Hyper-Structured Molecules III

224 Pages·2002·39.426 MB·\224

by  Hiroyuki Sasabe (Author)

Hyper-Structured Molecules III

Hyper-Structured
Molecules Ill
Chemistry, physics and applications
Edited by
Hiroyu ki Sasabe
Boca Raton London New York
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Contents
Preface vii
List of corresponding authors ix
1 Near field optical technologies: From imaging/
diagnostics to nano-fabrication/atom manipulation 1
MOTOICHI OHTSU
2 Hybridization of scanning near-field optical
microscope with scanning tunneling microscope 31
KEN NAKAJIMA, RUGGERO MICHELETTO, KEITA MITSUI,
TAKASHI ISOSHIMA, MASAHIKO HARA, TATSUO WADA,
HIROYUKI SASABE, AND WOLFGANG KNOLL
3 Organic spin clusters, fractals, and networks with
very high spin 46
ANDRZEJ RAJCA
4 Single-molecule magnets 61
DANIEL RUIZ, GEORGE CHRISTOU, AND
DAVID N. HENDRICKSON
5 From NLO-active alkynylmetal complexes to
organometallic dendrimers 90
MARK G. HUMPHREY, ANDREW M. McDONAGH,
STEPHAN HOUBRECHTS, INGE ASSELBERGHS,
ANDRE PERSOONS, TATSUO WADA, HIROYUKI SASABE,
MAREK SAMOC, AND BARRY LUTHER-DAVIES
vi Contents
6 A synthetic approach to rigid and dendritic
nano-sized Ruthenium complexes 100
MASAHISA OSAWA, MIKIO HOSHINO, AND YASUO WAKATSUKI
7 Worm-like dendrimers with flexible carbosilane
branches 109
N. OUALI, S. MERY, L. NOIREZ, AND A. SKOULIOS
8 Electrochemical construction of ordered porphyrin
polymers toward nano-molecular spin systems 123
FEIPENG WU, YASUHITO MAEDA, KAZUTAKA HIRAKAWA,
AND HIROSHI SEGAWA
9 Chromogenic receptors as potentially
hyper-structured molecules 136
YUJI KUBO
10 Design and synthesis toward starburst C60-based
conducting polyanilines 150
LONG Y. CHIANG, VIJAYARAJ ANANTHARAJ,
TAIZOON CANTEENWALA, AND LEE Y. WANG
11 Exotic condensed states of matter: Discotic mesogen
and optically isotropic liquid crystals 172
MICHIO SORAI AND KAZUYA SAITO
12 Phototriggered reactions of DNA and their
applications 190
ISAO SAITO, KIYOHIKO KAWAI, TAKASHI NAKAMURA,
SHIGEO MATSUDA, AND KENZO FUJIMOTO
13 Optimized second-harmonic generation from
alternate-layer Langmuir-Blodgett films of a
transparent dye and poly (f-butyl methacrylate) 196
GEOFFREY J. ASHWELL AND RAKESH RANJAN
Index 209
Preface
Under the strategic research promotion program by Japan Science and
Technology Corporation, the Core Research for Evolutional Science and
Technology (CREST) program has been launched in March, 1996. The
Hyper-Structured Molecules and their Application to Organic Quantum
Devices group was approved as a member of the CREST program for five
years. The aims of this group are to design molecules such as dendritic
polymers and topologically controlled molecules and to handle these mol­
ecules by ‘molecular tweezers’ such as photon STM. Hyper-structured mol­
ecules are topologically well-defined molecules in two and/or three
dimensions, and are expected to show novel quantum effects in molecules
themselves and molecular sequences, e.g., light-emitting molecules, chemical
amplification, and molecular magnets.
The first International Forum on Hyper-Structured Molecules was held
in Kusatsu, Japan, on November 4-6, 1996, the second one held in Sap­
poro on May 30-June 1, 1997, the third in Otsu on June 9-11, 1998, and
the fourth in Oiso on June 29-July 1, 1999, to discuss the future of these
new molecules and their possible application to organic quantum devices.
The highlights of these forums are planned to be published as a series of
monographs which contribute to the understanding of the current status
and progress of this field. Already we have published two monographs,
Hyper-Structured Molecules I (in 1999) and II (in 2000). This monograph
on Hyper-Structured Molecules III is based on the third and fourth forums
and covers molecular designs of dendrimers, oligomers, hyperbranched
polymers and/or high spin systems, molecular organizations and nanostruc­
tures, mesoscopic pattern formation, and scanning probe microscopy for
characterization and molecular handling.
I would like to express my sincere gratitude to all of the contributors to
the forums who made this new project a most promising research field.
The financial support by Japan Science and Technology Corporation is
viii Preface
also highly appreciated. Finally I would like to thank Gordon and Breach
Science Publishers for their continuous encouragement for this mono-
graph.
Hiroyuki Sasabe
Project Leader of HSM, CREST, JST
List of corresponding authors
Motoichi Ohtsu, Prof.
Interdisciplinary Graduate School
Tokyo Institute of Technology
4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan
Tel: [phone]; Fax: [phone]
E-mail: [email protected]
Ken Nakajima, Dr.
Frontier Research Systems (FRS)
The Institute of Physical & Chemical Research
2-1 Hirosawa, Wako, Saitama 351-0198, Japan
Tel.: [phone]; Fax: [phone]
E-mail: [email protected]
Andrzej Rajca, Prof.
Department of Chemistry
University of Nebraska Lincoln
Lincoln, Nebraska 68588, U.S.A.
Tel: [phone]; Fax: [phone]
E-mail: [email protected]
David N. Hendrickson, Prof.
Department of Chemistry and Biochemistry
University of California, San Diego
9500 Gilman Drive, Dept 0358, La Jolla, CA 92093-0358, U.S.A.
Tel: [phone]; Fax: [phone]
E-mail: [email protected]
Mark G. Humphrey, Dr.
Department of Chemistry, Australian National University
Canberra, ACT 0200, Australia
Tel: [phone]; Fax: [phone]
E-mail: [email protected]
Masahisa Osawa, Dr.
The Institute of Physical 8c Chemical Research
2-1 Hirosawa, Wako, Saitama 351-098, Japan