Epoxy Resins, Curing Agents, Compounds, and Modifiers: An Industrial Guide

520 Pages·1993·17.99 MB·English

by  Ernest W. Flick

EPOXY RESINS,
CURING AGENTS,
COMPOUNDS,
AND MODIFIERS
An Industrial Guide
Second Edition
by
Ernest W. Flick
I n NOY ES PUBLICATIONS
PI park ridge, New Jersw. U.S.A.
thgirypoC 8 1993 yb tsenrE .W kcilF
oN trap fo siht koob yam eb decudorper ro dezilitu ni
yna mrof ro yb yna ,snaem cinortcele ro ,lacinahcem
gnidulcni ,gniypocotohp gnidrocer ro yb yna -amrofni
noit egarots dna laveirter ,metsys tuohtiw noissimrep
ni gnitirw morf eht .rehsilbuP
yrarbiL fo ssergnoC golataC draC :rebmuN 92-32993
:NBSI O-8155-1322-4
detnirP ni eht detinU setatS
dehsilbuP ni eht detinU setatS fo aciremA yb
seyoN snoitacilbuP
IIiM ,daoR Park ,egdiR weN yesreJ 07656
10987654321
yrarbiL fo ssergnoC noitacilbuP-ni-gnigolataC Data
,kciR tsenrE .W
yxopE ,sniser gniruc ,stnega ,sdnuopmoc dna sreifidom : an
lairtsudni ediug yb/ tsenrE .W ,kcilF -- dn2 .de
.p .mc
sedulcnI .xedni
NBSI O-8155-1322-4
1. yxopE .sniser .I .eltiT
TP1180.E6P56 1992
668’.374--&20 92-32993
PIC
To
Evelyn and the late Donald Bartlett
and
Vella and Phil, Marilyn and wid, Alden and Dottie
and
their families
V
Preface
sihT koob sniatnoc desnednoc snoitpircsed of erom naht 2800 etad-ot-pu yxope
,sniser gniruc ,stnega yxope sdnuopmoc dna suoenallecsim .sreifidom tI lliw eb
of eulav ot lacinhcet dna laireganam lennosrep devlovni ni the erutcafunam dna
esu of the lanif stcudorp edam morf these suoirav sniser dna gniruc .stnega
yxopE sniser evah decneirepxe suodnemert growth ecnis rieht noitcudortni ni the
1950s. Rather naht gnimoceb a lanoitidart ytidommoc ,meti ,revewoh yeht are
won gnimoceb erom of a ytlaiceps .lacimehc New selucelom are ylraluger gnieb
,depoleved dna gnitsixe seno yltnatsnoc ,deifidom ot evig devorpmi ecnamrofrep
ni lanoitidart ,snoitacilppa as llew as wen snoitacilppa ni ygolonhcet-hgih areas.
erutuF growth appears ot eil ni the noitulove of wen stekram ni the ytlaiceps
ecnamrofrep areas.
ehT data ni the koob tneserper snoitceles morf 71 ’srerutcafunam evitpircsed
,erutaretil edam at on cost to, ron ecneulfni ,nroh the srekam or srotubirtsid of
these .slairetam tI si deveileb that lla of the raw slairetam dna dehsinif stcudorp
detsil are yltnerruc ,elbaliava hcihw lliw eb of tseretni ot readers denrecnoc htiw
raw lairetam .secnaunitnocsid
ehT koob si dedivid otni the gniwollof ruof :snoitces
.I yxopE sniseR
.II gniruC stnegA
.III yxopE sdnuopmoC
.VI suoenallecsiM sreifidoM
Each raw lairetam or tcudorp si ,debircsed as ,elbaliava htiw lacipyt yassa ro/dna
check tniop ,serugif dna osla a feirb noitpircsed gnizirammus tnatropmi serutaef
or snoitacilppa of the raw lairetam or .tcudorp
vii
viii Preface
Each raw lairetam or tcudorp has neeb detsil ni the noitces hcihw smees tsom
;elbacilppa ,revewoh the reader gnikees a raw lairetam or tcudorp dluohs check
each noitces hcihw dluoc ylbissop .ylppa
owT lanoitidda snoitces lliw osla eb lufesu ot the eht-redaer ’sreilppuS
,sesserddA dna a edarT emaN .xednI ehT elbat of stnetnoc si dezinagro ni hcus
a yaw as ot evres as a tcejbus .xedni
yM tselluf noitaicerppa si expressed ot the seinapmoc dna snoitazinagro who
deilppus the data dedulcni ni siht .koob
,rebotcO 1992 tsenrE .W kcilF
NOTICE
oT the tseb of ruo egdelwonk the noitamrofni ni siht
noitacilbup si ;etarucca revewoh the rehsilbuP does ton emussa
yna ytilibisnopser for the ycarucca or ssenetelpmoc of, or
secneuqesnoc gnisira ,morf hcus .noitamrofni sihT lairtsudnI
ediuG does ton troprup ot niatnoc deliated resu ,snoitcurtsni
dna yb sti egnar dna scope dluoc ton ylbissop do so. noitneM
of trade seman or laicremmoc stcudorp does ton etutitsnoc
tnemesrodne or noitadnemmocer for esu yb the .rehsilbuP
yxopE raw slairetam nac eb ,cixot dna therefore eud noituac
dluohs syawla eb desicrexe ni the esu of yna yllaitnetop
suodrazah .slairetam laniF noitanimreted of the ytilibatius of
yna noitamrofni or tcudorp for esu detalpmetnoc yb yna ,resu
dna the rennam of that ,esu si the elos ytilibisnopser of the
.resu eW ylgnorts dnemmocer that sresu seek dna adhere ot a
s’rerutcafunam or s’reilppus tnerruc snoitcurtsni for gnildnah
each lairetam yeht .esu
Contents and Subject Index
NOITCES I
EPOXY SNISER
Ciba-Geigy Corp. ........................................ 2
ETIDLARA diuqiL yxopE sniseR .......................... 2
lonehpsiB F yxopE sdiuqiL ............................... 4
detanimorB yxopE sdiuqiL ............................... 5
citahpilaolcyC yxopE sdiuqiL ............................. 6
cinortcelE edarG slairetaM ............................... 7
CINOBlARA
yxopE snoituloS ....................................... 8
lanoitcnufitluM yxopE sdiuqiL ............................ 11
diloS yxopE sniseR .................................... 13
laicepS sniseR ....................................... 17
UATRIMID
ytlaicepS diloS yxopE .................................. 19
CVC Specialty Chemicals, Inc. .............................. 21
ytlaicepS yxopE tcudorP eniL ............................ 21
EPALLO~ ERISYS
Dow Chemical .A.S.U ..................................... 22
D.E.R. diuqiL yxopE :sniseR lonehpsiB epyT-A sniseR ......... 22
D.E.R. diuqiL yxopE :sniseR dezylatacerP niseR ............... 23
detuliD sniseR ....................................... 23
locylgyloP epyT sniseR ................................. 23
WOD diuqiL yxopE sniseR .............................. 24
WOD diuqiL yxopE sniseR gniniatnoC a evitcaeR tneuliD ....... 26
WOD dezylatacerP diuqiL yxopE sniseR .................... 26
Hoechst Celanese Corp. ................................... 27
ix
x Contents and Subject Index
XOPOKCEB edixopE sniseR ............................. 27
XOPOKCEB detalumroF edixopE niseR smetsyS .............. 30
DUROXIU
Polychem Corp. ......................................... 32
JEWEL EZALG yxopE sniseR ........................... 32
JEWEL EZALG ytlaicepS yxopE sniseR .................... 33
laicepS evisehdA sniseR ................................ 34
Reichhold Chemicals, Inc. ................................. 35
TNILFORA retseyloP-yxopE sniseR ....................... 35
FUTOPE yxopE Esters ................................. 36
FUTOPE diuqiL yxopE sniseR ............................ 37
FUTOPE niseR snoituloS ............................... 41
FUTOPE diloS yxopE sniseR ............................. 43
YXOPLEK remotsalE deifidoM yxopE ...................... 44
Rhone-Poulenc, Inc. ..................................... 45
ZER-IPE remotsalE deifidoM sniseR ....................... 45
ZER-IPE yxopE niseR snoituloS .......................... 46
ZER-IPE diuqiL yxopE sniseR ........................... 48
ZER-IPE diloS yxopE sniseR ............................ 50
ZER-IPE elbicudeR/enrobretaW sniseR ..................... 51
XET-IPE yxopE Ester sniseR ............................ 53
detanimorB yxopE sniseR ............................... 55
HELOXY
hgiH ecnamrofreP lanoitcnufyloP ZER-IPE yxopE sniseR ........ 56
Shell Chemical Co. ...................................... 57
EPON sniseR dna niseR snoituloS ......................... 57
EPON sdiuqiL-sniseR .............................. 57
EPON sdiloS-sniseR ............................... 58
Powder gnidloM/gnitaoC Powder sdiloS .................. 59
EPON detanimorB-sniseR snoituloS .................... 61
EPON snoituloS-sniseR ............................. 61
EPON seitlaicepS-sniseR dna lanoitcnufitluM sniseR ....... 65
EPONOL sniseR ................................... 66
lonehpsiB A ...................................... 67
SHELL
stneuliD/setaidermetnI ............................... 68
CARDURA
EPONEX sniseR ...................................... 69
SHELL sniseR for detnirP gniriW Boards .................... 70
SECTION II
CURING AGENTS
qjinomoto Co., Inc. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Contents and Subject Index xi
ERUCIJA tnetaL gniruC stnegA ........................... 74
ERUC-ESY yxopE gniruC stnegA ......................... 75
Anhydrides and Chemicals Inc. ............................. 78
edirdyhnA yxopE smetsyS ............................... 78
AC-METHYL
BASF Carp ............................................. 82
NIMORAL enimA srenedraH ............................. 82
Buffalo Color Corp. ...................................... 83
ciniccuslynecedoD edirdyhnA ............................ 83
cilahthpordyhaxeH edirdyhnA ............................ 83
lyhteM cilahthpordyhaxeH edirdyhnA ....................... 84
CIDAN lyhteM edirdyhnA ............................... 84
ciniccuS edirdyhnA .................................... 84
Ciba-Geigy Corp. ....................................... 85
srotareleccA ......................................... 85
citahpiIA senimA ..................................... 87
sedirdyhnA .......................................... 89
citamorA senimA ..................................... 91
citahpilaolcyC senimA ................................. 94
ERUCAGRI 261 cinoitaC rotaitiniotohP ..................... 95
sedimayloP .......................................... 96
laicepS srenedraH ..................................... 99
Gray Valley Products Inc. ................................ 101
ERUCKCIUQ 195X tsaF gniyrD evitcaeR edimayloP .......... 101
CVC Specialty Chemicals, .cnI ............................. 102
gniruC srotareleccA/stnegA ............................. 102
ERISYS
Dow Chemical U.S.A. .................................... 103
gniruC :stnegA citahpilA senimayloP dna stcuddA ............ 103
D.E.H.
gniruC :stnegA citamorA senimayloP ...................... 104
CURITWE
gniruC :stnegA sedirdyhnA ............................. 10.5
gniruC :stnegA sedimayloP ............................. 107
KUWM.ID, EUREDVR, ANWIDE
gniruC :stnegA citylataC gniruC stnegA .................... 108
Emerson & Cuming, Inc. ................................. 109
:sevisehdA gniruC stnegA .............................. 109
:stnaluspacnE gniruC stnegA ............................ 111
Henkel Polymers Division ................................ 112
DIMANEG yxopE gniruC stnegA ........................ 112
DIMASREV yxopE gniruC stnegA ........................ 114
ENIMASREV yxopE gniruC stnegA ...................... 116
Hoechst-Celanese Corp. ................................. 121
xii Contents and Subject Index
XOPOKCEB laicepS srenedraH .......................... 121
Based on Polyamine, Based on Polyaminoamide
Huls America Inc. ...................................... 126
yxopE/enimA renedraH Raw slairetaM ..................... 126
VESTMIN, K!?STAGON
The Humphrey Chemical Co. ............................. 128
lynekIA dna lykIA detutitsbuS ciniccuS sedirdyhnA ............ 128
latnempoleveD lynekIA dna lykIA ciniccuS ,sedirdyhnA
lykIA cielaM sedirdyhnA ............................. 131
Leepoxy Plastics, Inc. .................................... 134
ERUCEEL B srenedraH ............................... 134
Lindau Chemicals Inc. ................................... 136
sedirdyhnA ......................................... 136
LINDRIDE
enimalyhtemidlyzneB )AMDB( .......................... 141
muinommalyhteirtlyzneB edirolhC )CAETB( ................ 141
muinommalyhtemirtlyzneB edirolhC )CAMTB( ............... 141
citylataC:1-XADNIL gniruC tnegA ....................... 141
Milliken Chemicals ..................................... 142
ENIMALLIM 5260 yxopE gniruC tnegA ................... 142
EDIRDLLIM sedirdyhnA .............................. 143
Pacific Anchor Chemical Corp. ............................ 145
yxopE gniruC :stnegA citahpiIA senimA .................... 145
.~UC..fbA ANCAMINE, SUR- WET
yxopE gniruC :stnegA senimaodimA ...................... 151
AhXXM.IDE
yxopE gniruC :stnegA citamorA senimA ................... 152
yxopE gniruC :stnegA citahphaolcyC senimA ................ 155
yxopE gniruC :stnegA sedimayloP ........................ 158
CIFICAP ROHCNA yxopE gniruC :stnegA ,FB sexelpmoC ...... 160
CIFICAP ROHCNA yxopE gniruC :stnegA sedimanayciD ....... 162
DICYANEX
CIFICAP ROHCNA yxopE gniruC :stnegA selozadimI ......... 164
IMICURE, CUREZOL
CIFICAP ROHCNA yxopE gniruC :stnegA lateM Based
stsylataC ......................................... 166
METACURE
CIFICAP ROHCNA yxopE gniruC :stnegA yraitreT senimA ..... 167
retaW elbisrepsiD gniruC stnegA ......................... 168
ANQUAMINE, CIASAMID
PMC Specialties Group, Inc. .............................. 169
enimalyhtemidlyzneB ................................. 169
Polychem Corp. ........................................ 170
yxopE renedraH Chart ................................. 170