Table Of ContentStudies in Surface Science and Catalysis 56
CATALYTIC OLEFIN POLYMERIZATION
Proceedings of the International Symposium on
Recent Developments in Olefin Polymerization
Catalysts, Tokyo, October 23- 25, 1989
This Page Intentionally Left Blank
Studies in Surface Science and Catalysis
Advisory Editors : B. Delmon and J. T. Yates
Vol. 56
CATALYTIC OLEFIN
PO LY ME RIZATION
PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON
RECENT DEVELOPMENTS IN OLEFIN POLYMERIZATION
CATALYSTS, TOKYO, OCTOBER 23-25,1989
Edited by
Tominaga Keii Professor Emeritus, Tokyo Institute of Technology
Kazuo Soga Professor, Tokyo Institute o f Technology
KODANSHA ELSEVIER
1990
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PRINTEIDN J APAN
List of Contributors
Numbers in parentheses indicate the chapter (5 ) in which the authors’ contributions appear.
Albornoz, A. (29)
Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela
Almquist, V. (6)
Statoil, 3960 Stathelle, Norway
Antberg, M. (35)
Hoechst AG, 6230 Frankfurt a. Main 80, F.R.G.
Arzoumanidis, G.G. (12)
Amoco Chemical Company, P. 0. Box 3011, Naperville, Illinois 60566, U.S.A.
Barazzoni, L. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Bark, A. (31)
Institut fiir Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King
Platz 6, 2 Hamburg 13, F.R.G.
Bernard, A. (30)
Solvay et Cie S.A., Laboratoire Central, Rue de Ransbeek 310, B-1120 Bruxelles, Belgique
Bobichon, C. (3) (8)
CNRS, Laboratoire des Materiaux Organiques, BP 24, 69390 Vernaison, France
B-, C. (9)
Groupe de Recherches de Lacq, BP34 LACQ, 64170 Artix, France
Bu, N. (4)
Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G
2G6
Chang, H.S. (21)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O. Box 131 Cheongryang, Seoul, Korea
Cheng, H.N. (32)
Research Center, Hercules Incorporated, Wilmington, Delaware 19894, U.S.A.
Chida, K. (15)
Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Inuna-gun,
Saitama 354, Japan
vj List of Contributors
Chien, J.C.W. (38)
Department of Polymer Science and Engineering, Department of Chemistry, University of
Massachusetts, Amherst, MA 01003, U.S.A.
Choi, H.K: (26)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O. Box 131, Cheongryang, Seoul, Korea
Chu, K.J. (21)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P. 0. Box 131, Cheongryang, Seoul, Korea
Chung, M.C. (26)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O.Box 131, Cheongryang, Seoul, Korea
Curtis, S. (32)
Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A.
Dake, I. (31)
Institut fur Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King
Platz 6, 2 Hamburg 13, F. R. G
Dolle, V. (35)
Hoechst AG, 6230 Frankfurt a. Main 80, F. R. G.
Duranel, L. (8)
Atochem G.R.L., BP 34 LACQ, 64170 Artix, France
Elder, M.J. (32)
Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A.
Endo, K. (18)
Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto,
Sumiyoshi-ku, Osaka 558, Japan
Ewen, J.A. (32)
Fina Oil and Chemical Company, P.O. Box 1200, Deer Park, Texas 77536, U.S.A.
Fenzl, W. (19)
Max-Planck-Institut & Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mulheim a.d.
Ruhr-1, F. R. G.
Ferrero, C. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Fiasse, P. (30)
Solvay et Cie S.A., Laboratoire Central, Rue de Ransbeek 310, B-1120 Bruxelles, Belgique
Fink, G.(19)
Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Miilheim a.d.
Ruhr-1, F.R.G.
Follestad, A. (6)
Statoil, 3960, Stathelle, Norway
Listof Gmhbium vii
Fuentes, A. (29)
Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela
Fujita, T. (17)
Yokkaichi Research Center, Mitsubishi Petrochemical Co., Ltd., 1 Toho-cho, Yokkaichi, Mie
510, Japan
Furuhashi, H. (14) (15)
Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Inuna-gun,
Saitama 354, Japan
Grubbs, R.H. (24)
Arnold and Mabel Bechman Laboratories of Chemical Synthesis, California Institute of
Technology, Pasadena CA 91125, U S A .
Guyot, A. (3) (8)
CNRS, Laboratoire des Materiaux Organiques, BP 24, 69390 Vernaison, France
Harkonen, M. (7)
Helsinki University of Technology, Department of Chemical Engineering, Kemistintie 1,
SF-02150 Espoo, Finland
Hattori, I. (25)
Elastomers Laboratory, Technical Center, Japan Synthetic Rubber Co., Ltd., 100 Kawajiri-cho,
Yokkaichi, Mie 510, Japan
Helleborg, S. (6)
Statoil, 3960 Stathelle, Norway
Herfert, N. (19)
Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Miilheim a.d.
Ruhr-1, F.R.G.
Ihm, S.K. (21)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, P.
0. Box 131, Cheongryang, Seoul, Korea
Iiskola, E. (11)
Polyolefins R & D, Neste Chemicals, SF-06850 Kulloo, Finland
Imai, M. (14)
Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun,
Saitama 354, Japan
Invernizzi, R. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Ishii, K. (22)
Toho Titanium Co. Ltd., 3-3-5 Chigasaki, Chigasaki-shi, Kanagawa 253, Japan
Jaber, I.A. (2) (19)
Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mdheim a.d.
Ruhr-1, F. R. G. (present address)
Jejelowo, M.O. (4)
Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G
2G6
vii List of Contributors
Job, J.F. (9)
CNRS, Laboratoire des Materiaux Organiques, BP 34, 69390 Vernaison, France
Jones, R.L. (32)
Fina Oil and Chemical Company, P.D. Box 1200, Deer Park, Texas 77536, U.S.A.
Kakugo, M. (13) (27) (36)
Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kimi-
tsu-gun, Chiba 299-02 Japan
Kaminsky, W. (31)
Institut fur Anorganische und Angewandte Chemie, Universitat Hamburg, Martin-Luther-King
Platz 6, 2 Hamburg 13, F.R.G.
Kang, K.S. (21)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O. Box 131, Cheongryang, Seoul, Korea
Karayannis, N.M. (12)
Amoco Chemical Company, P.O.Box 3011, Naperville, Illinois 60566, U.S.A.
Kashiwa, N. (33) (34)
Iwakuni Polymer Research Laboratories, Mitsui Petrochemical Industries, Ltd., Waki -cho,
Kuga-gun, Yamaguchi 740, Japan
Kataoka, T. (5)
Toho Titanium Co. Ltd., 3-3-5253, Chigasaki, Chigasaki-shi, Kanagawa 253, Japan
Keii, T. (1) (5)
Tokyo Institute of Technology, Preparation Committee of JAIST, Monbusho 7F1, Kasumigaseki
3-2-2, Chiyoda-ku, Tokyo 100, Japan
Kim, I. (26)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O.Box 131, Cheongryang, Seoul, Korea
Kim, J.H. (26)
Department of Chemical Engineering, Korea Advanced Institute of Science and Technology,
P.O.Box 131, Cheongryang, Seoul, Korea
Kioka, M. (33) (34)
Iwakuni Polymer Research Laboratories, Mitsui Petrochemical Industries, Ltd., Waki-cho,
Kuga-gun, Yamaguchi 740, Japan
Klein, R. (35)
Hoechst AG,6230 Frankfurt a. Main 80, F.R.G.
Lacombe, J.L. (3)
DPPG, Atochem, Mont, BP 3 Argagnon, 64300 Orthez, France
Lin, s. (20)
Institute of Polymer Science, Zhongshan University, Guangzhou, China
Liscano, J. (29)
Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela
List of Gmtribntm ix
Loontjens, A.J. (2)
DSM, Research and Patents, Geleen, Holland
Lynch, D.T. (4)
Department of Chemical Engineering, University of Alberta, Edmonton, Alberta, Canada T6G
2G6
Makino, K. (25)
Elastomers Laboratory, Technical Center, Japan Synthetic Rubber Co., Ltd., 100 Kawajiri-cho,
Yokkaichi, Mie 510, Japan
Mallin, D.T. (38)
Department of Polymer Science and Engineering, Department of Chemistry, University of
Massachusetts, Amherst, MA 01003, U.S.A.
Malquori, S. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Masi, F. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Menconi, F. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Mise, T. (37)
The Institute of Physical and Chemical Research, Hirosawa, Wako-shi, Saitama 351-01, Japan
Miya, S. (37)
Chisso Petrochemical Corporation, 5- 1 Goikaigan, Ichihara-shi, Chiba 290, Japan
Miyatake, T. (13) (36)
Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kmi-
tsu-gun, Chiba 299-02, Japan
Mizunuma, K. (13) (36)
Chiba Research Laboratory, Sumitomo Chemical Co. Ltd., 2-1 Kitasode, Sodegaura-cho, Kimi-
tsu-gun, Chiba 299-02, Japan
Moalli, A. (28)
EniChem Anic S.p.a., Polyolefins Division, Catalysts Research, S.Donato Milanese, Milano, Italy
Miiller, T. (19)
Max-Planck-Institut fur Kohlenforschung, Kaiser-Wilhelm-Platz-1, D-4330 Mulheim a.d.
Ruhr-1, F.R.G.
Munoz-Escalona, A. (29)
Polymer Laboratory, Chemistry Center, IVIC, Apartado 21827, Caracas 1020A, Venezuela
Murata, M. (14)
Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun,
Saitama 354, Japan
Nakano, A. (14) (15)
Tonen Sekiyukagaku K.K., Tonen Corporate Research & Development Laboratory, Iruma-gun,
Saitama 354, Japan
