Table Of ContentCarbon Nanomaterials in Clean Energy
Hydrogen Systems - II
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SeriesC:EnvironmentalSecurity
Carbon Nanomaterials in Clean
Energy Hydrogen Systems - II
editedby
Svetlana Yu. Zaginaichenko
Institute of Hydrogenand SolarEnergy,
Kiev, Ukraine
Dmitry V. Schur
Institute for Problemsof MaterialsScienceof NAS,
Kiev, Ukraine
Valeriy V. Skorokhod
Institute for Problemsof MaterialsScienceof NAS,
Kiev, Ukraine
Ayfer Veziroglu
International Association forHydrogen Energy,
University ofMiami, Miami,USA
and
Beycan ˙Ibrahimog˘lu
GaziUniversity,Department ofMechanical Engineering,
Ankara,Turkey
Published inCooperation with NATOEmerging SecurityChallengesDivision
Proceedings of theNATOAdvancedResearch Workshopon
Carbon Nanomaterials in Clean-EnergyHydrogen Systems
Yalta,Crimea, Ukraine
June 24–30,2010
ISBN 978-94-007-0901-0 (PB)
ISBN 978-94-007-0898-3 (HB)
ISBN 978-94-007-0899-0 (e-book)
DOI 10.1007/978-94-007-0899-0
Published bySpringer,
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Preface
The 2010 ARW “Carbon Nanomaterials in Clean-Energy Hydrogen Systems”
(CNCEHS’2010) was held in June 24–30, 2010 in the remarkable city of Yalta
(Crimea,Ukraine)knownforitsheroicandunusualhistory.Inthetraditionofthe
earlier conferences, CNCEHS’2010 meeting served as a multidisciplinary confer-
enceforthepresentationanddiscussionofthemostrecentresearchontransitionto
hydrogen-based energy systems, technologies for hydrogen production, storage,
utilization, carbon nanomaterials processing and chemical behavior, energy and
environmental problems. The aim of CNCEHS’2010 was to provide the wide
overviewofthelatestscientificresultsonbasicresearchandtechnologicalapplica-
tions of hydrogen interactions with carbon materials. As well-known, energy
shortage and environmental pollution is the major problem in the current word,
energy-saving characteristics of hydrogen occupies an important position in the
developmentofnewenergy,becausetheenergyisabasicandnecessarycomponent
in the development of the communities. The active delegates from different uni-
versities,research/academicorganizationsandgovernmentalagenciescouldmeet,
discussandpresentthemostrecentadvancesinhydrogenconcepts,processesand
systems, to evaluate current progress and to exchange academic information, to
identifyresearchneedsandfuturedevelopmentsinthisimportantarea.ThisARW
shouldhelpfurthertheprogressofhydrogen-basedsciencesandpromotetheuseof
hydrogenandcarbonnanomaterialsasessentialtomaketheHydrogenEconomya
reality.
According to the resolution of the International Advisory and Organizing
Committee, it has been established the awards “Oscars of Hydrogen Energy” for
scientists who have made major contributions to the promotion of hydrogen
energy worldwide. The world-famous scientist Prof. T. Nejat Veziroglu, who is
theauthorofagreatnumberofbooksandpapers,thePresidentoftheInternational
AssociationforHydrogenEnergy(IAHE),theFoundingDirectorofCleanEnergy
Research Institute of the University of Miami, USA, and the Founding Editor-
in-Chief of the International Journal of Hydrogen Energy was the first recipient
of the Award “Oscar of Hydrogen Energy”. Beycan Ibrahimoglu, the Director of
v
vi Preface
Dr. Dmitry V. Schur, chair of Organizing Committee of CNCENS’2010 and Prof. Beycan
I˙brahimog˘lu, Director of Plasmochemical Center in Ankara, Turkey, presented the first award
“Oscar of Hydrogen Energy” to Prof. T. Nejat Veziroglu, the President of the International
AssociationforHydrogenEnergy
Plasmochemical Center in Ankara, Turkey, was a producer of the “Oscar of
HydrogenEnergy”andwillbetheproviderofsuchawardsinthefuture.
Moreover according to the resolution of the International Advisory and
OrganizingCommittee,anumberofoutstandingscientistswhohaveconsiderable
achievementsinthefieldofcarbonnanostructuresandhydrogenenergyhavebeen
rewardedwithdiplomasofNATOARW“CarbonNanomaterialsinClean-Energy
HydrogenSystems”.Amongthemweresuchworld-widewell-knownscientistsas
Prof. Nikolay Kartel (Institute of Surface Chemistry of National Academy of
SciencesofUkraine,Kiev,Ukraine),Prof.NikolaKoprinarov(CentralLaboratory
for Solar Energy and New Energy of Bulgarian Academy of Sciences, Sofia,
Bulgaria), Prof. Marcin Leonowicz (Warsaw University of Technology, Poland),
Prof.VladimirI.ShapovalovandProf.RaoufO.Loutfy(Materials&Electrochem-
icalResearchCorporation,Tucson,USA),Prof.SergeyS.Ivanchev(St.-Petersburg
branchofInstituteofCatalysisnamedafterG.K.BoreskovoftheSiberianBranch
oftheRussianAcademyofScience,St.-Petersburg,Russia),Dr.YuriyM.Shulga
(Institute of Problems of Chemical Physics of Russian Academy of Sciences,
Chernogolovka, Russia), Zhanna Mileeva (The University of Salford, United
Kingdom), Nariman F. Javadov (Experimental-Industrial Plant of Institute for
Petroleum Chemical Processes (IPCP) of the Azerbaijan National Academy of
Sciences(NAS),Baku,Azerbaijan)andothers.
Preface vii
Members of International Advisory & Organizing Committee Dr. Yuriy M. Shulga, Prof.
Svetlana Yu. Zaginaichenko, Prof. T. Nejat Veziroglu and Dr. Dmitry V. Schur, presented the
NATOARWdiplomatoProf.SergeyS.Ivanchev,directorofSt.-PetersburgbranchofInstitute
of Catalysis named after G.K. Boreskov of the Siberian Branch of the Russian Academy of
Sciences,St.-Petersburg,Russia.
viii Preface
Thus, this event has attracted international researchers as well as younger
scientists to strengthen connections among scientists in the area of hydrogenated
carbon nanomaterials research. The CNCEHS’2010 is a solid example of how
NATO is promoting cooperation among scientists from developed countries of
Europe, America and NATO Partner countries. Since fossil fuel resources are
limitedandharmfultotheenvironment,moreattentionshavebeenpaidonrenew-
able energy recently. Therefore, conversion and utilization of renewable energy,
suchashydrogenenergy,becameoneofthemostimportant topicsofthisconfer-
ence since 1993 (1993, 1995, 1997, 1999, 2001, 2003, 2005, 2007). One goal in
organizing this conference was to prepare a discussion ambient for the related
peopleandscientistsworkingonrenewableenergyespeciallyonhydrogenenergy.
Weareplanningtorepeattheconferenceafter2years.WehopetheseARWandthe
onethatarebeingplanned for futurewillhelpthedevelopment ofthetechnology
onrenewableandhydrogenenergy.
The Proceedings of CNCEHS’2010 include some of the selected works pre-
senting in the course of oral presentations, at the poster sessions, and during the
round-tablediscussionsattheconferenceinYaltaandrepresentingthewidespectra
of hydrogen energy and carbon nanomaterials related themes, but also latest
progressinmanykeyareas.
Finally,theorganizationofthisconferencewassuccessfulthankstothesupport
by the Scientific and Environmental Affairs Division of NATO as the NATO
Science for Peace and Security Programme of the NATO Science Programme.
Their contribution isgratefullyacknowledged andtheOrganizingCommitteeand
all ARW participants want to overflow with effusive thanks to NATO for the
financialsupportoftheCNCEHS’2010ARW,andtoMr.JeanFournet,Assistant
SecretaryGeneral,ChairmanofNATOScienceCommittee,andDr.DenizBeten,
Section Head NATO Science for Peace Security, for the displayed mutual under-
standing and the comprehension of significance of problems under discussions at
theCNCEHS’2010ARW.
SvetlanaYu.Zaginaichenko
DmitryV.Schur
BeycanI˙brahimog˘lu
ValeriyV.Skorokhod
AyferVeziroglu
Contents
Preface............................................................................ v
Memorabledates............................................................... xv
85thAnniversaryofT.NejatVezirogluHonorary
ChairmanofICHMSPresidentofInternationalAssociation
forHydrogenEnergy.......................................................... xvi
75thAnniversaryofAcademicianV.V.Skorokhod....................... xviii
70thBirthdayofProfessorD.K.Ross....................................... xx
SvanteArrhenius,ChemistandNobelLaureate–
150thAnniversary........................................................... xxiii
WhowasPierreAuger?..................................................... xxiv
InmemoryofYu.F.Shmalko(14.04.1948–12.10.2008)................... xxv
InMemoryofN.S.Astratov(10.02.1944–19.08.2008) ................... xxvii
InMemoryofYuriiAndreevichOssipyan(1931–2008)................. xxviii
On150AnniversaryofM.PlanckBirthday................................ xxx
On115AnniversaryofP.L.KapitsaBirthday........................... xxxii
OnCentenaryofL.D.LandauBirthday.................................. xxxiv
1 ProblemsofDevelopmentofHydrogenPowerEngineering............ 1
L.F.Kozin,S.V.Volkov,S.G.Goncharenko,andB.I.Daniltsev
2 MaterialsContainingCarbonNanoparticlesforHydrogen
PowerEngineering....................................................... 23
E.M.Shpilevsky,S.A.Zhdanok,andD.V.Schur
ix
x Contents
3 AboutFe-Graphite-HPhaseDiagramLikeaScientificBase
ofHydrogenStoragesandHydrogenMembranes..................... 41
V.I.Shapovalov
4 SpecialFeaturesandRegularitiesofInteractionBetween
FullereneMoleculesandAromaticSolvents ........................... 53
N.S.Anikina,O.Ya.Krivuschenko,D.V.Schur,
S.Yu.Zaginaichenko,andE.A.Kamenetskaia
5 FullereneMoleculeasCatalystofSynthesis
ofCarbonNanotubes..................................................... 75
D.V.Schur,S.Yu.Zaginaichenko,V.A.Bogolepov,V.M.Adeev,
E.P.Rudakova,A.V.Kotko,V.V.Skorohod,andYu.M.Shulga
6 FormationandPropertiesofMagneticNanocrystallites
EmbeddedinCarbonBeads............................................. 81
M.Leonowicz,M.Izydorzak,A.D.Pomogailo,andG.Dzhardimaleva
7 HydrogenationofFulleriteC inGaseousPhase.................... 87
60
D.V.Schur,S.Yu.Zaginaichenko,A.F.Savenko,V.A.Bogolepov,
N.S.Anikina,A.D.Zolotarenko,Z.A.Matysina,T.NejatVeziroglu,
andN.E.Skryabina
8 CarbonNano/MicrostructuresforHybridHydrogen
StorageBasedonSpeciallyTreatedCarbonFibers.................. 107
Zh.A.Mileeva,I.L.Shabalin,D.K.Ross,V.A.Bogolepov,
S.Yu.Zaginaichenko,D.V.Schur,V.A.Begenev,
andZ.A.Matysina
9 CyclicHydrocarbonDecompositiontoCarbonNanoparticles
viaSparkDischarge..................................................... 115
M.KonstantinovaandN.Koprinarov
10 EncapsulatedFerromagneticNanoparticlesinCarbonShells....... 127
Al.D.Zolotarenko,An.D.Zolotarenko,V.A.Lavrenko,
S.Yu.Zaginaichenko,N.A.Shvachko,O.V.Milto,V.B.Molodkin,
A.E.Perekos,V.M.Nadutov,andYu.A.Tarasenko
11 ThePeculiaritiesofNanostructuresFormationinLiquidPhase.... 137
An.D.Zolotarenko,Al.D.Zolotarenko,E.Rudakova,
S.Yu.Zaginaichenko,A.G.Dubovoy,D.V.Schur,V.A.Lavrenko,
A.P.Pomytkin,A.E.Perekos,V.P.Zalutskiy,M.M.Divizinyuk,
E.V.Azarenko,andYu.A.Tarasenko
