Green Sustainable Process for Chemical and Environmental Engineering and Science: Switchable Solvents

242 Pages·2021·19.347 MB·English

by  Inamuddin, Rajender Boddula, Abdullah M. Asiri

GREEN SUSTAINABLE
PROCESS FOR
CHEMICAL AND
ENVIRONMENTAL
ENGINEERING AND
SCIENCE
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GREEN SUSTAINABLE
PROCESS
FOR CHEMICAL
AND ENVIRONMENTAL
ENGINEERING
AND SCIENCE
Switchable Solvents
Edited by
INAMUDDIN
Department of Applied Chemistry,Zakir Husain College of
Engineering and Technology, Facultyof Engineering and Technology,
Aligarh Muslim University, Aligarh,India
RAJENDER BODDULA
CAS Key Laboratory of Nanosystemsand Hierarchical Fabrication,
NationalCenterforNanoscience and Technology, Beijing, China
ABDULLAH M. ASIRI
Department of Chemistry, Faculty of Science, King Abdulaziz
University, Jeddah, Saudi Arabia
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Contents
Contributors ix
1. Switchablesolvents for bio-refinery applications 1
MuhammadZubairandAmanUllah
1. Introduction 1
2. Conceptofbiorefinery 2
3. Switchablesolventsforbiorefinery 4
4. Concludingremarksandfutureperspectives 15
References 16
2. Polarity-changing solvents for CO capture 21
2
ZeynabRezaeiyan,ShokufehBagheri,MohammadAminSedghamiz,
andMohammadRezaRahimpour
1. Introduction 21
2. SwitchablesolventforCO capture 27
2
3. SwitchableionicliquidsolventforCO capture 32
2
4. Conclusions 34
References 35
3. Applications ofswitchable solventsinscience and technology 39
MohammadFarazAhmerandQasimUllah
1. Introduction 39
2. Switchablewater(SW) 45
3. Technologicalandanalyticalapplicationsofswitchablesolvents 47
4. Conclusions 54
References 54
4. Switchablesolvents for CO capture 61
2
SatishKumar
1. Introduction 61
2. EnvironmentalchallengesduetoCO 64
2
3. SwitchablesolventsforthedetectionofCO 66
2
4. SwitchablesolventsforCO extraction 67
2
5. ReversibleionicliquidsolventsforthecaptureofCO 90
2
v
vi Contents
6. Conclusions 94
Acknowledgments 94
References 94
5. Switchable water 101
Dr.ElsaCherian
1. Introduction 101
2. Switchablepolaritysolvents 101
3. Switchablehydrophilicitysolvents 103
4. Switchablewater 104
5. Conclusion 106
References 106
6. Switchable solvents as alternative solvents for green chemistry 109
DivyaBajpaiTripathy,AnjaliGupta,AnuradhaMishra,M.A.Quraishi,
MohammadLuqman,andMohd.FarhanKhan
1. Introduction 109
2. Discoveryofswitchablesolvents 111
3. Typesofswitchablesolvents 111
4. ChemistryanddevelopmentofSS 120
5. GenerallydesirablepropertiesofSS 122
6. Acceptabilityofswitchablesolventsforgreenchemistry 123
7. Applicationsofswitchablesolventsasgreenalternatives 124
8. Futureprospectsandconclusions 127
References 127
7. Nanomaterials synthesis inswitchable solvents 133
AnjaliGupta,DivyaBajpaiTripathy,MeenuAggarwal,MohammadLuqman,
andMohd.FarhanKhan
1. Introduction 133
2. Ionicliquidsasswitchablesolvents 134
3. Reversemicellesfornanoparticlessynthesis 136
4. Reversemicro-emulsionsfornanoparticlesynthesis 141
5. Reversiblecappingagentsbasedonamines 143
6. Conclusion 144
References 145
8. CO -triggered switchable polaritysolvents and their advancements 149
2
PinkiChakraborty,AnupamaSharma,MohammadLuqman,Mohd.FarhanKhan,
andKarthikaySankhydhar
1. Introduction 149
2. ChemistryofCO -triggeredSPS 150
2
Contents vii
3. CO -triggeredSPS 151
2
4. Challengesandfutureconsiderations 154
5. Conclusion 155
References 155
9. Switchablegreen solvents for lipidsextraction from microalgae 157
DebanjanSanyal,G.VenkataSubhash,NishantSaxena,WrijuKargupta,AjitSapre,
andSantanuDasgupta
1. Introduction 157
2. Greensolvents 158
3. Microalgaelipidandextractionprocess 158
4. Perspectiveandconclusion 170
References 170
Furtherreading 174
10. CO triggered switchable and tunable solventsfor biocatalysis 177
2
K.K.AthiraandRameshL.Gardas
1. Introduction 177
2. Tunablesolventsforbiocatalysis 178
3. Switchablesolventsforbiocatalysis 180
4. Conclusionsandfutureperspectives 187
Acknowledgments 187
References 187
11. Basicsynthesisandsolvatochromicparametersinswitchablesolvents 191
NaushadAnwar,NimraShakeel,andMohdImranAhamed
1. Introduction 191
2. Chemicalsynthesisinaswitchablesolvent 192
3. Theoryonsolvatochromismprocess 193
4. Solvatochromicparameters 194
5. Conclusion 197
References 197
12. Switchable solventsfor catalysis 201
SaurabhJain,ShashankSharma,MohammadLuqman,
andMohd.FarhanKhan
1. Introduction 201
2. Switchablehydrophilicsolvents 202
3. Solventswithswitchablepolarity 207
4. Switchablewater 209
viii Contents
5. Surfaceoperation(switchablecationic/anionicsurfactants) 212
6. Materialsthatrespondtostimuli 214
7. Applicationofswitchablesolventsascatalyst 215
8. Switchablesolventsforbiocatalysis 216
9. Conclusions 217
References 217
Index 225
Contributors
Meenu Aggarwal
Departmentof Chemistry,Aggarwal College, Faridabad, Haryana, India
Mohd ImranAhamed
Departmentof Chemistry,Aligarh Muslim University, Aligarh,Uttar Pradesh, India
MohammadFaraz Ahmer
Departmentof Electrical and Electronics Engineering, Mewat Engineering College, Nuh,
Haryana, India
Naushad Anwar
Departmentof Chemistry,Aligarh Muslim University, Aligarh,Uttar Pradesh, India
K.K. Athira
Departmentof Chemistry,Indian Institute of Technology Madras,Chennai, India
Shokufeh Bagheri
Departmentof Chemical Engineering, Shiraz University, Shiraz, Iran
Pinki Chakraborty
School of Basic &Applied Sciences, Galgotias University, Greater Noida,India
Dr. Elsa Cherian
Departmentof Food Technology, SAINTGITS College of Engineering, Kottayam,
Kerala, India
Santanu Dasgupta
Reliance Industries Limited, Jamnagar,Gujarat, India
Ramesh L. Gardas
Departmentof Chemistry,Indian Institute of Technology Madras,Chennai, India
Anjali Gupta
DepartmentofChemistry,SchoolofBasicandAppliedSciences,GalgotiasUniversity,Greater
Noida, India
Saurabh Jain
Departmentof Biotechnology, MGIMT, Banthra, Lucknow, India
Wriju Kargupta
Monash University, Melbourne, VIC, Australia
ix