Handbook of Infrared Standards II. With Spectral Coverage Between 1.4 UM–4 UM and 6.2 UM–7.7 UM

720 Pages·1993·9.555 MB·English

by  Guy Guelachvili (Auth.)

HANDBOOK
OF
INFRARED STANDARDS II
With Spectral Coverage of
1.4 um-4 urn and 6.2 μητι-7.7 μητι
Guy Guelachvili K. Narahari Rao
Laboratoire de Physique Department of Physics
Moleculaire et Applications The Ohio State University
CNRS, Bat 350 Columbus, Ohio, U.S.A.
Universite Paris-Sud
Orsay Cedex, France
®
ACADEMIC PRESS, INC.
Harcourt Brace & Company, Publishers
Boston San Diego New York
London Sydney Tokyo Toronto
This book is printed on acid-free paper. @
COPYRIGHT ·ς) 1993 BY ACADEMIC PRESS, INC.
ALL RIGHTS RESERVED.
NO PART OF THIS PUBLICATION MAY BE REPRODUCED OR
TRANSMITTED IN ANY FORM OR BY ANY MEANS, ELECTRONIC
OR MECHANICAL, INCLUDING PHOTOCOPY, RECORDING, OR
ANY INFORMATION STORAGE AND RETRIEVAL SYSTEM, WITHOUI
PERMISSION IN WRITING FROM THE PUBLISHER.
ACADEMIC PRESS, INC.
1250 Sixth Avenue, San Diego, CA 92101
United Kingdom Edition published by
ACADEMIC PRESS INC. (LONDON) LTD.
24-28 Oval Road, London NW1 7DX
Library of Congress Cataloging-in-Publication Data
Guelachvili, Guy.
Handbook of infrared standards II : with spectral coverage of
1.4 μπι- 4 μπΊ and 6.2 μνη-1.7 μιη / Guy Guelachvili and K. Narahari Rao.
p. cm.
Includes bibliographical references.
ISBN 0-12-305362-5 (acid-free)
1. Infrared radiation—Standards—Handbooks, manuals, etc.
I. Rao, K. Narahari. II. Title. III. Title: Handbook of infrared
standards 2. IV. Title: Handbook of infrared standards two.
QC457.G828 1993
543\08583-dc20 92-47468
CIP
PRINTED IN THE UNITED STATES OF AMERICA
93 94 95 96 MV 9 8 7 6 5 4 3 2 1
INTRODUCTION
Numerous studies of molecular infrared spectra are being made routinely in several
laboratories of the world making use of commercially developed high resolution spec-
trometers. In 1986 a volume of the Handbook of Infrared Standards^ was published
for use in wavenumber calibrations of the day-to-day experimental spectroscopic in-
vestigations. It provides maps of selected molecular spectra along with their measured
wavenumbers in the region between 3 and 2600 μηι. This wavelength coverage was
mainly dictated by our desire to bring out a book of reasonable dimensions. The
present effort, designated as Handbook of Infrared Standards II, gwes the same type
of information about closely spaced spectral lines occurring in the nearer infrared
mainly between 1.4 and 4 μπ\. In this spectral region, in addition to the interest on
high resolution studies of overtone and combination bands employing Fourier spec-
trometers, tunable sources of one type or another are either operating or being
developed and it is believed that all researchers working in this area may find this
handbook useful. Complete listings and specifications of the diode lasers operable
in the region 1.4-4 μπι can be obtained from industries dealing with electro-optic
products2. The present undertaking combined with the books published previously3"5
Ό. Guelachvili and K. Narahari Rao, Handbook of Infrared Standards, Academic Press, Inc., Orlando,
Florida, 1986; the spectral coverage included in this book is between 3 and 2600 /xm.
2See for instance, 1992 Laser Focus World Buyers Guide, PennWell Publishing Company, 1421 South
Sheridan, Tulsa, Oklahoma 74101 USA.
3A. G. Maki and J. S. Wells, Wavenumber Calibration Tables From Heterodyne Frequency
Measurements, National Institute of Standards and Technology Publication 821, U.S. Department of Com-
merce, Washington, D.C. (1991); it gives computer-generated spectral maps and calculated values of the
wavenumbers of the stronger transitions in about the same spectral region as in Ref. 1.
4A. R. H. Cole, Tables of Wavenumbers for the Calibration of Infrared Spectrometers, second Edi-
tion, prepared under the auspices of the Commission on Molecular Structure and Spectroscopy of IUPAC,
Pergamon Press, N.Y. (1977).
5Earlier books: (a) Tables of Wavenumbers for the Calibration of Infrared Spectrometers, prepared under
the auspices of the Commission on Molecular Structure and Spectroscopy of IUPAC, Butterworths,
Washington (1961). (b) K. Narahari Rao, C. J. Humphreys and D. H. Rank ,Wavelength Standards in
the Infrared, Academic Press, N.Y. (1966).
VII
VIII Introduction
may fulfill some of the needs of the researcher in infrared spectroscopy. Surely, there
will be other attempts forthcoming as time goes by.
Molecular assignment information presented in this handbook has been taken from
the references given as superscripts after the species indicated below:
C H (6'7); OCS(8); NH (9'10); CHC1(11<12); CO(,3<14<15); N 0(16',7);
2 2 3 3 2
H 0(1819); HDO, D O(20).
2 2
Now, it may be recalled that at the meeting of the 17th Conference Generale des
Poids et Measures on October 20, 1983, in Paris, a new definition21 of the meter
was adopted "to open the way to the major improvements in the precision of
measurements." The new definition of the meter does not depend on a particular
radiation. It states that the "meter is the length of the path traveled by light in vacuum
during a time interval of 1/(299 792 458) of a second." That is to say, this definition
fixes the value of the speed of light at 299 792 458 m s-1 exactly. "The new defini-
tion has become practicable with the development of techniques for the measure-
ment of frequencies. ... in terms of the cesium standard that is used in the defini-
tion of the second.*" In order to enable investigators to pin down the absolute ac-
curacy of their data, we have herein summarized frequency measurements that have
been made since the publication of the previous handbook.1
The arrangement of material in this book is as follows. In Section I we present
spectral maps and wavenumber data for some easily available molecular species re-
corded with a Fourier transform spectrometer (FTS). Section II summarizes several
heterodyne frequency measurements while Section III gives an update of the precise
frequencies for Os0 lines determined by using saturation absorption resonances of
4
6R. D'Cunha, Y. A. Sarma, G. Guelachvili, R. Farrenq, Q. Kou, V. Malathy Devi, C. Benner, and
K. Narahari Rao, J. Mol. Spectrosc. 148, 213-225 (1991).
7W. J. Lafferty and A. S. Pine, J. Mol. Spectrosc. 141, 223-230 (1990).
8Andre Fayt and A. Belafhal (Private Communication, 1992).
9S. Urban, N. Tu, K. Narahari Rao, and G. Guelachvili, J. Mol. Spectrosc. 133, 312-330 (1989).
10G. Guelachvili, A. H. Abdullah, N. Tu, K. Narahari Rao, S. Urban, and D. Papousek, J. Mol. Spec-
trosc. 133, 345-364 (1989).
nM. Morillon-Chapey, G. Guelachvili, and P. Jensen, Can. J. Phys. 62, 247-253 (1984).
12N. Bensari-Zizi, C. Alamichel, and G. Guelachvili, Can. J. Phys, 59, 994-1004 (1981).
13G. Guelachvili, J. Mol. Spectrosc. 75, 251-269 (1979).
14G. Guelachvili, Opt. Comm. 8, 171-175 (1973).
15R. Farrenq, G. Guelachvili, A. J. Sauval, N. Grevesse, and C. B. Farmer, J. Mol. Spectrosc. 149,
375-390 (1991).
16C. Amiot and G. Guelachvili, J. Mol. Spectrosc. 51, 475-471 (1974).
17C. Amiot and G. Guelachvili, J. Mol. Spectrosc. 59, 171-190 (1976).
18J.-M. Flaud, C. Camy-Peyret, and R.A. Toth, Water Vapor Line Parameters from Microwave to
Medium Infrared, Pergamon Press (1981).
19C. Camy-Peyret, J.-M. Flaud, and J.-P. Maillard, J. Phys.-Letters 41, 23-26 (1980).
20T. Oshima and H. Sasada, J. Mol. Spectrosc. 136, 250-263 (1989).
21See, for instance, Metrologia, 19, 163-177 (1984).
*One second is identified as the duration of 9 192 631 770 periods of the radiation corresponding to
the transition between the two hyperfine levels of the ground state of the cesium - 133 atom; F=4, m=0
F
to F=3, m =0 transition of the fundamental state 2S of 133Cs.— NBS Spec. Publ. (U.S.) (1977).
F 1/2
Introduction ιχ
Os0 and C0 . To be sure, our interest in these handbooks has always been to ad-
4 2
dress ourselves to the development and availability of sufficient numbers of stan-
dards in the entire infrared. To that extent, in Section IV of the present book we
have included FTS generated spectral maps and wavenumber data for the CHC1
3
molecule in the region of 1309-1594 cm-1 for supplementing water vapor standards'
that may not be suitable in certain specific experiments.
Finally, we have provided summary maps so one can, at a glance, find out what
information has been made available in these handbooks from FTS techniques. The
summary map for this handbook appears on its inside front cover page; the same
type of map for the previous handbook appears on the inside of the back cover page
for convenient cross-reference.
Before concluding this introduction we are indeed very gratified that numerous
scientists around the world assisted us through discussions and other ways in bring-
ing out this book. We are particularly grateful to Jean COLLET and Alain UBEL-
MANN who are in charge of the high resolution interferometer at LPMA in Orsay,
France. We express our sincere thanks to:
In Belgium: A. BELAFHAL and Andre FAYT
In Czechoslovakia: Stepan URBAN
In Finland: Rauno ANTTILA
In France: Claude ALAMICHEL, Claude AMIOT, Christian BORDE, Claude
CAMY-PERET, Pierre CEREZ, Christian CHARDONNET, Jean-Marie
FLAUD, Nicole HUSSON, Qingli KOU, Jean-Yves MANDIN, and Mireille
MORILLON-CHAPEY
In Germany: Manfred WINNEWISSER and Brenda WINNEWISSER
In India: Romola DCUNHA
In Japan: Eizi HIROTA, Tetsuya OHSHIMA, Hiroyuki SASADA
In Morocco: Najate BEN SARI ZIZI
In USA: Arlan MANTZ and Paul ORMSBY
We also benefitted by meetings related to the subject "Unified wavenumber stan-
dards" of the IUPAC: 1992 members of which are:
M. BIRK, C. BORDE, J. BRAULT, L. R. BROWN, B. CARLI, A. R. H. COLE,
K. M. EVENSON, A. FAYT, G. GUELACHVILI, D. HAUSAMANN,
J. W. C. JOHNS, J. KAUPPINEN, Q. KOU, A. G MAKI, K. N. RAO,
W. URBAN, A. VALENTIN, J. VERGES, G WAGNER, M. WINNEWISSER,
and B. WINNEWISSER.
Finally, we appreciate the interest shown by Bureau National de Metrologie.
SECTION I
MAPS AND WAVENUMBER TABLES FOR THE NEW
SPECTRAL COVERAGE: 1.4 /tm-4 μνη
The spectra for this handbook have all been recorded with the high resolution Fourier
interferometer at the Laboratoire de Physique Moleculaire et Applications (LPMA)
in Orsay22, France. The apodized spectral resolution used in most cases was about
5.5 x 10 3 cm ~'. The spectra were calibrated with respect to the i> band of l2Cl60
3 2
and the l — 0 and 2 — 0 bands of l2Cl60; the absolute accuracy of the spectral posi-
tions is believed to be better than 0.001 cm"1. The pressure and path length informa-
tion of the gases appears on the right hand top corner of each of the spectral maps.
The format of this handbook is essentially the same as in prior efforts of this type.
That is, in pages 2-571, one sees a spectral map on one side and wavenumber data
on the other. Most of the entries here are self-explanatory. Each of the spectral lines
is identified either by a symbol or by a vertical bar, and a serial number has been
given to it. The wavenumbers and transition assignments appearing on the page
opposite each map are listed against serial numbers, which correspond exactly to
the numbers on the map.
!G. Guelachvili, Applied Opt. 17, 1322-1326 (1978).
2
3
IC ES 2CH 2CH 2CH 2CH 2CH 2CH
TOP ECI 21C 21C 21C 21C 21C 21C
ISO SP 1H 1H 1H 1H 1H 1H
ND 2 2 3 3 e.
BA TS ag
N p
TIONAL SIGNME (15) (20) (14) (19) (13) (18) osite
TA AS P P P P P P pp
O o
R
AVENUMBER 1, VAC CM' 4. 20308 11) 4. 35139 11) 65) 4. 47289 27) 4.52422 22) 4. 84123 15) 4. 87608 14) 5. 15426 23) 5.62325 23) 5.76217 12) 6.34792 12) 6.59551 54) 6.64885 6.78423 13) 21) 6.81752 54) 7.27367 7.36711 11) 7.45258 11) 16) 7.97148 46) 8. 23618 56) 8. 40709 8. 46795 11) 39) 8. 80861 12) 8. 94207 8. 97486 11) 11) 9. 21033 9.39381 11) 23) 9. 53408 12) 9. 82312 12) 9. 84772 ( 19) 0. 12288 the map on the
W 263263263263263263263263263263 263263263263263263263263263263 263263263263263263263263263264 in s.
LINE NO. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 line enthese
ral par
OP IC CIES 12CH 12CH spect ven in
ISOTSPE 12HC 12HC the is gi
ROTATIONAL BAND ASSIGNMENTS P (16) 2 P (21) 3 number identifying mental value. digit of the wavenumber on the opposite page.
WAVENUMBER 1CM', VAC 67) 2630. 20538 54) 2630. 45051 23) 2630. 53888 25) 2630. 70931 21) 2630. 72865 67) 2630. 97181 43) 2631.11137 22) 2631. 14020 24) 2631. 40895 56) 2631. 43734 2631. 68702 35) 12) 2631. 79748 22) 2631.87567 13) 2631.91184 18) 2631.99783 21) 2632. 07638 32) 2632. 17770 20) 2632.28741 13) 2632.37459 67) 2632. 54450 31) 2632. 58302 28) 2632. 65618 22) 2632.68663 35) 2632. 90315 51) 2633.13785 60) 2633.17862 36) 2633.19697 27) 2633. 47713 17) 2633.87185 ( 18) 2633.97391 LINE NO.": serial WAVENUMBER": experincertainty in the last BAND" : identification
INE NO. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 - "- "- U- "
L
2
5
IC ES CH CH CH CH CH CH CH CH
OP CI 1212 12 12 12 12 1212
T E CC C C C C CC
ISO SP 12H12H 2H1 12H 12H 12H 12H12H

e
BAND TS 2 1 3 2 3 2 1 3 e pag
TATIONAL ASSIGNMEN P (11) P (18) P (16) P (10) P (15) P ( 9) P (16) P (14) e opposi t
O h
R t

n
LINE WAVENUMBER 1NO. CM', VAC 91 11)2643. 35382 92 11)46718 2643. 93 11)55787 2643. 94 12)2643. 62583 95 11)67122 2643. 96 11)2644. 04320 97 61)40388 2644. 98 13)60239 2644. 99 12)2644. 77978 100 32)2645. 31105 101 63)2645. 98454 102 12)2646. 45030 103 16)65773 2646. 104 63)68568 2646. 105 43)71610 2646. 106 11)2647. 23183 107 46)43692 2647. 108 39)75192 2647. 109 21)35972 2648. 110 63)39258 2648. 27)70854 2648. 11 1 112 11)85144 2648. 113 60)97898 2648. 114 57)05094 2649. 115 19)23 004 2649. 116 19)34423 2649. 117 45)46206 2649. 118 41)49090 2649. 119 46)56376 2649. 120 12)67549 2649. 121 27)84475 2649. 122 04197 2650. ( 16) r I ali ne i r l the map o rentheses. a
p
I C ES CH CH pect n in
ISOTOP SPECI 1212HC 1212CH the s is give
ROTATIONAL BAND ASSIGNMENTS P (12) 2 P (17) 3 number Identifying mental value. digit of the wavenumber on the opposite page.
WAVENUMBER 1CM", VAC 11) 2640. 22998 18) 2640. 35572 38) 45494 2640. 32) 48897 2640. 20) 54303 2640. 31) 56995 2640. 12) 61439 2640. 27) 68229 2640. 39) 77177 2640. 26) 2640. 90511 11) 97624 2640. 66) 2641. 06028 22) 2641. 20653 11) 2641. 31561 14) 2641. 34114 21) 2641. 46902 11) 2641. 63217 25) 2641. 68775 23) 2641. 85903 11) 2641. 92667 66) 04678 2642. 48) 11992 2642. 11) 19842 2642. 11) 31852 2642. 44750 11) 2642. 11) 2642. 67403 11) 87794 2642. 37) 98193 2642. :05919 2643. ID 21784 2643. ( 11) LINE NO.": serial WAVENUMBER": experincertainty in the last BAND" : identification
INE NO. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 - "- "- U- "
L