Ionic Polymer Metal Composites for Sensors and Actuators

212 Pages·2019·9.597 MB·English

by  Inamuddin, Abdullah M. Asiri

Engineering Materials
Inamuddin
Abdullah M. Asiri Editors
Ionic Polymer
Metal
Composites for
Sensors and
Actuators
Engineering Materials
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Inamuddin Abdullah M. Asiri
(cid:129)
Editors
Ionic Polymer Metal
Composites for Sensors
and Actuators
123
Editors
Inamuddin AbdullahM. Asiri
Department ofChemistry Department ofChemistry
Faculty of Science Faculty of Science
KingAbdulaziz University KingAbdulaziz University
Jeddah, SaudiArabia Jeddah, SaudiArabia
ISSN 1612-1317 ISSN 1868-1212 (electronic)
Engineering Materials
ISBN978-3-030-13727-4 ISBN978-3-030-13728-1 (eBook)
https://doi.org/10.1007/978-3-030-13728-1
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Contents
Metal-Organic Framework Composites IPMC Sensors
and Actuators. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Bianca Maranescu and Aurelia Visa
Polysaccharide-Based Ionic Polymer Metal Composite Actuators . . . . . 19
A. Popa, A. Filimon and L. Lupa
Conducting Polymer Based Ionic Polymer Metal
Composite Actuators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
David Gendron
Role of Metal Ion Implantation on Ionic Polymer Metal
Composite Membranes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
Adina Maria Dobos and A. Filimon
Study on Time-Dependent Bending Response of IPMC Actuator. . . . . . 75
Hyung-Man Kim and N. D. Vinh
Ionic Polymer-Metal Composite Membranes Methods
of Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
Fatma Aydin Unal, Hakan Burhan, Fatima Elmusa, Shukri Hersi
and Fatih Sen
Ionic Polymer-Metal Composite Actuators Operable
in Dry Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
FatmaAydinUnal,HakanBurhan, SumeyyeKarakus,GizemKaraelioglu
and Fatih Sen
Pressure Sensors Based on IPMC Actuator . . . . . . . . . . . . . . . . . . . . . . 161
Gokhan Topcu, Tugrul Guner and Mustafa M. Demir
v
vi Contents
Robotic Assemblies Based on IPMC Actuators . . . . . . . . . . . . . . . . . . . 183
D. Josephine Selvarani Ruth
Design and Fabrication of Deformable Soft Gripper
Using IPMC as Actuator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Srijan Bhattacharya, Bikash Bepari and Subhasis Bhaumik
Metal-Organic Framework Composites
IPMC Sensors and Actuators
BiancaMaranescuandAureliaVisa
Abstract Metal-organic frameworks (MOFs), a highly studied class of complex
structuredporousmaterials,containingdifferenttypesofcentralmetalionsattached
to organic linkers, are used in various applications such as catalysis, separation,
absorption,photochemistry,protonconductivity,biotechnology,magnetismandsen-
soristicscienceetc.ThearchitecturalstructuresofMOFsprovidespecialproperties
as improved thermal and mechanical stabilities, high surface areas and large pore
sizes to these materials. The need for new functionalities is to take into account
that the fabrication methods must be robust, scalable, friendly to environment and
cost-effective.
· · ·
Keywords Metal-organicframeworks Sensors Molecularmachines Volatile
·
organiccompounds Actuators
1 Introduction
Developmentofmetal-organicframeworks(MOFs)orcoordinationpolymers(CPs)
is one of the most active research fields among chemistry and materials research
groups,duetoahighdiversityofapplications[1–9].MOFsnowcanbedesignedand
constructedstartingfromawidediversityofmetalionsormetal-containingclusters,
andorganicligands(Fig.1).
Thevarietyofmetalions,organiclinkersandstructuralstylescomeupwithan
endlessnumberofpotentialcombinations.
InternationalRoadmapforDevicesandSystems(IRDS),adescendantofInterna-
tionalTechnologyRoadmapforSemiconductors(ITRS)providespredictionsabout
likelysemiconductorsanddevices,withthemainaimtoalignacademicandresearch
lab efforts with electronic devices manufacturers and equipment suppliers. The
2017 edition reports, under emerging research materials, identify opportunities as
B
B.Maranescu·A.Visa( )
InstituteofChemistryTimis¸oaraoftheRomanianAcademy,300223Timis¸oara,Romania
e-mail:[email protected]
©SpringerNatureSwitzerlandAG2019 1
InamuddinandA.M.Asiri(eds.),IonicPolymerMetalCompositesforSensors
andActuators,EngineeringMaterials,https://doi.org/10.1007/978-3-030-13728-1_1
2 B.MaranescuandA.Visa
Fig.1 Generalstructureof
MOF
multifunctional materials/sensors, generation and energy storage, medical, as well
asflexibleelectronics[10].
Relyontheapplicationsetting,thesyntheticrouteisfollowedbothtobenefitfrom
the complexity of organics moiety, to decrease the production costs and to reduce
thesizetomoleculardimensions.
2 DesignandSynthesis
Since 1995, when the first synthesis was reported in the literature [11], most of
the syntheses have been performed by solvothermal methods using conventional
heating[12–16].Usually,thereactiontimesneeded werelong,several days inthe
caseofsolvothermalsynthesistosomeweeksfordiffusionmethods.Therefore,itis
importanttofindmoreefficientandtechno-economicallyviablealternativesynthetic
techniques,thatcanbeusedsuccessfullytoscaleuptheproductionofMOFs.
Thenewlydevelopedapproaches,suchasultrasounds[17–21],mechanochemical
[22–26],microwave(MW)[27–31]andelectrochemicalsynthesis[32–36],providea
promisingalternativeoftime-consumingsynthesisbyshorteningthesynthesistimes
andincreasingtheproductionyield.
By comparing with traditionally used zeolites and carbon materials, MOFs are
unique with reference to their extraordinarily high porosities, tunable pores, and
variousfunctionalsites.Diversemethodshavebeenappliedtodetect/sensedifferent
levels of gases, anions, cations, and various pollutants in addition of developing
materialsforsensing,drugdelivery,andheterogeneous catalysisinmanycontexts
(Fig.2).
Metal-OrganicFrameworkCompositesIPMCSensorsandActuators 3
Fig.2 MOFasactuators
andsensor
3 PropertiesandApplications
3.1 Nano/MolecularMachinesBasedActuators
Veryimportantandpromisingresearchdirectionisthedesignandbuildingofmolec-
ularmachines.In2016NobelprizeinchemistrywasgiventoJean-PierreSauvage,
SirJamesFraserStoddartandBenL.Feringaforthisfascinatingdomain[37,38].
Inordertoconstructnanomaterialswithmachine-likefunctions,sometechnolo-
gies were proposed by M. Venturi and co-workers [39]. Light-powered dynamic
nanomachineswhichimplylightenergystimulationofmaterialsareofgreatinterest.
Furthermore,lightstimuliareappliedtonanomachinesfromsmalldistanceswith-
outphysicalinteraction,andtheenergyquantaaremeasuredbytuningtheintensity,
wavelengthorpolarizationofthelight.
C. Barrett and co-workers [40] highlighted in their review article the most
encouraging models of the organization of switches and rotors into linear, two-
dimensional assembly, and strong three-dimensional crystals. These dynamic sys-
temsweredesignedandconstructedtoanswertoahighdiversityofactuationstimuli.
ActuatorsworkingonthisprincipleofMOFscanalsobeusedasartificialmolecular
machines[41,42].
M. Garcia Garibay and his co-workers [42, 43] performed researches in the
domain of pillared paddlewheel MOFs constructed by a modular approach using
9,10-bis-(pyridylethynyl)triptycene as a column and molecular rotator and dicar-
boxylatelinkersofvaryinglengthsandstericbulk.Using1,4-bicyclo[2.2.2]octane
dicarboxylicacid(BODCA)-MOF,amaterialwithahigh-symmetryBODCAlinker
inaZn Ocubiclattice,anultrafastrotationinanamphidynamiccrystallinemetal-
4
organicframeworkwasperformed(Fig.3a,b).
Fourkeyarchitecturalelementsweretakingintoaccount:(1)rotorsizeandshape,
(2)theaccessibilityoffreevolumehigherthanthevolumeofrotator,(3)thechemical
natureofligandaswellasofmetalandthedegreeoffreedomforrotatortothestator
and (4) the axial symmetries of rotator and stator. These kinds of molecules open
newperspectivesintheareasasgasstorage,catalysis,andphotochemistry.