Table Of Contentm
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9487_9789814651899_tp.indd 1 19/6/15 9:56 am
World Scientific Series in Materials and Energy*
ISSN: 2335-6596
Series Editor: Leonard C. Feldman (Rutgers University)
Published
Vol. 2 Handbook of Instrumentation and Techniques for Semiconductor Nanostructure
Characterization
edited by Richard Haight (IBM TJ Watson Research Center, USA),
Frances M. Ross (IBM TJ Watson Research Center, USA),
m James B. Hannon (IBM TJ Watson Research Center, USA) and
o
c Leonard C. Feldman (Rutgers University, USA)
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ntifi Vol. 3 The World Scientific Handbook of Energy
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w7/ Alexander Bismarck (Vienna University of Technology, Austria),
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B1. Vol. 6 Handbook of Solid State Batteries (2nd Edition)
State 187.5 edited by Nancy J. Dudney (Oak Ridge National Laboratory, USA),
d 8. William C. West (Nagoya University, Japan) and
of Soliby 7 Jagjit Nanda (Oak Ridge National Laboratory, USA)
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o Forthcoming
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nd Batteries
a
H edited by Jack Vaughey (Argonne National Lab., USA) and David Schroeder
Northern Illinois, USA)
Encyclopedia of Practical Semiconductors (In 4 Volumes)
edited by Eugene A. Fitzgerald (Massachusetts Institute of Technology, USA)
Graphene
edited by Michael G. Spencer (Cornell University, USA)
Handbook of Silicon Surfaces and Formation of Interfaces: Basic Science in the
Industrial World (2nd Edition)
Jarek Dabrowski and Hans-Joachim Mussig (Institute for Semiconductor
Research, Germany)
*The complete list of titles in the series can be found at
http://www.worldscientific.com/series/mae
Rhaimie - Handbook of Solid State Batteries.indd 1 18/6/2015 3:42:41 PM
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db Nancy J Dudney
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Oak Ridge National Laboratory, USA
William C West
Nagoya University, Japan
Jagjit Nanda
Oak Ridge National Laboratory, USA
World Scientific
NEW JERSEY • LONDON • SINGAPORE • BEIJING • SHANGHAI • HONG KONG • TAIPEI • CHENNAI • TOKYO
9487_9789814651899_tp.indd 2 19/6/15 9:56 am
Published by
World Scientific Publishing Co. Pte. Ltd.
5 Toh Tuck Link, Singapore 596224
USA office: 27 Warren Street, Suite 401-402, Hackensack, NJ 07601
UK office: 57 Shelton Street, Covent Garden, London WC2H 9HE
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ntific. A catalogue record for this book is available from the British Library.
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B1. electronic or mechanical, including photocopying, recording or any information storage and retrieval
State 187.5 system now known or to be invented, without written permission from the publisher.
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is not required from the publisher.
ISBN 978-981-4651-89-9
In-house Editor: Rhaimie Wahap
Typeset by Stallion Press
Email: [email protected]
Printed in Singapore
Rhaimie - Handbook of Solid State Batteries.indd 2 18/6/2015 3:42:41 PM
June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagev
Preface
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cie Solid-state batteries hold the promise of providing energy storage
w.worldsse only. wsaiftehtyhiagnhdstpeemcipfiecraetnuerregystaanbidlithyigihsspuoeswreerladteivnesittoy,tyheotsweiatshsofacrialteesds
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an high specific energy lithium metal anodes resulting in high active-
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massbasisspecificenergy.
Sincethelasteditionofthisbook,significantstridesinthefield
of solid-state batteries have been achieved. In this second edition
ofthisbook,wehaveboughttogethermanysubject-matterexperts
v
June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagevi
vi Preface
in the field of solid-state batteries, covering a wide range of topics.
Herein,theauthorssummarizeadvancementsin:
◦
Very high ionic conductivity sulfide- and oxide-based solid elec-
trolyteswithionicconductivitynearlyon-parwithliquidlithium-
ionelectrolytes
◦
Newsolidelectrolytesforthinfilmbatteriespreparedbyanumber
ofdifferenttechniques
◦
Adaptation of powerful characterization tools including syn-
m
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c chrotron based in-operando methods for studies of solid-state
c.
ntifi batteries
cie ◦ In-depthcharacterizationandmodelingofthenatureofthecritical
w.worldsse only. ◦ sDoelvideleolpecmtreonlytteo-feleacdtrvoadneciendterifna-cseitu and in-operando electron
m wwonal u microscopymethods
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Do0/2 performanceofsolidelectrolytesandsolid-statebatteries
atteries 48 on 1 ◦◦ NNeewwcseollliddeesliegcntsroilnyctoerspfoorratcionngdtuhcretieo-ndiomfelnitshioiunmal,sfltruuocrtiudree,sand
B1.
d State 8.187.5 ◦ Asildvvearniocends polymer electrolytes with a wide range of composi-
of Soliby 7 tions,structuralmotifs,andadditivesforimprovedionicconduc-
k tivityandmechanicalstability
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nd Yet many scientific and technological challenges remain. Many
a
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research activities focus on the ionic transport and electrochemical
reactions of a single material, yet the challenge for devices hinge
on the stability and unimpeded motion of ions across interfaces
betweentheelectrode-electrolyteandinsomecasesbetweenmulti-
pleelectrolytes.Celldesignsutilizingthick,energydenseelectrodes
with a relatively small electrolyte contact area will be particularly
challenging due to the high current density. The community also
needs to investigate and provide avenues for practical industrial
processingandmassproduction.
June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagevii
Preface vii
While a commercially viable solid-state battery competitive with
conventional lithium-ion batteries has yet to be fully realized, we
anticipate further advancements that will soon bring this exciting
newtechnologytofruition.
NancyJDudney
OakRidgeNationalLaboratory
WilliamCWest
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June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pageix
Contents
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State 187.5 Chapter2. In-situNeutronTechniquesforLithium
of Solid by 78. IYounpianngdHSeoalindd-SHtaotweaRrdecWhaanrggeableBatteries 51
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StudiesofAtomicandElectronic
StructureinBatteries 79
FaisalM.AlamgirandSamsonY.Lai
Chapter4. AnalyticalElectronMicroscopy—Study
ofAllSolid-StateBatteries 109
ZiyingWangandYingShirleyMeng
ix
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x Contents
Chapter5. Li-ionDynamicsinSolidsasSeenVia
RelaxationNMR 133
ViktorEppandMartinWilkening
Chapter6. CrystallineInorganicSolidElectrolytes:
ComputerSimulationsandComparisons
withExperiment 191
M.D.JohannesandN.A.W.Holzwarth
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atteries 48 on 1 Chapter9. ThinFilmLithiumElectrolytes 307
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State 187.5 JeaCho,JaneChang,AmyPrieto
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Ha All-Solid-StateRechargeable
LithiumBatteries 337
YasutoshiIriyamaandZempachiOgumi
Chapter11. CrystallineSulfideElectrolytes
forLi-SBatteries 365
GayatriSahuandChengduLiang
Chapter12. Super-ionicConductingOxideElectrolytes 391
JeffSakamoto
