker and A Lyddiatt (UK). 250
Optimization and design considerations of two-phase continuous protein separation
E Huenupi, A Gomez, BA Andrews and J A Asenjo (Chile). 256
Monitoring of adsorbate breakthrough curves within an expanded bed adsorption column
LJ Bruce, RH Clemmitt, DC Nash and HA Chase (UK). 264
Magnetically stabilised fluidised bed adsorption: practical benefit of uncoupling bed
expansion from fluid velocities in the purification of a recombinant protein from Escherichia
coli
Z Zhang, DA O’Sullivan and A Lyddiatt (UK). 270
1209
Contents of volume 74
On the generalization of thermodynamic properties for selection of bioseparation processes
LAM van der Widen and ESJ Rudolph (Netherlands). 275
Process integration of cell disruption and aqueous two-phase extraction
Z-G Su and X-L Feng (PR China). 284
Simulation and optimisation of integrated bioprocesses: a case study
Y H Zhou and N J Titchener-Hooker (UK). 289
An Expert System for selection of protein purification processes: experimental validation
M E Lienqueo, J C Salgado and J A Asenjo (Chile). 293
Calendar of meetings. 300
ISSUE 4
Papers
Removal of aqueous phenol and 2-chlorophenol with purified soybean peroxidase and raw
soybean hulls
C Flock, A Bassi and M Gi)zen (Canada). 303
Solvent extraction of gold by LIX 79: experimental equilibrium study
A M Sastre, A Madi, J L Cortina and F J Alguacil (Spain). 310
Deactivation by coke of a catalyst based on a SAPO-34 in the transformation of methanol
into olefins
A T Aguayo, A E Sanchez del Campo, A G Gayubo, A Tarrio and J Bilbao (Spain) .... 315
On the kinetics of magnesia hydration in magnesium acetate solutions
D Filippou, N Katiforis, N Papassiopi and K Adam (Greece). 322
The effect of commercial carbon de-ashing on its thermal stability and porosity
G Rychlicki, A P Terzyk and W Majehrzyeki (Poland). 329
Removal of diazo and triphenylmethane dyes from aqueous solutions through an adsorption
process
M Sankar, G Sekaran, S Sadulla and T Ramasami (India). 337
Corrosion inhibition by A-(alkyloxycarbonylmethyl)-N-triethanol ammonium chloride with
respect to the surface and thermodynamic properties
E A M Gad, Z Abdel-Hamid, D A Ismail and R A El-Adly (Egypt). 345
Photodegradation of the textile dye Reactive Black 5 in the presence of semiconducting
oxides
I Poulios and I Tsachpinis (Greece). 349
Synthesis of molecular sieves from Chilean kaolinites: 1. Synthesis of NaA type zeolites
V Sanhueza, U Kelm and R Cid (Chile). 358
Comparison of prednisolone production from cortexolone by free and immobilized isolated
and standard collection strains using mixed culture techniques
J Manosroi. A Manosroi, A Saraphanchotiwittaya (Thailand) and M Abe (Japan). 364
Extended Summaries: Joint Meeting of the Environmental Biotechnology, the
Biotechnology and the Food Commodities and Ingredients Groups of the SCI,
the Industrial Biochemistry and Biotechnology Group of the Biochemical Society
and the Process Technology Group of the Royal Society of Chemistry:
‘Improving the nutritional and technological functionalities of foods using
clean-process biotechnology’
Introduction
T Ridgway and A Wiseman (UK). 371
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Contents of volume 74
Introduction: Future ‘enzymes-by-design’ to control food-functionality
A Wiseman (UK). 371
Bioactive components of foods
H Wiseman (UK). 371
Added enzymes in food production
L F J Woods (UK). 372
Food enzymes and biotechnology
P Goodenough (UK). 373
The role and manipulation of enzymes in development of tomato flavour
A J Taylor (UK). 374
Cell wall degrading enzymes: manipulation for processing
G A Tucker (UK). 374
Introduction: ‘Clean and healthy’ food processing
T Ridgway (UK). 375
Enrichment of omega-3 fatty acids using lipase technology
G P McNeill (UK). 376
The use of onion waste as a raw material for functional foods
K W Waldron and A C Smith (UK). 376
Phenols, tannins and their transformation products in beverages: implications for health
M Clifford (UK). 376
Colourants, antioxidants and phytoestrogens from apple
T Ridgway (UK). 377
Calendar of meetings. 378
ISSUE 5
Review
Biological decontamination of oil spills in cold environments
R Margesin and F Schinner (Austria). 381
Papers
Hydrogen peroxide promoted wet air oxidation of phenol: influence of operating conditions
and homogeneous metal catalysts
F J Rivas, S T Kolaczkowski (UK), F J Beltran (Spain) and D B McLurgh (UK). 390
Biological stereoselective reduction of 2,6- and 3,5-dimethylcyclohexanones by Glomerella
cingulata
M Miyazawa, S Okamura and H Kameoka (Japan). 399
Production of optically pure L-valine in fluidized and packed bed reactors with immobilized
I-aminoacylase
A Bodalo-Santoyo, J L Gomez-Carrasco, E Gomez-Gomez, J Bastida-Rodriguez,
M F Maximo-Martin and A M Hidalgo-Montesinos (Spain). 403
The influence of system parameters on the stability of colloidal liquid aphrons
J T Scarpello and D C Stuckey (UK). 409
Preliminary studies in removing atrazine, isoproturon and imidacloprid from water by
natural sepiolite
E Gonzalez-Pradas, M Villafranca-Sanchez, M Socias-Viciana, M Femandez-Perez and
M D Urena-Amate (Spain). 417
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Contents of volunw 74
Enzymatic activity of Chromobacterium viscosum lipase in an AOT/Tween 85 mixed reverse
micellar system
M J Hossain, T Takeyama, Y Hayashi, T Kawanishi, N Shimizu and R Nakamura (Japan) 423
Removal of toxic metals from aqueous mixtures. Part 1: Biosorption
A I Zouboulis, E G Rousou, K A Matis (Greece) and I C Hancock (UK). 429
Insight into spent caustic treatment: on wet oxidation of thiosulfate to sulfate
M V Jagushte and V V Mahajani (India). 437
A thermophilic/mesophilic dual digestion system for treating waste activated sludge
R Roberts, S Le and C F Forster (UK). 445
Sensitivity analysis on a sequencing batch reactor model. II: Effect of stoichiometric and
operating parameters
A E Abasaeed (Saudi Arabia). 451
The phenomenology and the mathematical modelling of the silicone-supported chemical
oxidation of aqueous sulfide to elemental sulfur by ferric sulfate
A de Smul and W Verstraete (Belgium). 456
Solvent extraction with LIX 973N for the selective separation of copper and nickel
F J Alguacil and A Cobo (Spain). 467
Book reviews. 472
Calendar of meetings. 475
ISSUE 6
Review
L-Fucose: occurrence, physiological role, chemical, enzymatic and microbial synthesis
P T Vanhooren and E J Vandamme (Belgium). 479
Papers
Hydrogen production during the anaerobic acidogenic conversion of glucose
C-Y Lin and R-C Chang (Taiwan). 498
Enzymatic synthesis of optically active ferrocenes by immobilized lipase from Candida
Antarctica
T Kijima, Y Yaginuma and T Izumi (Japan). 501
Accumulation of zirconium and nickel by Citrobacter sp
G Basnakova and L E Macaskie (UK). 509
Characterisation of acylglycerol synthesis in aqueous foams by lipases
V M Shanmugam, P G Sasikumar and N M Rao (India). 515
Kinetic model-aided reactor design for peroxidase-catalyzed removal of phenol in the
presence of polyethylene glycol
Y Wu, K E Taylor, N Biswas and J K Bewtra (Canada). 519
The effect of D-glucose on milk clotting activity of Mucor miehei in a chemostat with biomass
retention
H Beyenal, ^ ^eker, B Salih and A Tanyolat; (Turkey). 527
Effect of complexing agents on liquid-phase adsorption and desorption of copper(II) using
chitosan
R-L Tseng, F-C Wu and R-S Juang (Taiwan). 533
Factors influencing critical flux in membrane filtration of activated sludge
S S Madaeni (Iran), A G Fane and D E Wiley (Australia). 539
Contents of volume 74
Selective removal of copper ions from aqueous solutions using modified silica beads
impregnated with LIX 84
J-S Kim and J Yi (Korea). 544
Steady state behaviour of three phase air lift bioreactors - an integrated model and
experimental verification
P Gikas and A G Livingston (UK). 551
Combined biological and chemical oxidation of ferrous sulphate using immobilized
Thiobacilliis ferrooxidans
M Nemati and C Webb (UK). 562
Recovery of microbial polysaccharides from fermentation broths by microfiltration on
ceramic membranes
C Harscoat, M Y Jaffrin, P Paullier, B Courtois and J Courtois (France). 571
Growth kinetics of Rhizopus fomiosa MUCL 28422 on raw cassava flour in solid state
fermentation
S C Stertz, C R Soccol (Brazil), M Raimbault (France), A Pandey (Brazil) and
J A Rodriguez-Leon (Cuba). 580
On the effect of gap size between baffle outer diameter and tube inner diameter on the
mixing characteristics of an oscillatory-baffled column
X Ni and C C Stevenson (UK). 587
Calendar of meetings. 594
ISSUE 7
Comment
Aquatic-environment xenoestrogens and phytoestrogens: no clean ecorestoration without
biointervention?
A Wiseman, P Goldfarb, T Ridgway and H Wiseman (UK). 597
Review
Utilization of genetically engineered microorganisms (OEMs) for bioremediation
C Garbisu and I Alkorta (Spain). 599
Papers
Optimisation of the enzymatic synthesis of «-octyl oleate with immobilised lipase in the
absence of solvents
J M S Rocha, M H Gil and F A P Garcia (Portugal). 607
Solid-state fermentation of waste pomace from olive processing
M S Haddadin, S M Abdulrahim, G Y Al-Khawaldeh (Jordan) and R K Robinson (UK) . . 613
A three-phase fluidized bed reactor in the combined anaerobic/aerobic treatment of
wastewater
J Yu, M Ji and P L Yue (Hong Kong). 619
Production of L-lactic acid by Lactobacillus delbmeckii in chemostat culture using an ion
exchange resins system
J M Monteagudo and M Aldavero (Spain). 627
Stabilization of a-amylase by chemical modification with carboxymethylcellulose
R Villalonga, L Gomez, H L Ramirez and M L Villalonga (Cuba). 635
Treatment of olive mill wastewaters by ozonation, aerobic degradation and the combination
of both treatments
F J Benitez, J Beltran-Heredia, J Torregrosa and J L Acero (Spain). 639
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Contcms (>l Ydliinit’ 74
Adsorption/desotption of phenols onto granular activated carbon in a liquid-solid fluidized
bed
R-C Wang and S-C Chang (Taiwan). 647
Modelling of kinetics and mass transfer in the hydrogenation of xylose over Raney nickel
catalyst
J-P Mikkola, T Salmi and R Sjoholm (Finland). 655
Recovery' of magnesium and protein from soy tofu whey by electrodialytic configurations
L Bazinet, D Ippersiel and F Lamarche (Canada). 663
A simplified model of peroxidase-catalyzed phenol removal from aqueous solution
I D Buchanan and J A Nicell (Canada). 669
Kinetics of addition of acrylic and methacrylic acids to epichlorohydrin in the presence of
chromium(III) ethanoate
A Bukowska and W Bukowski (Poland). 675
A new pH-based procedure to model toxic effects on nitrifiers in activated sludge
K Gernaey, D MafTei, P V^anrolleghem and W Verstraete (Belgium). 679
The operational strategy of intermittent cycle extended aeration system in treating sewage
J-S Chang, A-C Chen, M-Y Hung and M Shih (Taiwan). 688
Crossflow microfiltration of a primary sewage effluent - solids retention efficiency and flux
enhancement
Q Gan and S J Allen (UK). 693
Zinc and copper distribution in soils and their removal by chelating extraction
A Barona, 1 Aranguiz and A Elias (Spain). 700
Research Note
Effect of surfactants on a-amylase production in a solid substrate fermentation process
A P Goes and J D Sheppard (Canada). 709
Calendar of meetings. 713
ISSUE 8
Review
Ionic optodes: role in fiber optic chemical sensor technology
K Langry and B Rambabu (USA). 717
Papers
Recovery of proteins and other biological compounds using fibrous materials: I. Adsorption
by salt addition
LA Chen, RG Carbonell and GA Serad (USA). 733
Recovery of proteins and other biological compounds using fibrous materials: II.
Flocculation by polyelectrolyte addition
LA Chen, RG Carbonell and GA Serad (USA). 740
Lipase-catalyzed enantioselective esterification of 5'(+)-naproxen ester prodrugs in
cyclohexane
S-W’ Tsai, S-F Lin and C-S Chang (Taiwan). 751
Surface properties of emulsan-analogs
J Zhang, S-H Lee, RA Gross and D Kaplan (USA). 759
1214
Contents of volume 74
Nonlinear recursive feedback control for the regulation of substrate concentration in a fixed
bed bioreactor
J Gonzalez, R Aguilar, J Alvarez-Ramirez and MA Barron (Mexico). 766
Catalytic para-xylene maximization: III. Hydroisomerization of mera-xylene on H-ZSM-5
catalysts containing different platinum contents
AK Aboul-Gheit, SM Abdel-Hamid, SZ Mohamed and DS El-Desouky (Egypt). 771
Characteristics of gold biosorption from cyanide solution
H Niu and B Volesky (Canada). 778
Kinetics and mechanism of homogeneous catalytic hydroxylation of maleic acid by hydrogen
peroxide: III. Kinetics of the hydrolysis of c/s-epoxysuccinic acid
JO Oludipe (Nigeria). 785
The effect of nitrite correction on the evaluation of the rate of nitrate utilization under anoxic
conditions
S Sozen and D Orhon (Turkey). 790
Amino acid solubilization in cationic reversed micelles: factors affecting amino acid and
water transfer
MM Cardoso, MJ Barradas (Portugal), KH Kroner (Germany) and JG Crespo (Portugal). 801
Synthesis of benzylpyridine using copper zeolite and irradiation - a modified method
VN Telvekar, KG Akamanchi and BA Chaudhari (India). 812
Biodegradation of 2-, 3- and 4-iodobenzoic acids
LM Freitas dos Santos, A New and M Kingswood (UK). 815
Secretion of heterologous and native proteins, growth and morphology in batch cultures of
Aspergillus niger Bl-D at varying agitation rates
A Wongwicham, LM Harvey and B McNeil (UK). 821
Calendar of meetings. 829
ISSUE 9
Guest editorial
D Brown (UK). 833
Guest reviews - SCI Messel Scholars
Solid phase synthesis - designer linkers for combinatorial chemistry: a review
K Gordon and S Balasubramanian (UK). 835
Organometallic molecular modelling - the computational chemistry of metallocenes: a
review
N Fey (UK). 852
Production and detection of short-lived metal-containing molecules in the gas phase: a
review
MS Beardah and AM Ellis (UK). 863
Papers
Pentachlorophenol retention on to lignocellulosic activated carbons
R Arriagada and R Garcia (Chile). 870
Integration of continuous biological and chemical (ozone) treatment of domestic wastewater:
1. Biodegradation and post-ozonation
FJ Beltran, JF Garcia-Araya and PM Alvarez (Spain). 877
Contents of volume '^4
Integration of continuous biological and chemical (ozone) treatment of domestic wastewater:
2. Ozonation followed by biological oxidation
FJ Beltran, JF Garcia-Araya and PM Alvarez (Spain). 884
Separation mechanisms of citric and itaconic acids by water-immiscible amines
E Bressler and S Braun (Israel). 891
Methane combustion on sol-gel Rh/Zr02-Si02 catalysts
G Pecchi, P Reyes, F Orellana (Chile), T Lopez, R Gomez (Mexico) and JLG Fierro (Spain) 897
Retention of Cr(VI) and Hg(II) in Eucalyptus globulus- and peach stone-activated carbons
G Bello, R Cid, R Garcia and R Arriagada (Chile). 904
Effect of pH, cation concentration and sorbent concentration on cadmium and copper
removal by a granular activated carbon
A Seco, C Gabaldon, P Marzal and A Aucejo (Spain). 911
Book review. 919
Calendar of meetings. 920
ISSUE 10
Papers
Environmentally friendly liquid phase oxidation: enhanced selectivity in the aerial oxidation
of alkyl aromatics, epoxidations and the Baeyer-Villiger oxidation using novel silica
supported transition metal ions
IC Chisem, J Chisem, JS Rafelt, DJ Macquarrie, JH Clark and KA Utting (UK). 923
Effect of liquid volume in the gas-separator on the hydrodynamics of airlift reactors
WA Al-Masry (Saudi Arabia). 931
Evaluation of drum bioreactor performance used for decontamination of soil polluted with
polycyclic aromatic hydrocarbons
SH Woo and JM Park (Korea). 937
Removal of sulphur from Assam coal by bacterial conditioning and froth flotation
C Acharya, GV Rao (India), I Twardoska (Poland), RN Kar and LB Sukla (India). 945
Anaerobic treatment of acidified and non-acidified substrata in UASB reactors
A Elias, A Barona, J Ormazabal, G Ibarra and J Caamano (Spain). 949
Role of diazotrophic bacteria in the bioremediation of crude oil-polluted soil
INE Onwurah (Nigeria). 957
Detoxification of mercury by immobilized mercuric reductase
J-S Chang, Y-P Hwang, Y-M Fong and P-J Lin (Taiwan). 965
Quick analysis of enantioselectivity by a chromatographic reactor: II. Experimental
verification
J-Y Wu and S-W Liu (Taiwan). 974
Performance characteristics of novel mechanical foam breakers in a stirred tank reactor
NS Deshpande and M Barigou (UK). 979
Oxidative dehydrogenation of ethane over alkali-metal doped sulfated zirconia catalysts
S Wang, K Murata, T Hayakawa, S Hamakawa and K Suzuki (Japan). 988
Anaerobic and aerobic treatment of a simulated textile effluent
C O’Neill, FR Hawkes, SRR Esteves, DL Hawkes and SJ Wilcox (UK). 993
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