Table Of ContentCATIONIC
SURFACTANTS
SURFACTANT SCIENCE SERIES
CONSULTING EDITORS
MARTIN J. SCHICK FREDERICK M. FOWKES
Consultant (1915-1990)
New York, New York
1. Nonionic Surfactants, edited by Martin J. Schick (see also Volumes 19
and 231 ·
2. Solvent Properties of Surfactant Solutions, edited by Kozo Shinoda (out
of print)
3. Surfactant Biodegradation, by R. D. Swisher (see Volume 181
4. Cationic Surfactants, edited by Eric Jungermann (see also Volumes 34
and 371
5. Detergency: Theory and Test Methods (in three parts), edited by W. G.
Cutler and R. C. Davis (see also Volume 201
6. Emulsions and Emulsion Technology (in three parts), edited by Kenneth
J. Lissant
7. Anionic Surfactants (in two parts), edited by Warner M. Linfield (out of
print)
8. Anionic Surfactants: Chemical Analysis, edited by John Cross (out of
print)
9. Stabilization of Colloidal Dispersions by Polymer Adsorption, by Tatsuo
Sato and Richard Ruch
10. Anionic Surfactants: Biochemistry, Toxicology, Dermatology, edited by
Christian Gloxhuber (see Volume 431
11. Anionic Surfactants: Physical Chemistry of Surfactant Action, edited
by E. H. Lucassen-Reynders (out of print)
12. Amphoteric Surfactants, edited by B. R. Bluestein and Clifford L. Hilton
(out of print)
13. Demulsification: Industrial Applications, by Kenneth J. Lissant
14. Surfactants in Textile Processing, by Arved Datyner
15. Electrical Phenomena at Interfaces: Fundamentals, Measurements, and
Applications, edited by Ayao Kitahara and Akira Watanabe
16. Surfactants in Cosmetics, edited by Martin M. Rieger
17. lnterfacial Phenomena: Equilibrium and Dynamic Effects, by Clarence
A. Miller and P. Neogi
18. Surfactant Biodegradation, Second Edition, Revised and Expanded, by
R. D. Swisher
19. Nonionic Surfactants: Chemical Analysis, edited by John Cross
20. Detergency: Theory and Technology, edited by W. Gale Cutler and Erik
Kissa
21 . lnterfacial Phenomena in Apolar Media, edited by Hans-Friedrich Eicke
and Geoffrey D. Parfitt
22. Surfactant Solutions: New Methods of Investigation, edited by Raoul
Zana
23. Nonionic Surfactants: Physical Chemistry, edited by Martin J. Schick
24. Microemulsion Systems, edited by Henri l. Rosano and Marc Clausse
25. Biosurfactants and Biotechnology, edited by Naim Kosaric, W. L.
Cairns, and Neil C. C. Gray
26. Surfactants in Emerging Technologies, edited by Milton J. Rosen
27. Reagents in Mineral Technology, edited by P. Somasundaran and Brij
M. Moudgil
28. Surfactants in Chemical/Process Engineering, edited by Darsh T.
Wasan, Martin E. Ginn, and Dinesh 0. Shah
29. Thin Liquid Films, edited by I. B. Ivanov
30. Microemulsions and Related Systems: Formulation, Solvency, and
Physical Properties, edited by Maurice Bourrel and Robert S. Schecter
31 • Crystallization and Polymorphism of Fats and Fatty Acids, edited by
Nissim Garti and Kiyotaka Sato
32. lnterfacial Phenomena in Coal Technology, edited by Gregory D.
Botsaris and Yuli M. Glazman
33. Surfactant-Based Separation Processes, edited by John F. Scamehorn
and Jeffrey H. Harwell
34. Cationic Surfactants: Organic Chemistry, edited by James M.
Richmond
35. Alkylene Oxides and Their Polymers, by F. E. Bailey, Jr., and Joseph
V. Koleske
36. lnterfacial Phenomena in Petroleum Recovery, edited by Norman R.
Morrow
37. Cationic Surfactants: Physical Chemistry, edited by Donn N. Rubingh
and Paul M. Holland
38. Kinetics and Catalysis in Microheterogeneous Systems, edited by M.
Gratzel and K. Kalyanasundaram
39. lnterfacial Phenomena in Biological Systems, edited by Max Bender
40. Analysis of Surfactants, by Thomas M. Schmitt
41. Light Scattering by Liquid Surfaces and Complementary Techniques,
edited by Dominique Langevin
42. Polymeric Surfactants, by lrja Piirma
43. Anionic Surfactants: Biochemistry, Toxicology, Dermatology. Second
Edition, Revised and Expanded, edited by Christian G/oxhuber and
Klaus Kunst/er
44. Organized Solutions: Surfactants in Science and Technology, edited by
Stig E. Friberg and Bjorn Lindman
45. Defoaming: Theory and Industrial Applications, edited by P. R. Garrett
46. Mixed Surfactant Systems, edited by Keizo Ogino and Masahiko Abe
4 7. Coagulation and Flocculation: Theory and Applications, edited by
Bohuslav Dobia§
48. Biosurfactants: Production ·Properties ·Applications, edited by Naim
Kosaric
49. Wettability, edited by John C. Berg
50. Fluorinated Surfactants: Synthesis · Properties · Applications, Erik
Kissa
51. Surface and Colloid Chemistry in Advanced Ceramics Processing,
edited by Robert J. Pugh and Lennart Bergstrom
52. Technological Applications of Dispersions, edited by Robert B. McKay
53. Cationic Surfactants: Analytical and Biological Evaluation, edited by
John Cross and Edward J. Singer
ADDITIONAL VOLUMES IN PREPARATION
CATIONIC
SURFACTANTS
Analytical and Biological
Evaluation
edited by
John Cross
University of Southern Queensland
Toowoomba, Queensland, Australia
Edward J. Singer
Mobil Oil Corporation
Princeton, New Jersey
Marcel Dekker, Inc. New York• Basel• Hong Kong
Library of Congress Cataloging-in-Publication Data
Cationic surfactants: analytical and biological evaluation I edited by John Cross,
Edward J. Singer.
p. cm. -- (Surfactant science series; v. 53)
Includes bibliographical references and index.
ISBN 0-8247-9177-0 (acid-free)
1. Surface active agents. I. Cross, John. II. Singer, Edward J.
III. Series.
TP994.C382 1994
541.3'3--dc20 93-48585
CIP
The publisher offers discounts on this book when ordered in bulk quan
tities. For more information, write to Special Sales/Professional Marketing
at the address below.
This book is printed on acid-free paper.
Copyright© 1994 by Marcel Dekker, Inc. All Rights Reserved.
Neither this book nor any part may be reproduced or transmitted in any
form or by any means, electronic or mechanical, including photocopying,
microfilming, and recording, or by any information storage and retrieval
system, without permission in writing from the publisher.
Marcel Dekker, Inc.
270 Madison Avenue, New York, New York 10016
Current printing (last digit):
10 9 8 7 6 5 4 3 2 1
PRINTED IN THE UNITED STATES OF AMERICA
Preface
Of the cationic surfactants utilized in today's marketplace, quaternary am
monium compounds ( quats) represent by far the largest proportion. Amer
ican Oil Chemists' Society newswriter Anna Gillis has described quats as
"the ultimate workhorse of the surfactant industry. They are, for example,
used to decolorize sugar, kill bacteria in water beds, and loosen stubborn
oil in oil wells. They are found in a huge range of commercial preparations
from underarm deodorants to fiber glass resins. Mostly, however, they are
used to keep the family laundry soft." Although the actual tonnage utilized
each year falls well below that of anionic and nonionic surfactants, the
market is well established and growing steadily. Some 200 million pounds
(90,000 metric tons) of quats are produced each year in the United States
alone.
One of the earliest treatises devoted solely to this class of compounds
was Volume 4 of Marcel Dekker's outstandingly successful Surfactant Science
Series, Cationic Surfactants, edited by Eric Jungermann, a substantial work
published in 1970 containing over 600 pages. Over 20 years later, there is
a much wider range of speciality uses to which they may be put. Advances
in techniques by which they may be examined have been considerable,
and, of course, the literature concerning their various properties has mush
roomed. Any attempt to update Volume 4 in a single volume would have
produced a book of totally unwieldy dimensions. Consequently, the topics
have been subdivided into Cationic Surfactants: Organic Chemistry (Vol.
34), Cationic Surfactants: Physical Chemistry (Vol. 37), and Cationic Sur
factants: Analytical and Biological Evaluation (this volume).
iii
iv Preface
The analytical segment of this book is aimed at practicing chemists and
the new breed of environmental scientists who possess a general back
ground in chemistry, including the basic concepts of classical and modern
chemical analysis. Similarly, in addressing both short- and long-term in
teractions of cationic surfactants with biological systems, the biological
section relies on the basic working knowledge of scientists and engineers,
and focuses on their need to understand the systems with which they work,
be they skin, health, or wastewater. Detailed familiarity with cationic sur
factants is not assumed, an introductory chapter being included for that
purpose.
It is not intended that this book should function as a laboratory manual,
although appropriate experimental procedures are included. It is, rather,
a critical guide to the literature and methodology currently available, a
tour through the array of weapons that the practicing scientist can bring
to bear on any particular problem. Seldom will there be any one "correct"
approach to that problem. In the case of analytical work, so much depends
on the nature of the sample and on the detail required by the end user of
the result.
The authors comprise an international collection of experienced aca
demics and practitioners. They have not been required to operate within
any preconceived framework or to confine their treatment to a specified
set of surfactants: rather, they have been encouraged to present their
material in the manner that best suits their own areas of expertise.
Our sincere thanks go to the authors, who have provided their contri
butions so readily, and to their employers for supporting their efforts; to
the Series Editor, Dr. Martin Schick, who has worked and liaised tirelessly
on our behalf; to Brenda Cross for her patience and many late nights
chained to an uncooperative word processor; to the Marcel Dekker or
ganization for their smooth guidance along the production chain; and fi
nally, to the many hundreds of researchers, past and current, whose pub
lished works have made this volume possible.
John Cross
Edward J. Singer
