Table Of ContentICAME2003
ICAME2003
Proceedings of the 27th International Conference
on the Applications of the Mossbauer Effect (ICAME 2003)
held in Muscat, Oman, 21-25 September 2003
Edited by
M.E.ELZAIN
Sultan Qaboos University, Muscat, Oman
A. A. YOUSIF
Sultan Qaboos University, Muscat, Oman
A. D. AL RAWAS
Sultan Qaboos University, Muscat, Oman
and
A. M. GISMELSEED
Sultan Qaboos University, Muscat, Oman
Reprinted from Hyperjine Interactions
Volume 156, Nos. 1-4 (2004)
Volume 157, Nos. 1-4 (2004)
SPRINGER SCIENCE+BUSINESS MEDIA, B.V.
A c.I.P. Catalogue record for this book is available from the Library of Congress.
ISBN 978-90-481-6726-5 ISBN 978-1-4020-2852-6 (eBook)
DOI 10.1007/978-1-4020-2852-6
Printed on acid-free paper
All Rights Reserved
© 2004 Springer Science+ Business Media Dordrecht
Originally published by Kluwer Academic Publishers in 2004
Softcover reprint of the hardcover 1st edition 2004
No part of the material protected by this copyright notice
may be reproduced or utilized in any form or by any means,
electronic or mechanical, including photocopying,
recording or by any information storage and retrieval
system, without written permission from the copyright
owner.
Table of Contents
Preface 1-2
Advances in Experimentation, Theory and Methodology
A. L. KHOLMETSKII, V. A. EVDOKIMOV, M. MASHLAN, O. V. MI-
SEVICH and A. R. LOPATIK / Mossbauer Instrument Package
MS-2000IP 3-8
A. L. KHOLMETSKII, W. POTZEL, R. ROHLSBERGER, U. VAN BURCK
and E. GERDAU / Nuclear Resonant Scattering of Synchrotron Radi-
ation as a Method for Distinction between Covariant Ether Theories
and Special Relativity 9-13
M. MASHLAN, V. YEVDOKIMOV, J. PECHOUSEK, R. ZBORIL and
A. KHOLMETSKII / Mossbauer Spectrometer with Novel Moving
System and Resonant Detection of Gamma Rays 15-19
K. SZYMANSKI, D. SATULA and L. DOBRZYNSKI / Angular Distribution
of Hyperfine Magnetic Field in Fe304 and Fe66Ni34 from Mossbauer
Polarimetry 21-26
YU. MALTSEV, S. MALTSEV, M. MENZEL, B. ROGOZEV and A. SIL-
VESTROV / Two-Dimensional Mossbauer Spectra 27-30
Amorphous and Nanophase Materials, Small Particles
D.-S. XUE and F.-S. LI / 57Fe Mossbauer Study of Magnetic Nanowires 31-40
D.-S. XUE, L.-Y. ZHANG and F.-S. LI / Synthesis and Mossbauer Study of
Maghemite Nanowire Arrays 41-46
T. FURUBAYASHI / Mossbauer Characterization of Iron-Based Nanogranular
Films 47-50
N. S. GAJBHIYE, R. S. NINGTHOUJAM and J. WEISSMULLER / Moss-
bauer Study of Nanocrystalline E-Fe3-xCoxN System 51-56
N. S. GAJBHIYE, G. BALAJI, S. BHATTACHARYYA and M. GHAFARI/
Mossbauer Studies of Nanosize CUFe204 Particles 57-61
J. GHOSE, K. S. K. VARADWAJ and D. DAS / Mossbauer Studies on Nano-
crystalline Diol Capped y-Fe203 63-67
J. RESTREPO and J. M. GRENECHE / Hyperfine and Structural Properties of
the Mechanically Alloyed (FeMnhoCu7o System 69-73
Y. KOBAYASHI, S. KIAO, M. SETO, H. TAKATANI, M. NAKANISHI and
R. OSHIMA / 197 Au Mossbauer Study of Bimetallic Nanoparticles
Prepared by Sonochemical Technique 75-79
O. SCHNEEWEISS, N. PIZUROvA, Y. JIRAsKovA, T. ZAK, P. BEZDICKA
and H. REUTHER / Phase Composition and Properties of Iron
Nanocrystals and Clusters Embedded in MgO Matrix 81-87
S. J. STEWART, R. C. MERCADER, G. PUNTE, J. DESIMONI, G. CERNIC-
CHIARO and R. B. SCORZELLI / Shifting the Superparamagnetic
Limit of Nanosized Copper Iron Spinel 89-95
S. SINGHAL, A. N. GARG and K. CHANDRA / Synthesis of Nanocrystalline
Nio.5Zno.5Fe204 by Aerosol Route and Its Characterization 97-102
Applications in Physics, Including Magnetism and Lattice Dynamics
P. BONVILLE, J. A. HODGES, E. BERTIN, J.-PH. BOUCHAUD, P. DAL-
MAS DE REOTIER, L.-P. REGNAULT, H. M. R0NNOW,
J.-P. SANCHEZ, S. SOSIN and A. YAOUANC / Transitions and Spin
Dynamics at Very Low Temperature in the Pyrochlores Yb2Ti207 and
Gd2Sn207 103-111
S. J. KIM, K.-D. JUNG and C. S. KIM / Mossbauer and Neutron Diffraction
Studies on Co-AI Ferrite 113-122
I. A. AL-OMARI, A. GISMELSEED, A. RAIS, H. M. WIDATALLAH,
A. AL RAWAS, M. ELZAIN and A. A. YOUSIF / Mossbauer Studies
of Feo.7-xSio.3Mnx Alloys 123-127
K. BHARUTH-RAM, J. E. BUTLER, D. NAIDOO and G. KLINGELHOFER /
Observation of Substitutional Fe in CEMS Measurements on Syn-
thetic CVD Diamond 129-135
B. BRZESKA-MICHALAK and A. OSTRASZ / Interaction between In-
terstitial Hydrogen and Fe Atoms within the f3-Hydride Phase in
Nbl-yFeyHx Alloys 137-142
G. LI, T. AKITSU, O. SATO and Y. EINAGA / First Observation of Photoin-
duced Magnetization for the Cyano-Bridged 3d-4f Heterobimetallic
Assembly Nd(DMFMH20h(JL-CN)Fe(CN)s·H20 (DMF = N,N-
Dimethylformamide) 143-149
T. ERICSSON, Y. A. ABDU, H. ANNERSTEN and P. NORDBLAD / Non-
Magnetic Stainless Steels Reinvestigated - a Small Effective Field
Component in External Magnetic Fields 151-155
L. A. BAUM, S. J. STEWART, R. C. MERCADER and J. M. GRENECHE /
Magnetic Response and Hyperfine Magnetic Fields at Fe Sites of
Sr3Fe2M09 (M = Mo, Te, W, U) Double-Perovskites 157-163
M. T. JEONG / Modification of Nuclear Decay Constant in the Finite Space 165-168
J. S. KUM, S. J. KIM, I. B. SHIM and C. S. KIM / Mossbauer Studies and
Magnetic Properties of Y 3-xCexFe5012 169-174
N. KOJIMA, Y. ONO, Y. KOBAYASHI and M. SETO I Control of Charge
Transfer Phase Transition in Iron Mixed-Valence System (n-CnH2n+ 1)4
N[FeIIFellI(dtohl (n = 3-6; dto = C202S2) 175-179
A-F. LEHLOOH, S. MAHMOOD, M. MOZAFFARI and J. AMIGHIAN I
Mossbauer Spectroscopy Study on the Effect of AI-Cr Co-Substitution
in Yttrium and yttrium-Gadolinium Iron Garnets 181-185
A. GRUSKOVA, J. LIPKA, M. PAPANOVA, D. KEVICKA, A GONZA-
LEZ, G. MENDOZA, I. TOTH and J. SLAMA I Mossbauer Study
of Microstructure and Magnetic Properties (Co, Ni)-Zr Substituted
Ba Ferrite Particles 187-194
I. NOWIK and I. FELNER I Mossbauer Studies of Dilute 119Sn and 57Fe in
SrRu03 and Sr2FeRu06 195-200
O. YU. PANKRATOVA, A V. ZABOLOTNAYA, K. A HISTIAEV, V. V. PAN-
CHUCK, V. G. SEMENOV, R. A ZVINCHUK and A V. SUVOROV I
Mossbauer Studies on the Quasibinary System FeTe1.45-TiTe1.45 201-204
M. ELZAIN, A AL RAWAS, A YOUSIF, A GISMELSEED, A RAIS,
I. AL-OMARI, K. BOUZIANE and H. WIDATALLAH I Magnetic
Properties of Iron Clusters in Silver 205-212
A YOUSIF, K. BOUZIANE, M. E. ELZAIN, X. REN, F. J. BERRY, H. M. WI-
DATALLAH, A AL RAWAS, A GISMELSEED and I. A AL-
OMARI I Magnetic Properties of Nanocrystalline FexCul-x Alloys
Prepared by Ball Milling 213-221
H. M. WIDATALLAH, A M. GISMELSEED, K. BOUZIANE, F. J. BERRY,
A D. AL-RAWAS, I. A AL-OMARI, A A YOUSIF and
M. E. ELZAIN I The Formation of Lithiated Ti-Doped a-Fe203
Nanocrystalline Particles by Mechanical Milling of Ti-Doped Lithium
Spinel Ferrite 223-228
A. RAIS, A A YOUSIF, A GISMELSEED, M. E. ELZAIN, A AL RAWAS
and I. A AL-OMARI I Effect of Mg2+ on the Magnetic Compensa-
tion of Lithium-Chromium Ferrite 229-234
T. SUENAGA, S. NASU, T. KAWAKAMI and R. H. HERBER I High-
Pressure 57Fe Mossbauer Spectroscopy of Octamethyl-Ethynyl-
Ferrocene 235-240
T. SEGI, S. NASU, S. MORIMOTO and H. TOKORO I 57Fe Mossbauer
Spectroscopic Study of Fe-B Compounds 241-245
Biological and Medical Applications
V. SCHUNEMANN, C. JUNG, F. LENDZIAN, A-L. BARRA, T. TESCHNER
and A X. TRAUTWEIN I Mossbauer- and EPR-Snapshots of an
Enzymatic Reaction: The Cytochrome P450 Reaction Cycle 247-256
M. MIKHAYLOVA, Y. S. JO, D. K. KIM, N. BOBRYSHEVA, Y. ANDER-
SSON, T. ERIKSSON, M. OSMOLOWSKY, V. SEMENOV and
M. MUHAMMED / The Effect of Biocompatible Coating Layers on
Magnetic Properties of Superparamagnetic Iron Oxide Nanoparticles 257-263
T. OHYA, J. TAKEDA and M. SATO / Spin States of Iron(III) in Highly
Saddled Dodecaphenylporphyrin Complexes 265-272
M. I. OSHTRAKH, O. B. MILDER and V. A. SEMIONKIN / Mossbauer
Spectroscopy of Iron Containing Vitamins and Dietary Supplements 273-277
M. I. OSHTRAKH, O. B. MILDER, V. A. SEMIONKIN, P. G. PROKOPENKO
and L. I. MALAKHEEVA / Comparative Study of Human Liver
Ferritin and Chicken Liver by Mossbauer Spectroscopy. Preliminary
R~~ m~M
T. TESCHNER, A. X. TRAUTWEIN, V. SCHUNEMANN, L. A. YAT-
SUNYK and F. A. WALKER / Low-Spin Ferriheme Models of
the Cytochromes: Correlation of Molecular Structure with EPR and
Mossbauer Spectral Parameters 285-291
P. WEGNER, M. BEVER, V. SCHUNEMANN, A. X. TRAUTWEIN,
C. SCHMIDT, H. BONISCH, M. GNIDA and W. MEYER-
KLAUCKE / Iron-Sulfur Proteins Investigated by EPR-, Mossbauer-
and EXAFS-Spectroscopy 293-298
Chemical Applications, Structure and Bonding
M. ABDELMOULA, M. PETITJEAN, G. CABOCHE, J.-M. GENIN and
L. C. DUFOUR / Mossbauer Study of Lanthanum-Strontium Ferro-
manganite Oxides 299-303
F. J. BERRY, O. HELGASON and J. W. F. MOSSELMANS / Iron-57 Moss-
bauer Spectroscopic Investigation of Manganese-Doped y-Fe203 305-309
K. IKEDA, N. KOJIMA, Y. ONO, Y. KOBAYASHI, M. SETO, X. J. LIU and
Y. MORITOMO / Study on Chemical Bond and Electronic State of
New Gold Mixed Valence Complexes CS2[AuIX2][AuIIIY4] (X, Y =
CI, Br, I) by Means of 197 Au Mossbauer Spectroscopy 311-314
S. KAMALI, L. HAGGSTROM, S. RONNETEG and R. BERGER / Magnetic
Properties of TIC02Se2 Studied by Mossbauer Spectroscopy 315-319
J. LINDEN, P. KAREN, H. YAMAUCHI and M. KARPPINEN / Exploring
the Verwey-Type Transition in GdBaFe205+w Using 57Fe Mossbauer
Spectroscopy 321-325
P. E. LIPPENS, J.-c. JUMAS and J. OLIVIER-FOURCADE / First Princi-
ples Calculations of Mossbauer Spectra of Intermetallic Anodes for
Lithium-Ion Batteries 327-333
F. J. BERRY, X. REN, J. R. GANCEDO and J. F. MARCO / 57Fe Mossbauer
Spectroscopy Study of LaFel-xCox03 (x = 0 and 0.5) Formed by
Mechanical Milling 335-340
T. M. MEAZ and C. BENDER KOCH / A Crystallographic and Mossbauer
Spectroscopic Study of BaCoo.5xZnO.5x Tix Fe12-2x019 (M-Type
Hexagonal Fenite) 341-346
H. MEHNER, M. MENZEL and M. NOFZ / Laboratory Intercomparison
on the Determination of the Fe(II)/Fe(III) Ratio in Glass Using
Mossbauer Spectroscopy 347-352
S. NAKASHIMA, Y. ASADA and T. OKUDA / 57Fe Mossbauer Spectroscopic
Study on the Assembled Iron Complexes 353-358
M. TAKEDA, J. WANG, T. NISHIMURA, K. SUZUKI, T. KITAZAWA and
M. TAKAHASHI / 155Gd Mossbauer Isomer Shifts and Quadrupole
Coupling Constants of Gadolinium Complexes 359-364
L. STIEVANO, R. DELLA PERGOLA and F. E. WAGNER / Mossbauer Spec-
troscopy in the Characterisation of Polymetallic Cluster Compounds:
a Triple Mossbauer Study of (PPh4) [Fe2Ir2(CO) 12 {j.L3-Au(PPh3) }] 365-370
F. RENZ and P. KEREP / The Nonanuclear [Mo(IV){ (CN)Fe(III)(3-ethoxy-
saldptn) }s]CI4 Complex Compound Exhibits Multiple Spin Transi-
tions Observed by Mossbauer Spectroscopy 371-377
Earth Sciences, Mineralogy and Archaeology
O. HELGASON / Processes in Geophysics Studied by Mossbauer Spec-
troscopy 379-388
Y. A. ABDU, H. ANNERSTEN, L. S. DUBROVINSKY and N. A. DUBRO-
VINSKAIA / High Pressure Mossbauer Studies on FCC Fe53Ni47
Alloy 389-394
M. FAJARDO, G. A. PEREZ ALCAzAR, A. M. MOREIRA and N. L. SPE-
ZIALI / Mossbauer and XRD Comparative Study of Host Rock and
Iron Rich Mineral Samples from Paz del Rio Iron Ore Mineral Mine
in Colombia 395-402
R. ZBORIL, M. MASHLAN, L. MACHALA, 1. WALLA, K. BARCOVA and
P. MARTINEC / Characterization and Thermal Behaviour of Garnets
from Almandine-Pyrope Series at 1200°C 403-410
N. I. CHISTYAKOVA, V. S. RUSAKOV, D. G. ZAVARZINA, A. I. SLO-
BODKIN and T. V. GOROHOVA / Mossbauer Study of Magnetite
Formation by Iron- and Sulfate-Reducing Bacteria 411-415
S. K. DEDUSHENKO, I. B. MAKHINA, A. A. MAR'IN, V. A. MUKHANOV
and YU. D. PERFILIEV / What Oxidation State of Iron Determines
the Amethyst Colour? 417-422
E. ENEROTH and C. BENDER KOCH / Fe-Hydroxysulphates from Bacterial
Fe2+ Oxidation 423-429
A. KUNO, M. MATSUO, A. P. SOTO and K. TSUKAMOTO I Mossbauer
Spectroscopic Study of a Mural Painting from Morgadal Grande,
Mexico 431-437
H. REUTHER, T. ARNOLD and E. KRAWCZYK-BARSCH I Quantification
of Secondary Fe-Phases Formed During Sorption Experiments on
Chlorites 439-443
R. AISSA, C. RUBY, A. GEHIN, M. ABDELMOULA and J.-M. R. GENIN I
Synthesis by Coprecipitation of AI-Substituted Hydroxysulphate
Green Rust Fe~IFe~ty)AI~II(OHh2S04' nH20 445-451
R. RUFFLER, E. GJYLA<;I and K. NAGORNY I Mossbauer Study of Ancient
Albanian Ceramics 453-458
M. Y. HASSAAN, F. M. EBRAHIM and S. H. SALAH I Variation of Some
Physical Properties of Brownmillerite Doped with a Transition Metal
Oxide 459-464
T. M. MEAZ, M. A. AMER and C. BENDER KOCH I Iron-Containing
Adsorbents in Great Nile Sediments 465-469
Industrial Applications, Including Catalysis and Corrosion
J.-M. R. GENIN I Fe (II-III) Hydroxysalt Green Rusts; from Corrosion to Min-
eralogy and Abiotic to Biotic Reactions by Mossbauer Spectroscopy 471-485
A. GISMELSEED, M. ELZAIN, A. YOUSIF, A. AL RAWAS, I. A. AL-
OMARI, H. WIDATALLAH and A. RAIS I Identification of Corro-
sion Products Due to Seawater and Fresh Water 487-492
A. NAKANISHI and T. KOBAYASHI I Atmospheric Corrosion on Steel
Studied by Conversion Electron Mossbauer Spectroscopy 493-496
L. ALDON, P. KUBIAK, A. PICARD, P. E. LIPPENS, J. OLIVIER-FOUR-
CADE and J.-C. JUMAS I Mossbauer Spectrometry as a Powerful
Tool to Study Lithium Reactivity Mechanisms for Battery Electrode
Materials 497-503
Material Science and Metallurgy
J. DESIMONI I Arrangements of Interstitial Atoms in fcc Fe-C and Fe-N
Solid Solutions 505-521
J. CHOJCAN I A Dilute-Limit Heat of Solution of 3d Transition Metals in Iron
Studied with 57Fe Mossbauer Spectroscopy 523-529
L. VERGARA, J. DESIMONI, A. FERNANDEZ GUILLERMET and
G. J. ZARRAGOICOECHEA I Distribution of N Atoms in the fcc
Fe-N Interstitial Solid Solution 531-539
M. MIZRAHI, A F. CABRERA, S. M. COTES, S. J. STEWART, R. C. MER-
CADER and J. DESIMONI / Distribution of Mn Atoms in a Substi-
tutional bcc-FeMn Solid Solution 541-545
M. M. EL-DESOKY, A AL-HAJRY, M. TOKUNAGA, T. NISHIDA and
M. Y. HASSAAN / Effect of Sulfur Addition on the Redox State of
Iron in Iron Phosphate Glasses 547-553
C. M. IONICA, L. ALDON, P. E. LIPPENS, F. MORAT O, J. OLIVIER-
FOURCADE and J.-C. JUMAS / Structural and Electronic Features
of Sb-Based Electrode Materials: 121 Sb Mossbauer Spectrometry 555-561
N. LAKSHMI, K. VENUGOPALAN and V. K. AGARWAL / Study of
Disordered Fe2Cr(l_x)MnxAl Alloys 563-567
D. OYOLA LOZANO, Y. R. MARTINEZ, H. BUSTOS and G. A PEREZ
ALCAzAR / Mossbauer and X-ray Study of Fel-xAlx, 0.2 :;:; x :;:;
0.5, Samples Produced by Mechanical Alloying 569-574
H. REUTHER, E. RICHTER, F. PROKERT, M. VEDA, A F. BELOTO and
G. F. GOMES / Investigation of Steel Surfaces Treated by a Hybrid
Ion Implantation Technique 575-579
Surfaces, Interfaces, Thin Films and Multilayers
M. CARBUCICCHIO and M. RATEO / Ferromagnetic Planar Nanocompos-
ites 581-593
M. A ANDREEVA / Surface and Interface Investigations by Nuclear Resonant
Scattering with Standing Waves 595-606
M. A. ANDREEVA, L. HAGGSTROM, B. LINDGREN, B. KALSKA,
A-M. BLIXT, S. KAMALI, O. LEUPOLD and R. RUFFER /
Nuclear Resonant Reflectivity Investigations of a Thin Magnetic 57Fe
Layer Adjacent to a Superconducting V Layer 607-613
J. JURASZEK, J. TEILLET, A FNIDIKI and M. TOULEMONDE / CEMS
Investigations of Swift Heavy Ion Irradiation Effects in Tb/Fe Multi-
layers 615-621
K. K. KADYRZHANOV, V. S. RUSAKOV, B. O. KORSHIYEV, T. E. TURKE-
BAEV and M. F. VERESCHAK / Thermally Induced Processes of
Intermetalloid Phase Formation in Laminar Systems Fe-Sn 623-628
K. NOMURA, K. TAKAHASHI, M. TAKEDA, K. SHIMIZU, H. HABASAKI
and E. KUZMANN / DCEMS Study of Thin Oxide Layers and In-
terface of Stainless Steel Films Deposited by Sputtering Austenitic
AISI304 629-636
K. NOMURA and Y. YAMADA / CEMS Study on Fe Films Deposited by
Laser Ablation 637-641
