Table Of Contentiiix
PREFACE
The global environmental problems, especially the global warming caused by the
accelerative accumulation of carbon dioxide in the atmosphere, are nowadays the most
crucial for human beings as well as global sustainability. Due to this global
environmental issue, the scientists and engineers, who had a strong interest and wished
to contribute to solve the carbon dioxide problem from technological aspects, gathered
and discussed the countermeasures in this conference. As a result of this effort, carbon
dioxide utilization has been making a progress and distinct contributions in conducting
the strategies for carbon dioxide mitigation and in finding the solution of these
environmental problems by adoption of a variety of technologies. In this regard, since
the first conference, held in 1991 at Nagoya, Japan, the ICCDU conferences have been
held every two years (alternating between North America, Europe, and Asia) with the
aim of coveting the latest developments in the field of carbon dioxide chemistry as it
pertains to utilization.
The 7th International Conference on Carbon Dioxide Utilization (7th ICCDU) was
held successfully at the Hoam Convention Center in Seoul, Korea from October 21 to
October ,61 2003. We would like to express sincere thank all the members of the Local
Organizing Committee for their active supports for the conference, the several
organizations for their financial support, and all the distinguished participants who have
traveled to Korea from around the world. The attendance in this conference was very
encouraging with respect to the futuristic perspective of the scientific field and the
efforts for the development on carbon dioxide utilization. The 7th ICCDU Conference
was organized by Korea Research Institute of Chemical Technology (KRICT) and
Carbon Dioxide Reduction & Sequestration (CDRS) R&D Center in Korea.
During the 4 day meeting of the 7th ICCDU, 5 plenary lectures, 41 keynote
lectures, and 35 papers were presented orally in 4 sessions and 66 papers were presented
as posters. Their topics of the 7th ICCDU covered the followings:
2OC separation and recovery including advanced 2OC separation system and
-
materials for 2OC separation
2OC as oxidant including dehydrogenation and oxidative conversions
-
heterogeneous catalysis of 2OC including catalytic 2OC conversions, plasma &
-
microwave application and 2OC rich syngas from biomass & fossil fuels
- homogeneous catalysis of 2OC including chemicals from CO2, polymers using
20C and electro- and photocatalytic reduction of 20C
biology and biochemistry of C02 utilization
-
vix
studies in supercritical 2OC including spectroscopic techniques and reactions in
-
supercritical 2OC
- utilization of 4HC/2OC hydrates
This book was conceived as the proceedings of the 7th ICCDU, which reflect the
most recent research results and stimulating scientific discussions with new challenges
in advancing the development of carbon dioxide utilization. These topics are important
in green chemistry and technology that are considered as essential fields for the global
sustainability. The organizers wish to express sincere appreciation to attendees of the
7th ICCDU and the authors for submitting their manuscripts to the proceedings.
We are grateful to the outstanding scientists who accepted our invitation to
overview vital research areas in plenary lectures and the keynote lectures that introduce
the important topics of each session covered by the conference. We are also grateful to
Dr. Choong Seob Kim (President of KRICT), Dr. Sang Do Park (Director of CDRS),
Prof. Yoichi Kaya (RITE/NEDO), Prof. Eunyoung Heo (Seoul National Univ.) for their
generous financial and administrative support.
We wish to thank Dr. Soo Min Oh (KRICT), Dr. Myoung-Jae Choi (KRICT), and
Prof. Woonsup Shin (Sogang Univ.), who have spent so much time and efforts for the
success of the 7th ICCDU conference.
Furthermore, we wish to thank members of the Research Center for Nanocatalysis
(RCNC), KRICT, especially Dr. Sung Hwa Jhung and Mr. Do-Young Hong, who very
efficiently helped in the preparation of the proceedings.
Finally we wish to acknowledge the help and support by co-operating
organizations and sponsors from industries.
Seoul, October 2003
Editors
Sang-Eon Park
Jong-San Chang
Kyu-Wan Lee
XV
Chairman's Remark
Thanks to the Contributors of 7 ht ICCDU,
This proceedings contain papers presented and displayed as posters at the Seventh
International Conference on Carbon Dioxide Utilization (ICCDU VII) held for four
days during October 12--16, 2003 at Hoam Convention Center in Seoul, Korea.
The ICCDU conferences are held every two years alternating continental. The First
ICCDU was held in Nagoya, Japan in 1991, the second at Bari, Italy in 1993, the third
at Oklahoma, USA in 1995, the fourth in Kyoto, Japan in 1997, the fifth at Karlsruhe,
Germany in 1999, the sixth at Breckenridge, USA in 2001 and the Seventh in Seoul,
Korea in 2003. The eighth will be held in Norway in 2005.
This Conference was aimed to cover the latest developments in the field of carbon
dioxide chemistry as it pertains to utilization in the world. In the 7 ht Conference
included seven fields and 12 detail subjects and emphasized specially on the
presentations of research results scale in pilot and demonstration operation and
utilization of biomass and CO2/methane hydrates which are recently more interested as
sustainable and renewable energy sources.
This ICCDU VII, was organized jointly by Korea Research Institute of Chemical
Technology (KRICT) and Carbon Dioxide Reduction & Sequestration R&D Center
(CDRS).
The conference was financially supported by the Ministry of Science and
Technology of Korea, Korea Research Institute of Chemical Technology, Carbon
Dioxide Reduction & Sequestration R&D Center and Research Institute of Innovative
Technology for the Earth (RITE)/New Energy and Industrial Technology Development
Organization (NEDO) in Japan.
I would like express my sincere thank to the all attendees and organizations for
their contribution to and cooperation in the 7 ht ICCDU.
Greetings from Yanji, Jilin, China
Chairman of ICCDU VII
Prof. .rD Ing. Kyu-Wan Lee
Yanbian University of Science & Technology
(YUST), Yanji, Jilin, China 133000
xvii
noitazinagrO
Organizing Committee
Chairman
Kyu-Wan Lee KRICT, Korea
yraterceS
Sang-Eon Park Inha Univ., Korea
International Advisory Board
Michele Aresta Campus ,.vinU Italy
David Beecy Department of Energy, ASU
Son-Ki Ihm KAIST, Korea
Donald Darensbourg saxaT A &M Univ., ASU
Tomoyki Inui Kyoto Univ., Japan
Eckhard Dinjus Karlsruhe Research Centre, Germany
Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan
Baldur Eliasson ABB Switzerland Ltd., Switzerland
Kenneth Nicholas Univ.of Oklahoma, ASU
International Scientific Committee
Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland
Philip Jessop Queen's Univ., Canada
Danielle Ballivet Universit~ de Bourgogne, France
Klaus .S Lackner Los Alamos National Laboratory, ASU
Dan DuBois .vinU of North Carolina, ASU
Jae-Sung Lee POSTECH, Korea
David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden
Kyu-Wan Lee KRICT, Korea
Giuseppe Filardo .vinU of Palermo, Italy
Chang-jun Liu Tianjin Univ., China
Martin .M Halmann Weizmann Institute of Science, Israel
nah-uY Sun Chinese Academic of Sciences, China
xvii
noitazinagrO
Organizing Committee
Chairman
Kyu-Wan Lee KRICT, Korea
yraterceS
Sang-Eon Park Inha Univ., Korea
International Advisory Board
Michele Aresta Campus ,.vinU Italy
David Beecy Department of Energy, ASU
Son-Ki Ihm KAIST, Korea
Donald Darensbourg saxaT A &M Univ., ASU
Tomoyki Inui Kyoto Univ., Japan
Eckhard Dinjus Karlsruhe Research Centre, Germany
Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan
Baldur Eliasson ABB Switzerland Ltd., Switzerland
Kenneth Nicholas Univ.of Oklahoma, ASU
International Scientific Committee
Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland
Philip Jessop Queen's Univ., Canada
Danielle Ballivet Universit~ de Bourgogne, France
Klaus .S Lackner Los Alamos National Laboratory, ASU
Dan DuBois .vinU of North Carolina, ASU
Jae-Sung Lee POSTECH, Korea
David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden
Kyu-Wan Lee KRICT, Korea
Giuseppe Filardo .vinU of Palermo, Italy
Chang-jun Liu Tianjin Univ., China
Martin .M Halmann Weizmann Institute of Science, Israel
nah-uY Sun Chinese Academic of Sciences, China
xvii
noitazinagrO
Organizing Committee
Chairman
Kyu-Wan Lee KRICT, Korea
yraterceS
Sang-Eon Park Inha Univ., Korea
International Advisory Board
Michele Aresta Campus ,.vinU Italy
David Beecy Department of Energy, ASU
Son-Ki Ihm KAIST, Korea
Donald Darensbourg saxaT A &M Univ., ASU
Tomoyki Inui Kyoto Univ., Japan
Eckhard Dinjus Karlsruhe Research Centre, Germany
Yoichi Kaya Research Institute of Innovative Technology for eht Earth, Japan
Baldur Eliasson ABB Switzerland Ltd., Switzerland
Kenneth Nicholas Univ.of Oklahoma, ASU
International Scientific Committee
Alfons Baiker Swiss Federal Institue of ,ygolonhceT Switzerland
Philip Jessop Queen's Univ., Canada
Danielle Ballivet Universit~ de Bourgogne, France
Klaus .S Lackner Los Alamos National Laboratory, ASU
Dan DuBois .vinU of North Carolina, ASU
Jae-Sung Lee POSTECH, Korea
David Dyrssen Chalmers .vinU of Technology and Gothenburg Univ., Sweden
Kyu-Wan Lee KRICT, Korea
Giuseppe Filardo .vinU of Palermo, Italy
Chang-jun Liu Tianjin Univ., China
Martin .M Halmann Weizmann Institute of Science, Israel
nah-uY Sun Chinese Academic of Sciences, China
xviii
Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland
Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan
Shohei Inoue Tokyo Univ. of Science, Japan
Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and
Technology, Japan
Local Advisory Board
Yong-Bok Chae Seoul National Univ., Korea
Hyun-Ku Rhee Seoul National Univ., Korea
Ho-In Lee Seoul National Univ., Korea
Sang-Chul Shim Kyungpook National Univ., Korea
Local Organizing Committee
Kyu-Wan Lee (Chairman) KRICT, Korea
Sang-Eon Park (Secretary) Inha Univ., Korea
Jong-San Chang KRICT, Korea
Jin-Suck Lee KIER, Korea
Soon-Haeng Cho KIER, Korea
Kew-Ho Lee KRICT, Korea
Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea
Dae-Won Park Pusan National Univ., Korea
Sung Hwa Jhung KRICT, Korea
Myoung-Jae Choi KRICT, Korea
Sang-Do Park KIER, Korea
Hee-Moon muE KEPRI, Korea
Woonsup Shin Sogang Univ., Korea
Sung-Hwan naH Hanyang Univ., Korea
Supporting Organizations
The Organizing Committee gratefully acknowledges the receipt of financial support from
Korea Research Institute of Chemical Technology (KRICT)
Ministry of Science dna Technology (MOST)
Korea Science dna Engineering Foundation (KOSEF)
xviii
Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland
Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan
Shohei Inoue Tokyo Univ. of Science, Japan
Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and
Technology, Japan
Local Advisory Board
Yong-Bok Chae Seoul National Univ., Korea
Hyun-Ku Rhee Seoul National Univ., Korea
Ho-In Lee Seoul National Univ., Korea
Sang-Chul Shim Kyungpook National Univ., Korea
Local Organizing Committee
Kyu-Wan Lee (Chairman) KRICT, Korea
Sang-Eon Park (Secretary) Inha Univ., Korea
Jong-San Chang KRICT, Korea
Jin-Suck Lee KIER, Korea
Soon-Haeng Cho KIER, Korea
Kew-Ho Lee KRICT, Korea
Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea
Dae-Won Park Pusan National Univ., Korea
Sung Hwa Jhung KRICT, Korea
Myoung-Jae Choi KRICT, Korea
Sang-Do Park KIER, Korea
Hee-Moon muE KEPRI, Korea
Woonsup Shin Sogang Univ., Korea
Sung-Hwan naH Hanyang Univ., Korea
Supporting Organizations
The Organizing Committee gratefully acknowledges the receipt of financial support from
Korea Research Institute of Chemical Technology (KRICT)
Ministry of Science dna Technology (MOST)
Korea Science dna Engineering Foundation (KOSEF)
xviii
Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland
Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan
Shohei Inoue Tokyo Univ. of Science, Japan
Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and
Technology, Japan
Local Advisory Board
Yong-Bok Chae Seoul National Univ., Korea
Hyun-Ku Rhee Seoul National Univ., Korea
Ho-In Lee Seoul National Univ., Korea
Sang-Chul Shim Kyungpook National Univ., Korea
Local Organizing Committee
Kyu-Wan Lee (Chairman) KRICT, Korea
Sang-Eon Park (Secretary) Inha Univ., Korea
Jong-San Chang KRICT, Korea
Jin-Suck Lee KIER, Korea
Soon-Haeng Cho KIER, Korea
Kew-Ho Lee KRICT, Korea
Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea
Dae-Won Park Pusan National Univ., Korea
Sung Hwa Jhung KRICT, Korea
Myoung-Jae Choi KRICT, Korea
Sang-Do Park KIER, Korea
Hee-Moon muE KEPRI, Korea
Woonsup Shin Sogang Univ., Korea
Sung-Hwan naH Hanyang Univ., Korea
Supporting Organizations
The Organizing Committee gratefully acknowledges the receipt of financial support from
Korea Research Institute of Chemical Technology (KRICT)
Ministry of Science dna Technology (MOST)
Korea Science dna Engineering Foundation (KOSEF)
xviii
Allan .A Johansson The Technical Research Centre of Pinland (VTT), Finland
Tatsuaki amihsaY Research Institute of lnnovative Technology for the Earth, Japan
Shohei Inoue Tokyo Univ. of Science, Japan
Shin-ya Yokoyama AIST Chugoku National Institute of Advanced Industrial Science and
Technology, Japan
Local Advisory Board
Yong-Bok Chae Seoul National Univ., Korea
Hyun-Ku Rhee Seoul National Univ., Korea
Ho-In Lee Seoul National Univ., Korea
Sang-Chul Shim Kyungpook National Univ., Korea
Local Organizing Committee
Kyu-Wan Lee (Chairman) KRICT, Korea
Sang-Eon Park (Secretary) Inha Univ., Korea
Jong-San Chang KRICT, Korea
Jin-Suck Lee KIER, Korea
Soon-Haeng Cho KIER, Korea
Kew-Ho Lee KRICT, Korea
Jae-Ou Choi Pohang Institute of Industrial Science and Technology, Korea
Dae-Won Park Pusan National Univ., Korea
Sung Hwa Jhung KRICT, Korea
Myoung-Jae Choi KRICT, Korea
Sang-Do Park KIER, Korea
Hee-Moon muE KEPRI, Korea
Woonsup Shin Sogang Univ., Korea
Sung-Hwan naH Hanyang Univ., Korea
Supporting Organizations
The Organizing Committee gratefully acknowledges the receipt of financial support from
Korea Research Institute of Chemical Technology (KRICT)
Ministry of Science dna Technology (MOST)
Korea Science dna Engineering Foundation (KOSEF)
