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About Design, Synthesis and Characterization of new Supramolecular Architectures
This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.
Detailed Information
| Author: | Massimo Baroncini (auth.) |
|---|---|
| Publication Year: | 2011 |
| ISBN: | 9783642192845 |
| Pages: | 105 |
| Language: | English |
| File Size: | 1.842 |
| Format: | |
| Price: | FREE |
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