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About Electrochemistry Lecture 2 - Notes
The Butler-Volmer equation describes how the current flowing at an electrode depends on the electrode potential. It considers both the cathodic and anodic reactions that occur. The equation contains terms for exchange current density, temperature, number of electrons transferred, Faraday's constant, electrode potential, and symmetry factor. At small potentials, the equation simplifies to a linear relationship between current and potential. At large potentials, it takes on an exponential form known as the Tafel equation. The exchange current density and transfer coefficient can be determined from Tafel plots of logarithmic current versus potential. Mass transport such as diffusion and convection also influence the reaction rate and can control the overall process. Fick's laws of diffusion describe how
Detailed Information
Author: | ['Craftychemist'] |
---|---|
Publication Year: | 2015 |
Pages: | 17 |
Language: | English |
Format: | |
Price: | FREE |
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