Table Of Contentइंटरनेट मानक
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IS 13080 (1991): Pesticide - Pirimiphos-Methyl, Technical
[FAD 1: Pesticides and Pesticides Residue Analysis]
“!ान $ एक न’ भारत का +नम-ण”
Satyanarayan Gangaram Pitroda
““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee””
“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै”
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“Knowledge is such a treasure which cannot be stolen”
i
IS 13080:19§1
:_
:
TTtfmTm
Indian Standard
PESTICIDE - PIRIMIPHOS-METHYL,
TECHNICAL - SPECIFICATION
UDC 632’95 : 547’853’3 PIRIM
Q BIS 1991
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
May 1991 Price Group 1
sedicitseP lanoitceS ,eettimmoC FADC 1
.
FOREWORD
sihT naidnI dradnatS was detpoda yb eht uaeruB fo naidnI Standards, retfa eht tfard dezilanif yb
eht sedicitseP lanoitceS eettimmoC had neeb devorppa yb eht dooF and erutlucirgA noisiviD
.licnuoC
,lyhtem-sohpimiriP lacinhcet is deyolpme ni eht noitaraperp fo ladicitcesni .snoitalumrof
lyhtem-sohpimiriP is eht detpecca nommoc eman yb eht lanoitanretnI noitazinagrO rof -azidradnatS
noit ( 0SI ) rof eht ladicitsep lacimehc -sohplyhtemid-O~~-ly-4-nidimiryplyhtem-6-onimalyhteid-2-O
.etaoihtorohp ehT laciripme and larutcurts ealumrof and ralucelom mass fo lyhtem-sohpimirip era
nevig :woleb
Empirical Formula Structural Formula Molecular Mass
SP303NozHllC 3’503
nI eht noitaraperp fo this standard, eud noitaredisnoc has neeb nevig ot eht snoisivorp fo eht
Insecticides Act, 1968 and eht seluR demarf .rednuereht ,revewoH this standard is tcejbus ot eht
snoitcirtser desopmi rednu eseht reverehw .elbacilppa
roF eht esoprup fo gnidiced rehtehw a ralucitrap tnemeriuqer fo this standard is deilpmoc ,htiw eht
lanif ,eulav devresbo ro ,detaluclac gnisserpxe eht tluser fo a tset ro ,sisylana shall eb dednuor ffo ni
ecnadrocca htiw SI 2 : 1960 seluR‘ rof gnidnuor ffo laciremun seulav ( revised )‘. ehT rebmun fo
tnacifingis secalp deniater ni eht dednuor ffo eulav dluohs eb eht emas as that fo eht deificeps eulav .
ni this standard.
IS 13080: 1991
Indian Standard
PESTICIDE - PIRIMIPHOS-METHYL,
TECHNICAL - SPECIFICATION
)b noitacidnI fo eht ecruos fo ;rerutcafunam
1 SCOPE
)c etaD fo erutcafunam and etad fo ;yripxe
sihT standard sebircserp eht stnemeriuqer and eht
sdohtem fo sampling and tset rof -sohpimirip )d hctaB ;rebmun
,lyhtem .lacinhcet )e teN mass fo ;stnetnoc
)f lyhtem-sohpimiriP ,tnetnoc tnecrep (
2 REFERENCES and m/m 1;
ehT naidnI Standards detsil ni xennA A era )g ehT muminim yranoituac eciton as dedrow
yrassecen stcnujda ot this standard. rednu eht and seluR
Insecticides Act, 1968
demarf .rednuereht
3 REQUIREMENTS
5.2 ehT reniatnoc yam osla eb dekram htiw eht
3.1 Description dradnatS Mark.
ehT lairetam shall eb ni eht mrof a krad straw
deruoloc ot nworb/der diuqil at serutarepmet 6 SAMPLING
evoba 20°C. ehT lairetam yam niatnoc slatsyrc
evitatneserpeR samples fo eht lairetam shall eb
fo lyhtemsohpimirip ni secart and shall eb eerf
drawn as debircserp ni SI 10946 : 1984.
morf suoenartxe .rettam
NOTES
3.2 Miscibility with Trimethyl Benzene, Technical 1 erofeB gniward evitatneserper ,selpmas smurd llahs
enO trap fo eht lairetam shall eb yletelpmoc eb dekcehc rof eht ecneserp fo slatsyrc dna fi ,dnuof
tsum eb .dewaht To etatilicaf ,siht eht smurd yam eb
elbicsim htiw eerht parts fo lyhtemirt ,enezneb derots ni a mraw moor ro yllaitrap desremmi ni
,lacinhcet gniwohs ton erom than a tniaf .ytidibrut yletaredom toh retaw ( mumixam erutarepmet C°05 )
rof a doirep fo ton erom naht 24 sruoh roirp ot
3.3 ehT lairetam shall osla ylpmoc htiw eht .gnilpmas
stnemeriuqer deificeps ni elbaT 1.
2 ecnO deviecer ni eht ,yrotarobal eht selpmas llahs
eb derots at a erutarepmet woleb .C°52
4 PACKING
ehT lairetam shall eb dekcap ni naelc and yrd 7 TESTS
dlim leets drums ylbatius dereuqcal morf .edisni
ehT reniatnoc shall osla ylpmoc htiw lareneg 7.1 stseT shall eb deirrac tuo yb eht sdohtem
stnemeriuqer as nevig ni SI 8190 traP( 2 ) : 1988. derrefer ot ni 3.2 and 1oc 4, 5 & 6 fo elbaT 1.
5 MARKING 7.2 Quality of Reagents
5.1 ehT reniatnoc shall eb yleruces desolc and Unless deificeps ,esiwrehto erup slacimehc and
raeb ylbigel and ylbiledni eht gniwollof -mrofni dellitsid retaw ( ees SI 1070 : 1977 ) shall eb
noita ni noitidda ot yna rehto noitamrofni as deyolpme ni .stset
deriuqer rednu eht and
Insecticides Act, 1968
seluR demarf :rednuereht NOTE - eruP‘ ’slacimehc llahs naem slacimehc taht
od ton niatnoc seitirupmi hcihw tceffa eht stluser fo
)a emaN fo eht ;lairetam .sisylana
Table 1 Requirements for Pirimiphos-Methyl, Technical
( Clause 3.3 )
SI No. Characteristic Requirement Method of Test, Ref to
A--_-------~
Tc-------
xennA fo esualC .oN fo traP .oN fo
sihT dradtnaS SI 6940 : 1982 SI 1448 : 1982
(1) (2) (3) (4) (5) (6)
)i lyhtem-sohpimiriP ,tnetnoc tnecrep 90’0 B -
yb ,ssam Min
)ii erutsioM ,tnetnoc tnecrep yb ,ssam Max 0’2 - 4.1 -
)iii evitaleR ytisned at 27/27”C, nlM 1’16 - 5 -
)vi ytidicA ( sa H,S04 >, tnecrep yb ,ssam Max 0.5 - 13.5.4
)v hsalF tniop ( lebA ,) “C, Min 37.8 - - 20
1
SI 13080:1991
ANNEX A
( Item 2 )
LIST OF REFERRED INDIAN STANDARDS
IS No. Title IS No. Title
l
1070 : 1977 retaW for lareneg yrotarobal 8190 tnemeriuqeR for gnikcap of
esu ( second revision ) (Part 2) : 1988 :sedicitsep Part 2 diuqiL
1448 hsalF tniop yb lebA sutarappa sedicitsep ( second revision )
(P : 20) : 1982 ( first revision )
6940 : 1982 Methods of tests for sedicitsep
dna rieht snoitalumrof ( first 10946 : 1984 Methods of gnilpmas for -inhcet
revision ) lac grade sedicitsep
ANNEX B
[Table 1, Item (i )]
DETERMINATION OF PIRIMIPHOS-METHYL CONTENT
B-l GENERAL dna neht ekam pu the emulov ot the kram htiw
.mroforolhc
A noitrop of the elpmas si devlossid ni a -orolhc
mrof gniniatnoc lanretni dradnats .ekil ehT 2.4-B Preparation of Standard Pirimiphos-Methyl
evitca enacedatco-n tneidergni tnetnoc si detamitse
Standard Solution
gas yllacihpargotamorhc yb gnirapmoc htiw a
ecnerefer dradnats of nwonk .ytirup hgieW yletarucca tuoba 0’2 g of dradnats
lyhtem-sohpimirip otni a lm-OOl cirtemulov .ksalf
2-B SUTARAPPA evlossiD ni OI lm of .mroforolhc ddA 25 lm of
1.2-B saG hpargotamorhC lanretni dradnats noitulos morf a ,etterub shake
ot evlossid the lyhtem-sohpimirip dna ekam pu
A gas hpargotamorhc dettif htiw a emalf -azinoi
the emulov htiw .mroforolhc
noit detector dna na .redrocer-muc-rotargetni ehT
evitseggus gnitarepo snoitidnoc are nevig ,woleb 3.4-B Preparation of Sample Solution
hcihw nac eb degnahc dedivorp noitazidradnats
si :enod hgieW yletarucca a ytitnauq of elpmas ot -noc
niat 0’2 g of lyhtem-sohpimirip otni a lm-OOl
Column ,ssalG 2 m gnol dna 6 mm 0.D
cirtemulov ksalf dna add 10 lm .mroforolhc ddA
packed htiw ~1 tnecrep SE30 no
25 lm of lanretni dradnats noitulos morf a etterub
dica washed etilec 345 ( 021-001
dna shake ot evlossid the lyhtem-sohpimirip
hsem ). noitidnoC the nmuloc yb
elpmas dna ekam pu the emulov htiw .mroforolhc
gnigrup htiw negortin at C°003
.thginrevo retfA ,gninoitidnoc 4.4-B Estimation
pretreat the nmuloc htiw 3 -cejni
snoit each of 10 1“~ of lyliS 8 at Before gnitrats the ,sisylana tcejni eciwt 3 lr of
eno etunim slavretni ot diova dradnats lyhtem-sohpimirip ot etarebiliuqe the
gniliat of the peaks dna ot niatbo metsys dna esu the data morf these -otamorhc
retteb .ycneiciffe smarg ot set the rotargetni .sretemarap yrraC
tuo the etacilpud snoitcejni of dradnats dna
Temperature elpmas snoitulos dna record the detargetni areas
nmuloC 22O’C for each peak.
noitcejnI C°062
Detector C°003 S-B NOITALUCLAC
lyhtem-sohpimiriP ,tnetnoc tnecrep yb ssam
Carrier Gas and Flow Rate
negortiN 50 nim/lm lm X R2 x P
=
negordyH 50 nim/lm
2m x RI
riA 300 nim/lm
where
2.2-B Microlitre Syringe - 1p-ol .yticapac ml = ,ssam ni g, of lyhtem-sohpimirip
3-B STNEGAER ;dradnats
R = peak area of ;elpmas
1.3-B eoacedatcO-n - lacitylana tnegaer grade a ~-
peak area of lanretni ;dradnats
( see Note rednu .)5-B
P = tnecrep ytirup of lyhtem-sohpimirip
2.3-B lyhteM-sohpimiriP ecnerefeR dradnatS - of
;dradnats
nwonk .ytirup
ma = ,ssam ni g, of elpmas nekat for the
3.3-B lyliS 8 or tnelaviuqE ;tset dna
4.3-B mroforolhC - cihpargotamrohc grade. peak area of lyhtem-sohpimirip
;dradnats
4-B ERUDECORP
1R = peak area of lanretni .dradnats
1.4-B noitaraperP of lanretnI dradnatS noituloS
NOTE - lonacedatcO osla nac eb desu sa lanretni
hgieW yletarucca 0’2 g enacedatco-n otni a lm-OOl .dradnats nI esac lonacedatco si ,desu eraperp a 0’5
cirtemulov ,ksalf evlossid ni 10 lm mroforolhc ( v/v ) noitulos ni .mroforolhc
2
.
I I
I
Standard Mark
I
ehT esu of the dradnatS Mark si denrevog yb the snoisivorp of the Bureau of Indian
Standards Act, 1986 dna the seluR dna snoitalugeR edam .rednuereht ehT dradnatS Mark no
stcudorp derevoc yb na naidnI dradnatS syevnoc the ecnarussa that yeht evah neeb decudorp
ot ylpmoc htiw the stnemeriuqer of that dradnats rednu a llew denifed metsys of ,noitcepsni
gnitset dna ytilauq lortnoc hcihw si desived dna desivrepus yb SIB dna operated yb the
.recudorp dradnatS dekram stcudorp are osla ylsuounitnoc checked yb SIB for ytimrofnoc
ot that dradnats as a rehtruf .draugefas sliateD of snoitidnoc rednu hcihw a ecnecil for the
esu of the dradnatS Mark yam eb detnarg ot srerutcafunam or srecudorp yam eb deniatbo
morf the uaeruB of naidnI .sdradnatS
I I
Bureau of Indian Standards
SIB is a yrotutats noitutitsni dehsilbatse rednu eht ot etomorp
Bureau of Indian Standards Act, 1986
suoinomrah tnempoleved fo eht seitivitca fo ,noitazidradnats gnikram and ytilauq noitacifitrec fo sdoog
and gnidnetta ot detcennoc srettam ni eht .yrtnuoc
Copyright
.
SIB has eht thgirypoc fo all its .snoitacilbup oN trap fo eseht snoitacilbup yam eb decudorper ni
yna mrof tuohtiw eht roirp noissimrep ni gnitirw fo .SIB sihT seod ton edulcerp eht eerf ,esu ni eht
esruoc fo gnitnemelpmi eht standard, fo yrassecen ,sliated hcus as slobmys and ,sezis epyt ro edarg
.snoitangised seriuqnE gnitaler ot thgirypoc eb desserdda ot eht rotceriD ( snoitacilbuP ,) .SIB
Revision of Indian Standards
naidnI Standards era deweiver yllacidoirep and ,desiver nehw yrassecen and ,stnemdnema fi ,yna era
issued morf emit ot .emit sresU fo naidnI Standards dluohs niatrecsa that yeht era ni noissessop fo
eht tsetal stnemdnema ro .noitide stnemmoC no this naidnI dradnatS yam eb tnes ot SIB gnivig eht
gniwollof ecnerefer :
toD : .oN FAD 1 ( 4041 )
Amendments Issued Since Publication
Amend No. etaD fo eussI txeT detceffA
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